Rode served as violin soloist to Napoleon I of France and toured extensively in the Netherlands, Germany, England and Spain, staying with François-Adrien Boïeldieu in Saint Petersburg for 1804-1809, and later spending much time in Moscow. Ludwig van Beethoven wrote his last violin sonata (opus 96) for Rode when the violinist was visiting Vienna. He also performed chamber music, but the backbone of his repertoire was formed by Viotti's concertos which served as models for his own concertos. These, as well as the 24 Caprices (which have been recorded by Oscar Shumsky), were written during 1814-1819 when he lived in Berlin.
In all, Pierre Rode composed 13 violin concertos and many other works for violin. Although Rode's violin concertos have some significance in the development of the Romantic concerto, they are nowadays rarely performed, and his major contribution to music must be seen in his influence to younger violinists, such as Louis Spohr, who adopted his style and developed it further. He turned out to be unsuccessful for some time and Spohr found that his skill had deteriorated. He refused to touch the violin for quite a while.
Pierre Rode died at Château de Bourbon near Damazan, Lot-et-Garonne, in his native Aquitaine.