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Einstein Relation (kinetic Theory)
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In physics (namely, in kinetic theory) the Einstein relation (also known as Einstein-Smoluchowski relation) is a previously unexpected connection revealed by Albert Einstein in 1905 and later by Marian Smoluchowski (1906) in their papers on Brownian motion:

D = {mu_p , k_B T}

linking D, the Diffusion constant, and μp, the mobility of the particles; where k_B is Boltzmann's constant, and T is the absolute temperature.

The mobility μp is the ratio of the particle's terminal drift velocity to an applied force, μp = vd / F.

This equation is an early example of a fluctuation-dissipation relation.

Diffusion of particles

In the limit of low Reynolds number, the mobility μ is the inverse of the drag coefficient γ. For spherical particles of radius r, Stokes' law gives

gamma = 6 pi , eta , r,

where η is the viscosity of the medium. Thus the Einstein relation becomes

D=frac{k_B T}{6pi,eta,r}

This equation is also known as the Stokes-Einstein Relation. We can use this to estimate the Diffusion coefficient of a globular protein in aqueous solution: For a 100 kDalton protein, we obtain D ~10-10 m² s-1, assuming a "standard" protein density of ~1.2 103 kg m-3.

Electrical conduction

When applied to electrical conduction, it is normal to define an electrical mobility by multiplying the mechanical mobility mu_p by the charge of the particle q of the charge carriers:

mu_q = q*{mu_p}

or alternatively formulated:

mu_q = {{v_d}over{E}}

where E is the applied electric field; so the Einstein relation becomes

D = {{mu_q , k_B T}over{q}}

In a semiconductor with an arbitrary density of states the Einstein relation is

D = {{mu_q , p}over{q {{d , p}over{d eta}}}}

where eta is the chemical potential and p the particle number

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