Definitions

quartz

quartz

[kwawrts]
quartz, one of the commonest of all rock-forming minerals and one of the most important constituents of the earth's crust. Chemically, it is silicon dioxide, SiO2. It occurs in crystals of the hexagonal system, commonly having the form of a six-sided prism terminating in a six-sided pyramid; the crystals are often distorted and twins are common. Quartz may be transparent, translucent, or opaque; it may be colorless or colored. Varieties are classified as crystalline and cryptocrystalline. Crystalline varieties include ordinary colorless crystallized quartz, or rock crystal; rose quartz; yellow quartz, sometimes used as imitation topaz; smoky quartz, or cairngorm stone; milk-white milky quartz; aventurine quartz, which contains scales of hematite or mica; and amethyst. Varieties of cryptocrystalline quartz, the crystal structure of which can be seen only under the microscope, if at all, are chalcedony, flint, hornstone, and chert. Colored varieties of chalcedony known by special names are carnelian, sard, chrysoprase, agate, onyx, sardonyx, and jasper. Clastic quartzes are sand and sandstone.

Common, coarse-grained variety of quartz that ranges in colour from nearly black through smoky brown. No distinct boundary exists between smoky and colourless quartz. Its abundance causes it to be worth considerably less than either amethyst or citrine. Heating bleaches the stone, the colour sometimes passing through yellow; these yellow pieces are often sold as citrine.

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Translucent, coarse-grained variety of the silica mineral quartz found in pegmatites. Rose quartz is valued for its pale to rich pink colour, which is due to very small amounts of titanium. It has been carved since early times and has been faceted to provide gems of good brilliance. Its milky aspect is attributed to tiny, needlelike inclusions of rutile, which, when oriented, give the polished stone an asterism (optical phenomenon of a star-shaped figure) like that found in sapphire, but not as sharp or intense. Rose quartz occurs in Brazil, Madagascar, Sweden, Namibia, California, and Maine, among other sites.

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Second most abundant mineral (after feldspar) in the Earth's crust, present in many rocks. Quartz, which consists of silica, or silicon dioxide (SiO2), has great economic importance. Many varieties are gemstones, including amethyst, citrine, smoky quartz, and rose quartz. Sandstone, composed mainly of quartz, is an important building stone. Large amounts of quartz sand (or silica sand) are used in the manufacture of glass and ceramics and for molds in metal casting. Crushed quartz is used as an abrasive in sandpaper; silica sand is employed in sandblasting; and sandstone is used whole to make whetstones, millstones, and grindstones. Silica glass (or fused quartz) is used in optics to transmit ultraviolet light. Tubing and various vessels of fused quartz have important laboratory applications, and quartz fibres are employed in extremely sensitive weighing devices.

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Quartz (from German ) is the most abundant mineral in the Earth's continental crust (although feldspar is more common in the world as a whole). It is made up of a lattice of silica tetrahedra. Quartz has a hardness of 7 on the Mohs scale and a density of 2.65 g/cm³.

Crystal habit

Quartz belongs to the rhombohedral crystal system. The ideal crystal shape is a six-sided prism terminating with six-sided pyramids at each end. In nature quartz crystals are often twinned, distorted, or so intergrown with adjacent crystals of quartz or other minerals as to only show part of this shape, or to lack obvious crystal faces altogether and appear massive. Well-formed crystals typically form in a 'bed' that has unconstrained growth into a void, but because the crystals must be attached at the other end to a matrix, only one termination pyramid is present. A quartz geode is such a situation where the void is approximately spherical in shape, lined with a bed of crystals pointing inward.

Varieties

Pure quartz is colorless or white; colored varieties include rose quartz, amethyst, smoky quartz, milky quartz, and others. Quartz goes by an array of different names. The most important distinction between types of quartz is that of macrocrystalline (individual crystals visible to the unaided eye) and the microcrystalline or cryptocrystalline varieties (aggregates of crystals visible only under high magnification). Chalcedony is a generic term for cryptocrystalline quartz. The cryptocrystalline varieties are either translucent or mostly opaque, while the transparent varieties tend to be macrocrystalline.

Although many of the varietal names historically arose from the color of the mineral, current scientific naming schemes refer primarily to the microstructure of the mineral. Color is a secondary identifier for the cryptocrystalline minerals, although it is a primary identifier for the macrocrystalline varieties. This does not always hold true.

Major Varieties
Chalcedony Any cryptocrystalline quartz, although generally only used for white or lightly colored material. Otherwise more specific names are used.
Agate Multi-colored, banded chalcedony, semi-translucent to translucent
Onyx Agate where the bands are straight, parallel and consistent in size.
Jasper Opaque chalcedony, typically red to brown
Aventurine Translucent chalcedony with small inclusions (usually mica) that shimmer.
Tiger's eye Fibrous gold to red-brown coloured quartz, exhibiting chatoyancy.
Rock crystal Clear, colorless
Amethyst Purple, transparent
Citrine Yellow to reddish orange to brown, greenish yellow
Prasiolite Mint green, transparent
Rose quartz Pink, translucent, may display diasterism
Rutilated quartz Contains acicular (needles) inclusions of rutile
Milk quartz White, translucent to opaque, may display diasterism
Smoky quartz Brown to grey, opaque
Morion Dark-brown, opaque
Carnelian Reddish orange chalcedony, translucent

Synthetic and artificial treatments

Not all varieties of quartz are naturally occurring. Prasiolite, an olive colored material, is produced by heat treatment; natural prasiolite has also been observed in Lower Silesia in Poland. Although citrine occurs naturally, the majority is the result of heat-treated amethyst. Carnelian is widely heat-treated to deepen its color.

Due to natural quartz being so often twinned, much of the quartz used in industry is synthesized. Large, flawless and untwinned crystals are produced in an autoclave via the hydrothermal process; emeralds are also synthesized in this fashion. While these are still commonly referred to as quartz, the correct term for this material is silicon dioxide.

Occurrence

Quartz occurs in hydrothermal veins and pegmatites. Well-formed crystals may reach several meters in length and weigh hundreds of kilograms. These veins may bear precious metals such as gold or silver, and form the quartz ores sought in mining. Erosion of pegmatites may reveal expansive pockets of crystals, known as "cathedrals."

Quartz is a common constituent of granite, sandstone, limestone, and many other igneous, sedimentary, and metamorphic rocks.

Related silica minerals

Tridymite and cristobalite are high-temperature polymorphs of SiO2 that occur in high-silica volcanic rocks. Coesite is a denser polymorph of quartz found in some meteorite impact sites and in metamorphic rocks formed at pressures greater than those typical of the Earth's crust. Stishovite is a yet denser and higher-pressure polymorph of quartz found in some meteorite impact sites. Lechatelierite is an amorphous silica glass SiO2 which is formed by lightning strikes in quartz sand.

History

The name "quartz" comes from the German "Quarz", which is of Slavic origin (Czech miners called it křemen). Other sources insist the name is from the Saxon word "Querkluftertz", meaning cross-vein ore.

Quartz is the most common material identified as the mystical substance maban in Australian Aboriginal mythology. It is found regularly in passage tomb cemeteries in Europe in a burial context, eg. Newgrange or Carrowmore in the Republic of Ireland. The Irish word for quartz is grian cloch, which means 'stone of the sun'.

Roman naturalist Pliny the Elder believed quartz to be water ice, permanently frozen after great lengths of time. (The word "crystal" comes from the Greek word for ice.) He supported this idea by saying that quartz is found near glaciers in the Alps, but not on volcanic mountains, and that large quartz crystals were fashioned into spheres to cool the hands. He also knew of the ability of quartz to split light into a spectrum. This idea persisted until at least the 1600s.

In the 17th century, Nicolas Steno's study of quartz paved the way for modern crystallography. He discovered that no matter how distorted a quartz crystal, the long prism faces always made a perfect 60 degree angle.

Charles Sawyer invented the commercial quartz crystal manufacturing process in Cleveland, Ohio, United States. This initiated the transition from mined and cut quartz for electrical appliances to manufactured quartz.

Quartz's piezoelectric properties were discovered by Jacques and Pierre Curie in 1880. The quartz oscillator or resonator was first developed by Walter Guyton Cady in 1921 George Washington Pierce designed and patented quartz crystal oscillators in 1923 Warren Marrison created the first quartz oscillator clock based on the work of Cady and Pierce in 1927

Piezoelectricity

Quartz crystals have piezoelectric properties, that is they develop an electric potential upon the application of mechanical stress. An early use of this property of quartz crystals was in phonograph pickups. One of the most common piezoelectric uses of quartz today is as a crystal oscillator. The quartz clock is a familiar device using the mineral. The resonant frequency of a quartz crystal oscillator is changed by mechanically loading it, and this principle is used for very accurate measurements of very small mass changes in the quartz crystal microbalance and in thin-film thickness monitors.

See also

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References

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