Case hardening involved packing the iron in a substance high in carbon, and heating it in that environment to encourage carbon to migrate into the surface of the iron. This formed a thin layer of higher carbon steel on the surface, with the carbon content gradually decreasing further from the surface. The resulting product had much of the toughness of the softer iron core, with the hardness and wear resistance of the outer steel.
The traditional method of applying the carbon to the surface of the iron involved packing the iron in a mixture of ground bone and charcoal or a combination of leather, hooves, salt and urine, all inside a well-sealed box. The resulting package is then heated to a high temperature, but still under the melting point of the iron, and left at that temperature for a length of time. The longer the package is held at the high temperature, the deeper the carbon will diffuse into the surface. Different depths of hardening would be needed for different purposes; sharp tools would need deep hardening to allow them to be ground and resharpened without exposing the soft core, while machine parts like gears might need only a shallow hardening for increased wear resistance.
The resulting case hardened part may show a distinct coloration on the surface. The iron darkens significantly, and shows a mottled pattern of black, blue and purple caused by the various compounds formed by impurities in the bone and charcoal. This oxide surface works similar to blueing, providing some degree of corrosion resistance, in addition to being considered by many to be a very attractive finish. Case coloring refers to this pattern, and is commonly encountered as a decorative finish on replica firearms such as those patterned after single action Colt revolvers and lever-action rifles.
With modern steelworking techniques, it is possible to make homogenous steels of low to high carbon content, removing much of the original motivation for case hardening. However, the heterogeneous nature of case hardened steel may still be desirable, as it provides a combination of hardness and toughness that cannot readily be matched by homogenous alloys.
Adding an easily decomposed carbonate "energiser" such as barium carbonate breaks down to BaO + CO2 and this encourages the reaction
It's 'common knowledge' that case-hardening was done with bone, but this is misleading. Although bone was used, the main carbon donor was hoof and horn. Bone contains some carbonates, but is mainly calcium phosphate (as hydroxylapatite). This doesn't have the beneficial effect on encouraging CO production and it can also supply phosphorus as an impurity into the steel alloy.
The term case hardening is derived from the practicalities of the carburization process itself, which is essentially the same as the ancient process. The steel work piece is placed inside a case packed tight with a carbon-based case hardening compound. This is collectively known as a carburizing pack. The pack is put inside a hot furnace for a variable length of time. Time and temperature determines how deep into the surface the hardening extends. However, the depth of hardening is ultimately limited by the inability of carbon to diffuse deeply into solid steel, and a typical depth of surface hardening with this method is up to 1.5 mm. Other techniques are also used in modern carburizing, such as heating in a carbon rich atmosphere. Small items may be case hardened by repeated heating with a torch and quenching in a carbon rich medium, such as the commercial products Kasenit / Casenite or "Cherry Red". Older formulations of these compounds contain potentially toxic cyanide compounds, such as ferrocyanide compounds, while the more recent types such as Cherry Red do not.
Flame or induction hardening are processes in which the surface of the steel is heated to high temperatures (by direct application of a flame, or by induction heating) then cooled rapidly, generally using water; this creates a "case" of martensite on the surface. A carbon content of 0.4–0.6 wt% C is needed for this type of hardening.
Typical uses are for the shackle of a lock, where the outer layer is hardened to be file resistant, and mechanical gears, where hard gear mesh surfaces are needed to maintain a long service life while toughness is required to maintain durability and resistance to catastrophic failure.
A process used to case harden steel with a carbon content between 0.1 and 0.3 wt% C. In this process steel is introduced to a carbon rich environment and elevated temperatures for a certain amount of time, and then quenched so that the carbon is locked in the structure; one of the simpler procedures is repeatedly to heat a part with an acetylene torch set with a fuel-rich flame and quench it in a carbon-rich fluid such as oil.
Carburization is a diffusion-controlled process, so the longer the steel is held in the carbon-rich environment the greater the carbon penetration will be and the higher the carbon content. The carburized section will have a carbon content high enough that it can be hardened again through flame or induction hardening.
It's possible to carburize only a portion of a part, either by protecting the rest by a process such as copper plating, or by applying a carburizing medium to only a section of the part.
The carbon can come from a solid, liquid or gaseous source; if it comes from a solid source the process is called pack carburizing. Packing low carbon steel parts with a carbonaceous material and heating for some time diffuses carbon into the outer layers. A heating period of a few hours might form a high-carbon layer about one millimeter thick.
Liquid carburizing involves placing parts in a bath of a molten carbon-containing material, often a metal cyanide; gas carburizing involves placing the parts in a furnace maintained with a methane-rich interior.
This process heats the steel part to 482–621 °C (900–1150 °F) in an atmosphere of ammonia gas and dissociated ammonia. The time the part spends in this environment dictates the depth of the case. The hardness is achieved by the formation of nitrides. Nitride forming elements must be present for this method to work; these elements include chromium, molybdenum, and aluminium. The advantage of this process is it causes little distortion, so the part can be case hardened after being quench and tempered and machined.
This process produces a thin, hard shell (between 0.010 and 0.030 inches) that is harder than the one produced by carburizing, and can be completed in 20 to 30 minutes compared to several hours so the parts have less opportunity to become distorted. It is typically used on small parts such as bolts, nuts, screws and small gears. The major drawback of cyaniding is that cyanide salts are poisonous.
This process is similar to cyaniding except a gaseous atmosphere of ammonia and hydrocarbons is used instead of sodium cyanide. If the part is to be quenched then the part is heated to 775–885 °C (1425–1625 °F); if not then the part is heated to 649–788 °C (1200–1450 °F). Trade names for the process include Tenifer, Melonite, Sursulf, Arcor, Tufftride, and Koline.
Firearms were a common item case hardened in the past, as they required precision machining best done on low carbon alloys, yet needed the hardness and wear resistance of a higher carbon alloy. Many modern replicas of older firearms, particularly single action revolvers, are still made with case hardened frames, or with case coloring, which simulates the mottled pattern left by traditional charcoal and bone case hardening.
Another common application of case hardening is on screws, particularly self-drilling screws. In order for the screws to be able to drill, cut and tap into other materials like steel, the drill point and the forming threads must be harder than the material(s) that it is drilling into. However if the whole screw is uniformly hard, it will become very brittle and it will break easily. This is overcome by ensuring that only the case is hardened and the core remains relatively soft. For screws and fasteners, case hardening is less complicated as it is achieved by heating and quenching in the form of heat treatment
For theft prevention, lock shackles and chains are often case-hardened to resist cutting while remaining less brittle inside to resist impacts. As case hardened components can only be cut by grinding, they are generally cut to length before case hardening.
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