Aluminium alloy compositions are registered with the Aluminium Association. Many organizations publish more specific standards for the manufacture of aluminium alloy, including the Society of Automotive Engineers standards organization, specifically its aerospace standards subgroups, and the ASTM.
Where failure is not an issue but excessive flex is undesirable due to requirements for precision of location, or efficiency of transmission of power, simple replacement of steel tubing with similarly sized aluminium tubing will result in a degree of flex which is undesirable; for instance, the increased flex under operating loads caused by replacing steel bicycle frame tubing with aluminium tubing of identical dimensions will cause misalignment of the power-train as well as absorbing the operating force. To increase the rigidity by increasing the thickness of the walls of the tubing increases the weight proportionately, so that the advantages of lighter weight are lost as the rigidity is restored.
In such cases, aluminium may best be used by redesigning the dimension of the part to suit its characteristics; for instance making a bicycle frame of aluminium tubing that has an oversize diameter rather than thicker walls. In this way, rigidity can be restored or even enhanced without increasing weight. The limit to this process is the increase in susceptibility to buckling failure.
The latest models of the Corvette automobile, among others, are a good example of redesigning parts to make best use of aluminium's advantages. The aluminium chassis members and suspension parts of these cars have large overall dimensions for stiffness but are lightened by reducing cross-sectional area and removing unneeded metal. As a result, they are not only equally or more durable and stiff than the steel parts they replace, but they possess an airy gracefulness that most people find attractive. Similarly, aluminium bicycle frames can be optimally designed so as to provide rigidity where required, yet exhibit some extra flexibility, which functions as a natural shock absorber for the rider.
The strength and durability of aluminium varies widely, not only as a result of the components of the specific alloy, but also as a result of the manufacturing process. This variability, plus a learning curve in employing it, has from time to time gained aluminium a bad reputation. For instance, a high frequency of failure in many poorly designed early aluminium bicycle frames in the 1970s hurt aluminium's reputation for this use. However, the widespread use of aluminium components in the aerospace and high-performance automotive industries, where huge stresses are withstood with vanishingly small failure rates, illustrates that properly built aluminium bicycle components need not be intrinsically unreliable. Time and experience has subsequently proven this to be the case.
Similarly, use of aluminium in automotive applications, particularly in engine parts that must survive in difficult conditions, has benefited from development over time. An Audi engineer, in commenting about the V12 engine--producing over 500 horsepower (370 kW)--of an Auto Union race car of the 1930s that was recently restored by the Audi factory, noted that the engine's original aluminium alloy would today be used only for lawn furniture and the like. As recently as the 1960s, the aluminium cylinder heads and crankcase of the Corvair earned a reputation for failure and stripping of threads in holes, even as large as spark plug holes, which is not seen in current aluminium cylinder heads.
One important structural limitation of an aluminium alloy is its fatigue properties. While steel has a high fatigue limit (the structure can theoretically withstand an infinite number of cyclical loadings at this stress), aluminium's fatigue limit is near zero, meaning that it will eventually fail under even very small cyclic loadings, but for small stresses this can take an exceedingly long time.
Aluminium also is subject to internal stresses and strains when it is overheated; the tendency of the metal to creep under these stresses tends to result in delayed distortions. For instance, the warping or cracking of overheated aluminium automobile cylinder heads is commonly observed, sometimes years later, as is the tendency of welded aluminium bicycle frames to gradually twist out of alignment from the stresses of the welding process. Thus, the aerospace industry avoids heat altogether by joining parts with adhesives or mechanical fasteners. Adhesive bonding was used in some bicycle frames in the 1970s, with unfortunate results when the aluminium tubing corroded slightly, loosening the adhesive and collapsing the frame.
Stresses in overheated aluminium can be relieved by heat-treating the parts in an oven and gradually cooling it — in effect annealing the stresses. Yet these parts may still become distorted, so that heat-treating of welded bicycle frames, for instance, can result in a significant fraction becoming misaligned. If the misalignment is not too severe, the cooled parts may be bent into alignment. Of course, if the frame is properly designed for rigidity (see above), that bending will require enormous force.
Aluminium's intolerance to high temperatures has not precluded its use in rocketry; even for use in constructing combustion chambers where gases can reach 3500 K. The Agena upper stage engine used a regeneratively cooled aluminium design for some parts of the nozzle, including the thermally critical throat region; in fact the extremely high thermal conductivity of aluminium prevented the throat from reaching the melting point even under massive heat flux, resulting in a reliable lightweight component.
Because of its high conductivity and relatively low price compared with copper in the 1960s, aluminium was introduced at that time for household electrical wiring in the United States, even though many fixtures had not been designed to accept aluminium wire. But the new use brought some problems:
All of this resulted in overheated and loose connections, and this in turn resulted in some fires. Builders then became wary of using the wire, and many jurisdictions outlawed its use in very small sizes, in new construction. Yet newer fixtures eventually were introduced with connections designed to avoid loosening and overheating. At first they were marked "Al/Cu", but they now bear a "CO/ALR" coding.
Another way to forestall the heating problem is to crimp the aluminium wire to a short "pigtail" of copper wire. A properly done high-pressure crimp by the proper tool is tight enough to reduce any thermal expansion of the aluminium. Today, new alloys, designs, and methods are used for aluminium wiring in combination with aluminium terminations.
| Alloy | Si | Fe | Cu | Mn | Mg | Cr | Zn | V | Ti | Bi | Ga | Pb | Zr | Limits†† | Al | |
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| each | total | |||||||||||||||
| 1060 | 0.25 | 0.35 | 0.05 | 0.03 | 0.03 | 0.03 | 0.05 | 0.05 | 0.03 | 0.03 | 0.03 | 0.03 | 0.03 | 0.03 | 99.6 min | |
| 1100 | 0.95 Si+Fe | 0.05-0.20 | 0.05 | 0.10 | 0.05 | 0.15 | 99.0 min | |||||||||
| 2014 | 0.50-1.2 | 0.7 | 3.9-5.0 | 0.40-1.2 | 0.20-0.8 | 0.10 | 0.25 | 0.15 | 0.05 | 0.15 | remainder | |||||
| 2024 | 0.50 | 0.50 | 3.8-4.9 | 0.30-0.9 | 1.2-1.8 | 0.10 | 0.25 | 0.15 | 0.05 | 0.15 | remainder | |||||
| 2219 | 0.2 | 0.30 | 5.8-6.8 | 0.20-0.40 | 0.02 | 0.10 | 0.05-0.15 | 0.02-0.10 | 0.10-0.25 | 0.05 | 0.15 | remainder | ||||
| 3003 | 0.6 | 0.7 | 0.05-0.20 | 1.0-1.5 | 0.10 | 0.05 | 0.15 | remainder | ||||||||
| 3004 | 0.30 | 0.7 | 0.25 | 1.0-1.5 | 0.8-1.3 | 0.25 | 0.05 | 0.15 | remainder | |||||||
| 3102 | 0.40 | 0.7 | 0.10 | 0.05-0.40 | 0.30 | 0.10 | 0.05 | 0.15 | remainder | |||||||
| 4043 | 4.5-6.0 | 0.80 | 0.30 | 0.05 | 0.05 | 0.10 | 0.20 | 0.05 | 0.15 | remainder | ||||||
| 5052 | 0.25 | 0.40 | 0.10 | 0.10 | 2.2-2.8 | 0.15-0.35 | 0.10 | 0.05 | 0.15 | remainder | ||||||
| 5083 | 0.40 | 0.40 | 0.10 | 0.40-1.0 | 4.0-4.9 | 0.05-0.25 | 0.25 | 0.15 | 0.05 | 0.15 | remainder | |||||
| 5086 | 0.40 | 0.50 | 0.10 | 0.20-0.7 | 3.5-4.5 | 0.05-0.25 | 0.25 | 0.15 | 0.05 | 0.15 | remainder | |||||
| 5154 | 0.25 | 0.40 | 0.10 | 0.10 | 3.10-3.90 | 0.15-0.35 | 0.20 | 0.20 | 0.05 | 0.15 | remainder | |||||
| 5356 | 0.25 | 0.40 | 0.10 | 0.10 | 4.50-5.50 | 0.05-0.20 | 0.10 | 0.06-0.20 | 0.05 | 0.15 | remainder | |||||
| 5454 | 0.25 | 0.40 | 0.10 | 0.50-1.0 | 2.4-3.0 | 0.05-0.20 | 0.25 | 0.20 | 0.05 | 0.15 | remainder | |||||
| 5456 | 0.25 | 0.40 | 0.10 | 0.50-1.0 | 4.7-5.5 | 0.05-0.20 | 0.25 | 0.20 | 0.05 | 0.15 | remainder | |||||
| 6005 | 0.6-0.9 | 0.35 | 0.10 | 0.10 | 0.40-0.6 | 0.10 | 0.10 | 0.10 | 0.05 | 0.15 | remainder | |||||
| 6005A† | 0.50-0.9 | 0.35 | 0.30 | 0.50 | 0.40-0.7 | 0.30 | 0.20 | 0.10 | 0.05 | 0.15 | remainder | |||||
| 6060 | 0.30-0.6 | 0.10-0.30 | 0.10 | 0.10 | 0.35-0.6 | 0.5 | 0.15 | 0.10 | 0.05 | 0.15 | remainder | |||||
| 6061 | 0.40-0.8 | 0.7 | 0.15-0.40 | 0.15 | 0.8-1.2 | 0.04-0.35 | 0.25 | 0.15 | 0.05 | 0.15 | remainder | |||||
| 6063 | 0.20-0.6 | 0.35 | 0.10 | 0.10 | 0.45-0.9 | 0.10 | 0.10 | 0.10 | 0.05 | 0.15 | remainder | |||||
| 6066 | 0.9-1.8 | 0.50 | 0.7-1.2 | 0.6-1.1 | 0.8-1.4 | 0.40 | 0.25 | 0.20 | 0.05 | 0.15 | remainder | |||||
| 6070 | 1.0-1.7 | 0.50 | 0.15-0.40 | 0.40-1.0 | 0.50-1.2 | 0.10 | 0.25 | 0.15 | 0.05 | 0.15 | remainder | |||||
| 6082 | 0.7-1.3 | 0.50 | 0.10 | 0.40-1.0 | 0.60-1.2 | 0.25 | 0.20 | 0.10 | 0.05 | 0.15 | remainder | |||||
| 6105 | 0.6-1.0 | 0.35 | 0.10 | 0.10 | 0.45-0.8 | 0.10 | 0.10 | 0.10 | 0.05 | 0.15 | remainder | |||||
| 6162 | 0.40-0.8 | 0.50 | 0.20 | 0.10 | 0.7-1.1 | 0.10 | 0.25 | 0.10 | 0.05 | 0.15 | remainder | |||||
| 6262 | 0.40-0.8 | 0.7 | 0.15-0.40 | 0.15 | 0.8-1.2 | 0.04-0.14 | 0.25 | 0.15 | 0.40-0.7 | 0.40-0.7 | 0.05 | 0.15 | remainder | |||
| 6351 | 0.7-1.3 | 0.50 | 0.10 | 0.40-0.8 | 0.40-0.8 | 0.20 | 0.20 | 0.05 | 0.15 | remainder | ||||||
| 6463 | 0.20-0.6 | 0.15 | 0.20 | 0.05 | 0.45-0.9 | 0.05 | 0.05 | 0.15 | remainder | |||||||
| 7005 | 0.35 | 0.40 | 0.10 | 0.20-0.7 | 1.0-1.8 | 0.06-0.20 | 4.0-5.0 | 0.01-0.06 | 0.08-0.20 | 0.05 | 0.15 | remainder | ||||
| 7072 | 0.7 Si+Fe | 0.10 | 0.10 | 0.10 | 0.8-1.3 | 0.05 | 0.15 | remainder | ||||||||
| 7075 | 0.40 | 0.50 | 1.2-2.0 | 0.30 | 2.1-2.9 | 0.18-0.28 | 5.1-6.1 | 0.20 | 0.05 | 0.15 | remainder | |||||
| 7116 | 0.15 | 0.30 | 0.50-1.1 | 0.05 | 0.8-1.4 | 4.2-5.2 | 0.05 | 0.05 | 0.03 | 0.05 | 0.15 | remainder | ||||
| 7129 | 0.15 | 0.30 | 0.50-0.9 | 0.10 | 1.3-2.0 | 0.10 | 4.2-5.2 | 0.05 | 0.05 | 0.03 | 0.05 | 0.15 | remainder | |||
| 7178 | 0.40 | 0.50 | 1.6-2.4 | 0.30 | 2.4-3.1 | 0.18-0.28 | 6.3-7.3 | 0.20 | 0.05 | 0.15 | remainder | |||||
| †Manganese plus chromium must be between 0.12-0.50%.††This column lists the limits that apply to all elements, whether a table column exists for them or not, for which no other limits are specified. | ||||||||||||||||