In mechanics, a constant of motion is a quantity that is conserved throughout the motion, imposing in effect a constraint on the motion. However, it is a mathematical constraint, the natural consequence of the equations of motion, rather than a physical constraint (which would require extra constraint forces). Common examples include energy, linear momentum, angular momentum and the Laplace-Runge-Lenz vector (for inverse-square force laws).
Constants of motion are useful because they allow properties of the motion to be derived without solving the equations of motion. In fortunate cases, even the trajectory of the motion can be derived as the intersection of isosurfaces corresponding to the constants of motion. For example, Poinsot's construction shows that the torque-free rotation of a rigid body is the intersection of a sphere (conservation of total angular momentum) and an ellipsoid (conservation of energy), a trajectory that might be otherwise hard to derive and visualize. Therefore, the identification of constants of motion is an important objective in mechanics.
There are several methods for identifying constants of motion.
Another useful result is Poisson's theorem, which states that if two quantities and are constants of motion, so is their Poisson bracket .
A system with n degrees of freedom, and n constants of motion, such that the Poisson bracket of any pair of constants of motion vanishes, is known as a completely integrable system. Such a collection of constants of motion are said to be in involution with each other.
And also, that there is a wave function which obeys Schrodinger's equation
Taking the time derivative of the expectation value of Q requires use of the product rule, and results in
| = frac{d}{dt} langle psi > Q | psi rangle , | |
| = langle frac{dpsi}{dt} > Q | psi rangle + langle psi | frac{dQ}{dt} | psi rangle + langle psi | Q | frac{dpsi}{dt} rangle, | |
| = frac{-1}{ihbar} langle H psi > Q | psi rangle + langle psi | frac{dQ}{dt} | psi rangle + frac{1}{ihbar}langle psi | Q | H psi rangle , | |
| = frac{-1}{ihbar} langle psi > HQ | psi rangle + langle psi | frac{dQ}{dt} | psi rangle + frac{1}{ihbar}langle psi | QH | psi rangle , | |
| = frac{-1}{i hbar} langle psi>left[H,Qright]|psi rangle + langle psi | frac{dQ}{dt} | psi rangle , |
So finally,
| frac{d}{dt} langle psi > Q | psi rangle = frac{-1}{i hbar} langle psi| left[H,Q right]|psi rangle + langle psi | frac{dQ}{dt} | psi rangle , |
In general, an integrable system has constants of motion other than the energy. By contrast, energy is the only constant of motion in a non-integrable system; such systems are termed chaotic. In general, a classical mechanical system can be quantized only if it is integrable; as of 2006, there is no known consistent method for quantizing chaotic dynamical systems.