A
ferrate is the anion FeO
42- in which
iron is in a +6 formal
oxidation state (
iron VI). A ferrate can be formed by
oxidizing iron with strong oxidizing agents under
alkaline conditions or in the solid state by heating a mixture of iron filings and powdered potassium nitrate, but it is unstable, especially at neutral to acid
pH. Aqueous solutions of ferrates are pink when dilute, deep red at higher concentrations. Ferrate ion is a stronger oxidizing agent than
permanganate and will oxidize
ammonia to elemental
nitrogen.
See also