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leah4sci.com/hydride-shift-mechanism

Hydride shifts and methyl shifts can occur in organic chemistry reactions if there is a carbocation intermediate. While Markovnikov’s rule placed the carbocation on the more substituted of the 2 former sp2 (double bound) carbon atoms, if there is an EVEN MORE substituted carbon nearby you’ll get a carbocation rearrangement.

web.pdx.edu/~wamserc/C334F10/rearrangements.pdf

hydride shift should occur. If a secondary carbocation is vicinal to a quaternary carbon, a 1,2-alkyl shift should occur. The general rule in alkyl shifts is: the smaller alkyl substituent tends to be the substituent that shifts. Therefore, the most common 1,2-alkyl shift is a 1,2-methyl shift.

www.reference.com/science/hydride-shift-e18ce85e017948a4

A hydride shift is a rearrangement of atoms in which an unstable carbocation is transformed into a more stable one. Carbocations are ions with positively charged carbon atoms and are often found in organic chemistry.

en.wikipedia.org/wiki/1,2-rearrangement

The 1,2-rearrangement belongs to a broad class of chemical reactions called rearrangement reactions. A rearrangement involving a hydrogen atom is called a 1,2-hydride shift. If the substituent being rearranged is an alkyl group, it is named according to the alkyl group's anion: i.e. 1,2-methanide shift, 1,2-ethanide shift, etc.

www.ochempal.org/index.php/alphabetical/g-h/12-hydride-shift

A 1,2-hydride shift is a carbocation rearrangement in which a hydrogen atom in a carbocation migrates to the carbon atom bearing the formal charge of +1 (carbon 2) from an adjacent carbon (carbon 1). eg: see also 1,2-alkyl shift, 1,2-aryl shift

en.wikipedia.org/wiki/Hydride_shift

[1,7] sigmatropic shifts are predicted by the Woodward–Hoffmann rules to proceed in an antarafacial fashion, via a Mobius topology transition state. An antarafacial [1,7] shift is observed in the conversion of lumisterol to vitamin D 2, where following an electrocyclic ring opening to previtamin D 2, a methyl hydrogen shifts.

www.quora.com/What-is-the-order-of-shifting-rearrangement-in-hydride-alkyl-and...

If you are asking about migratory aptitude of Hydride, alkyl and phenyl groups, the order is: hydride > Phenyl = Tert-Alkyl > Sec-Alkyl > Primary Alkyl > Methyl There are two ways to understand / remember it: (1) The group which has maximum charge...

leah4sci.com/hydride-shift

Ring Expansion via Hydride Shift and Methyl Shift. November 18, 2012 By Leah4sci 2 Comments. Ring expansions occur as a carbocation rearrangement when an unstable cycloalkane is near a carbocation. You will come across ring expansion mechanisms during alkene reactions and later in SN1 and E1 reactions. ... Ring expansions may be followed by a 1 ...