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www.ochempal.org/index.php/alphabetical/g-h/12-hydride-shift

A 1,2-hydride shift is a carbocation rearrangement in which a hydrogen atom in a carbocation migrates to the carbon atom bearing the formal charge of +1 (carbon 2) from an adjacent carbon (carbon 1). eg: see also 1,2-alkyl shift, 1,2-aryl shift

en.wikipedia.org/wiki/1,2-rearrangement

The rearrangement is intramolecular and the starting compound and reaction product are structural isomers.The 1,2-rearrangement belongs to a broad class of chemical reactions called rearrangement reactions.. A rearrangement involving a hydrogen atom is called a 1,2-hydride shift.If the substituent being rearranged is an alkyl group, it is named according to the alkyl group's anion: i.e. 1,2 .....

chem.libretexts.org/Courses/Purdue/Purdue:_Chem_26505:_Organic_Chemistry_I...

Hydration of Alkenes: Hydride Shift. In a more complex case, when alkenes undergo hydration, we also observe hydride shift. Below is the reaction of 3-methyl-1-butene with H 3 O + that furnishes to make 2-methyl-2-butanol: Once again, we see multiple products. In this case, however, we see two minor products and one major product.

www.differencebetween.com/difference-between-hydride-and-methyl-shift

The rearranged carbocation is the major product of a synthesis reaction because it is the most stable form. If a secondary carbocation is vicinal to a tertiary carbon atom bearing a hydrogen atom, then a hydride shift occurs. We call this a 1,2-hydride shift. This shift is possible when there is a positive charge on the carbon atom where its ...

web.pdx.edu/~wamserc/C334F10/rearrangements.pdf

The mechanism of a 1,2-hydride shift and 1,2-alkyl shift. The mechanism for a 1,2-hydride and a 1,2-alkyl shift are the same. The arrow (electron movement) starts at the bond of the substituent moving and points right at the carbocation. This shows that the atom/atoms in the substituent with the electrons moved to the carbocation.

leah4sci.com/hydride-shift

They key is to recognize when a ring is unstable, and the type of rearrangement that will help it become more stable. But don’t stop there. Ring expansions may be followed by a 1,2-hydride or 1,2-methyl shift. The video below takes you through a tricky reaction mechanism taken from a students actual exam.

www.chemistrysteps.com/carbocation-rearrangements-sn1-reactions

This specific reaction of a rearrangement was a 1,2-hydride shift. The numbers are to emphasize that this shift can only happen from adjacent carbons. You cannot move the hydride ion 5 bonds away just because it gives a more stable carbocation. The other type of rearrangement is the 1,2-methyl shift. Here instead of the hydride ion, we have a ...

www2.chemistry.msu.edu/faculty/reusch/VirtTxtJml/rearrang.htm

Loss of water from the 3º-carbinol site, followed by a reversible 1,2-hydride shift, generates the conjugate acid of the ketone product. At short reaction times, racemization of recovered diol starting material occurs at the same rate as rearrangement.

en.wikipedia.org/wiki/Sigmatropic_reaction

[1,5] shifts. A [1,5] shift involves the shift of 1 substituent (hydride, alkyl, or aryl) down 5 atoms of a π system. Hydrogen has been shown to shift in both cyclic and open-chain compounds at temperatures at or above 200 ˚C. These reactions are predicted to proceed suprafacially, via a Hückel-topology transition state.

www.khanacademy.org/.../sn1-sn2-tutorial/v/carbocation-rearrangement-practice

Well, we could try a hydride shift again, but instead of trying one of the two hydrogens on the left, we could try this hydrogen on the right, the one in blue. So, lets try a hydride shift with that one. So, this hydrogen and these two electrons are gonna move over here to the carbon in magenta. So, let's draw what we would form.