Any chemical element with valence electrons in two shells instead of only one. This structure gives them their outstanding ability to form ions containing more than one atom (complex ions, or coordination compounds), with a central atom or ion (often of a transition metal) surrounded by ligands in a regular arrangement. Theories on the bonding in these ions are still being refined. The elements in the periodic table from scandium to copper (atomic numbers 21–29), yttrium to silver (39–47), and lanthanum to gold (57–79, including the lanthanide series) are frequently designated the three main transition series. (Those in the actinide series and beyond, 89–111, also qualify.) All are metals, many of major economic or industrial importance (e.g., iron, gold, nickel, titanium). Most are dense, hard, and brittle, conduct heat and electricity well, have high melting points, and form alloys with each other and other metals. Their electronic structure lets them form compounds at various valences. Many of these compounds are coloured and paramagnetic (see paramagnetism) and (as do the metals themselves) often act as catalysts. Seealso rare earth metal.

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Any of a large class of chemical elements including scandium (atomic number 21), yttrium (39), and the 15 elements from 57 (lanthanum) to 71 (see lanthanides). The rare earths themselves are pure or mixed oxides of these metals, originally thought to be quite scarce; however, cerium, the most plentiful, is three times as abundant as lead in the Earth's crust. The metals never occur free, and the pure oxides never occur in minerals. These metals are similar chemically because their atomic structures are generally similar; all form compounds in which they have valence 3, including stable oxides, carbides, and borides.

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