Sir George Gabriel Stokes, 1st Baronet FRS (13 August 1819–1 February 1903), was a mathematician and physicist, who at Cambridge made important contributions to fluid dynamics (including the Navier–Stokes equations), optics, and mathematical physics (including Stokes' theorem). He was secretary, then president, of the Royal Society.
Stokes was the oldest of the trio of natural philosophers, James Clerk Maxwell and Lord Kelvin being the other two, who especially contributed to the fame of the Cambridge school of mathematical physics in the middle of the 19th century. Stokes's original work began about 1840, and from that date onwards the great extent of his output was only less remarkable than the brilliance of its quality. The Royal Society's catalogue of scientific papers gives the titles of over a hundred memoirs by him published down to 1883. Some of these are only brief notes, others are short controversial or corrective statements, but many are long and elaborate treatises.
His work on fluid motion and viscosity led to his calculating the terminal velocity for a sphere falling in a viscous medium. This became known as Stokes' law. He derived an expression for the frictional force (also called drag force) exerted on spherical objects with very small Reynolds numbers.
His work is the basis of the falling sphere viscometer,in which the fluid is stationary in a vertical glass tube. A sphere of known size and density is allowed to descend through the liquid. If correctly selected, it reaches terminal velocity, which can be measured by the time it takes to pass two marks on the tube. Electronic sensing can be used for opaque fluids. Knowing the terminal velocity, the size and density of the sphere, and the density of the liquid, Stokes' law can be used to calculate the viscosity of the fluid. A series of steel ball bearings of different diameter is normally used in the classic experiment to improve the accuracy of the calculation. The school experiment uses glycerine as the fluid, and the technique is used industrially to check the viscosity of fluids used in processes. The same theory explains why small water droplets (or ice crystals) can remain suspended in air (as clouds) until they grow to a critical size and start falling as rain (or snow and hail). Similar use of the equation can be made in the settlement of fine particles in water or other fluids.
The CGS unit of kinematic viscosity was named "stokes" in recognition of his work.
Perhaps his best-known researches are those which deal with the wave theory of light. His optical work began at an early period in his scientific career. His first papers on the aberration of light appeared in 1845 and 1846, and were followed in 1848 by one on the theory of certain bands seen in the spectrum.
In 1849 he published a long paper on the dynamical theory of diffraction, in which he showed that the plane of polarization must be perpendicular to the direction of propagation. Two years later he discussed the colours of thick plates.
In 1852, in his famous paper on the change of wavelength of light, he described the phenomenon of fluorescence, as exhibited by fluorspar and uranium glass, materials which he viewed as having the power to convert invisible ultra-violet radiation into radiation of longer wavelengths that are visible. The Stokes shift, which describes this conversion, is named in Stokes' honor. A mechanical model, illustrating the dynamical principle of Stokes's explanation was shown. The offshoot of this, Stokes line, is the basis of Raman scattering. In 1883, during a lecture at the Royal Institution, Lord Kelvin said he had heard an account of it from Stokes many years before, and had repeatedly but vainly begged him to publish it.
In the same year, 1852, there appeared the paper on the composition and resolution of streams of polarized light from different sources, and in 1853 an investigation of the metallic reflection exhibited by certain non-metallic substances. The research was to highlight the phenomenon of light polarization. About 1860 he was engaged in an inquiry on the intensity of light reflected from, or transmitted through, a pile of plates; and in 1862 he prepared for the British Association a valuable report on double refraction, a phenomenon where certain crystals show different refractive indices along different axes. Perhaps the best known crystal is Iceland spar, transparent calcite crytsals.
A paper on the long spectrum of the electric light bears the same date, and was followed by an inquiry into the absorption spectrum of blood.
In other departments of physics may be mentioned his paper on the conduction of heat in crystals (1851) and his inquiries in connection with Crookes radiometer; his explanation of the light border frequently noticed in photographs just outside the outline of a dark body seen against the sky (1883); and, still later, his theory of the x-rays, which he suggested might be transverse waves travelling as innumerable solitary waves, not in regular trains. Two long papers published in 1840—one on attractions and Clairaut's theorem, and the other on the variation of gravity at the surface of the earth—also demand notice, as do his mathematical memoirs on the critical values of sums of periodic series (1847) and on the numerical calculation of a class of definite integrals and infinite series (1850) and his discussion of a differential equation relating to the breaking of railway bridges (1849), research related to his evidence given to the Royal Commission on the Use of Iron in Railway structures after the Dee bridge disaster of 1847.
In his presidential address to the British Association in 1871, Lord Kelvin stated his belief that the application of the prismatic analysis of light to solar and stellar chemistry had never been suggested directly or indirectly by anyone else when Stokes taught it to him at Cambridge University some time prior to the summer of 1852, and he set forth the conclusions, theoretical and practical, which he learnt from Stokes at that time, and which he afterwards gave regularly in his public lectures at Glasgow. These statements, containing as they do the physical basis on which spectroscopy rests, and the way in which it is applicable to the identification of substances existing in the sun and stars, make it appear that Stokes anticipated Kirchhoff by at least seven or eight years. Stokes, however, in a letter published some years after the delivery of this address, stated that he had failed to take one essential step in the argument—not perceiving that emission of light of definite wavelength not merely permitted, but necessitated, absorption of light of the same wavelength. He modestly disclaimed "any part of Kirchhoff's admirable discovery," adding that he felt some of his friends had been over-zealous in his cause. It must be said, however, that English men of science have not accepted this disclaimer in all its fullness, and still attribute to Stokes the credit of having first enunciated the fundamental principles of spectroscopy.
In another way, too, Stokes did much for the progress of mathematical physics. Soon after he was elected to the Lucasian chair he announced that he regarded it as part of his professional duties to help any member of the university in difficulties he might encounter in his mathematical studies, and the assistance rendered was so real that pupils were glad to consult him, even after they had become colleagues, on mathematical and physical problems in which they found themselves at a loss. Then during the thirty years he acted as secretary of the Royal Society he exercised an enormous if inconspicuous influence on the advancement of mathematical and physical science, not only directly by his own investigations, but indirectly by suggesting problems for inquiry and inciting men to attack them, and by his readiness to give encouragement and help.
Stokes was involved in several investigations into railway accidents, especially the Dee bridge disaster in May 1847, and he served as a member of the subsequent Royal Commission into the use of cast iron in railway structures. He contributed to the calculation of the forces exerted by moving engines on bridges. The bridge failed because a cast iron beam was used to support the loads of passing trains. Cast iron is brittle in tension or bending, and many other similar bridges had to be demolished or reinforced.
He appeared as an expert witness at the Tay Bridge disaster, where he gave evidence about the effects of wind loads on the bridge. The centre section of the bridge (known as the High Girders) was completely destroyed during a storm on December 28, 1879, while an express train was in the section, and everyone aboard died (more than 75 victims). The Board of Inquiry listened to many expert witnesses, and concluded that the bridge was
As a result of his evidence, he was appointed a member of the subsequent Royal Commission into the effect of wind pressure on structures. The effects of high winds on large structures had been neglected at that time, and the commission conducted a series of measurements across Britain to gain an appreciation of wind speeds during storms, and the pressures they exerted on exposed surfaces.