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- A Romanization of the Chinese character 甘 (Gān), an abbreviation for Gansu Province in the People's Republic of China
- A Romanization of the Chinese character 赣 (Gàn), an abbreviation for:
- Gan River
- Jiangxi Province in the People's Republic of China, through which the river flows
- Gan (linguistics) varieties of Chinese, which are concentrated in and form the typical speech of Jiangxi
- gan is the ISO 639-3 language code for Gan
- Gan (deity) a deity worshipped in the vicinity of Thistle Mountain, in Guangxi Province, China.
- Gan (Stephen King), the creative overforce in The Dark Tower series by Stephen King
- GAN (cycling team), a French cycling team
- GaN, Gallium(III) nitride, a direct-bandgap semiconductor material of wurtzite crystal structure
- .gan, the file extension for documents created by GanttProject
- gan, an Elvish board game played in The Obsidian Trilogy by Mercedes Lackey and James Mallory
In places:
- Gan, Norway, a village in Fet in Norway
- Gan, Pyrénées-Atlantiques, a commune in the Pyrénées-Atlantiques département in France
- Gan (Huvadhu Atoll), Republic of Maldives
- Gan (Laamu Atoll), Republic of Maldives
- Gan (Seenu Atoll), Republic of Maldives
- Gan International Airport, Maldive by IATA code
- Gananoque, Ontario, Canada, by local nickname
In fictional characters:
- Olag Gan, a fictional character in the British television series Blake's 7
- Gan Isurugi, a fictional character from the Rival Schools video game series
GAN as an acronym may refer to:
- Generic Access Network formerly known as Unlicensed Mobile Access (UMA)
- Giant axonal neuropathy and is also the name of the gene that when mutated causes the disorder.
- Global Area Network
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Last updated on Tuesday July 08, 2008 at 14:07:20 PDT (GMT -0700)
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The compound is a direct-bandgap semiconductor material of wurtzite crystal structure, with a wide (3.4 eV) band gap, used in optoelectronic, high-power and high-frequency devices. It is a binary group III/group V direct bandgap semiconductor. Its sensitivity to ionizing radiation is low (like other group III nitrides), making it a suitable material for solar cell arrays for satellites. Because GaN transistors can operate at much hotter temperatures and work at much higher voltages than GaAs transistors, they make ideal power amplifiers at microwave frequencies.
Physical properties
GaN is a very hard, mechanically stable material with large heat capacity. In its pure form it resists cracking and can be deposited in thin film on sapphire or silicon carbide, despite the mismatch in their lattice constants. GaN can be doped with silicon (Si) or with oxygen to N-type and with magnesium (Mg) to P-type, however the Si and Mg atoms change the way the GaN crystals grow, introducing tensile stresses and making them brittle. Gallium nitride compounds also tend to have a high spatial defect frequency, on the order of a hundred million to ten billion defects per square centimeter.GaN-based parts are very sensitive to electrostatic discharge.
Developments
The high crystalline quality of GaN can be realized by low temperature deposited buffer layer technology. This high crystalline quality GaN led to the discovery of p-type GaN, p-n junction blue/UV-LEDs and room-temperature stimulated emission (indispensable for laser action). This has led to the commercialization of high-performance blue LEDs and long-lifetime violet-laser diodes (LDs), and to the development of nitride-based devices such as UV detectors and high-speed field-effect transistors.High-brightness GaN light-emitting diodes (LEDs) completed the range of primary colors, and made applications such as daylight visible full-color LED displays, white LEDs and blue laser devices possible. The first GaN-based high-brightness LEDs were using a thin film of GaN deposited via MOCVD on sapphire. Other substrates used are zinc oxide, with lattice constant mismatch only 2%, and silicon carbide (SiC).
Group III nitride semiconductors are recognized as one of the most promising materials for fabricating optical devices in the visible short-wavelength and UV region. Potential markets for high-power/high-frequency devices based on GaN include microwave radio-frequency power amplifiers (such as used in high-speed wireless data transmission) and high-voltage switching devices for power grids. A potential mass-market application for GaN-based RF transistors is as the microwave source for microwave ovens, replacing the magnetrons currently used. The large band gap means that the performance of GaN transistors is maintained up to higher temperatures than silicon transistors.The first Gallium Nitride metal/oxide semiconductor field-effect transistor (GaN MOSFET) was experimentally demonstrated by Weixiao Huang of Rensselaer Polytechnic Institute in early 2008
Applications
GaN, when doped with a suitable transition metal such as manganese, is a promising spintronics material (magnetic semiconductors).Nanotubes of GaN are proposed for applications in nanoscale electronics, optoelectronics and biochemical-sensing applications
A GaN-based blue laser diode is used in the Blu-ray disc technologies, and in devices such as the Sony PlayStation 3.
The mixture of GaN with In (InGaN) or Al (AlGaN) with a band gap dependent on ratio of In or Al to GaN allows to build light emitting diodes (LEDs) with colors that can go from red to blue.
Synthesis
GaN crystals can be grown from a molten Na/Ga melt held under 100atm pressure of N2 at 750oC. As Ga will not react with N2 below 1000oC the powder must be made from something more reactive, and is usually made in one of the following ways:Ga + NH3 -> GaN + 3/2H2
Ga2O3 + NH3 -> GaN + H2O
Safety and toxicity aspects
The toxicology of GaN has not been fully investigated. The dust is an irritant to skin, eyes and lungs. The environment, health and safety aspects of gallium nitride sources (such as trimethylgallium and ammonia) and industrial hygiene monitoring studies of MOVPE sources have been reported recently in a review.See also
References
Further reading
- Isamu Akasaki and Hiroshi Amano: "Breakthroughs in Improving Crystal Quality of GaN and Invention of the p–n Junction Blue-Light-Emitting Diode" Japanese Journal of Applied Physics, Vol. 45, No. 12, 2006, pp. 9001-9010.
- Isamu Akasaki and Hiroshi Amano: " Crystal Growth and Conductivity Control of Group III Nitride Semiconductors and Their Application to Short Wavelength Light Emitters" Japanese Journal of Applied Physics, Vol. 36, 1997, pp. 5393-5408.
- Shuji Nakamura, Gerhard Fasol, Stephen J. Pearton, The Blue Laser Diode : The Complete Story, Springer; 2nd edition, October 2, 2000, (ISBN 3-540-66505-6)
- Jacques I. Pankove, T. D. Moustakas, Gallium Nitride (GaN) II: Semiconductors and Semimetals, Academic Press, 1998 (ISBN 0-12-752166-6)
- Shuji Nakamura, Gerhard Fasol, Stephen J Pearton The Blue Laser Diode: The Complete Story, Springer Verlag, 2nd Edition (October 2, 2000)
- UCSB Press release describing Shuji Nakamura's work
External links
Generic
- The Wide Bandgap Semiconductor Materials and Devices Group at MIT
- The Cambridge center for galium nitride (GaN)
- Photonics Sources Group, Tyndall National Institute GaN and other photonics research at the Tyndall National Institute, Ireland.
- External MSDS Data Sheet
- Ioffe data archive
- National Compound Semiconductor Roadmap page at ONR
- Nitronex Nitronex is a corporation that is manufacturing GaN on silicon RF power transistors and GaN on silicon epi wafers for sale.
- Ferdinand-Braun-Institut für Höchstfrequenztechnik (FBH), Berlin
Commercial links
- Informative commercial link to Trimethylgallium and other metalorganics.
- Interactive Vapor Pressure Chart for metalorganics
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Last updated on Tuesday July 22, 2008 at 05:44:55 PDT (GMT -0700)
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