tempering, process involving slow and moderate heating to increase the hardness and toughness of metals that have undergone previous heat treatment. Metals are usually hardened (see hardening) by being heated to high temperatures and quenched rapidly. This treatment causes brittleness, which is reduced by tempering. Steel is notably responsive to tempering, and makers of tools, weapons, armor, and other articles of steel have long had great skill in the process. Tempering is not necessary for such products as razors and files, in which hardness is sought but brittleness is not a serious disadvantage. Other products, e.g., swords and saws, require tempering for toughness. In the handicraft process of tempering, the condition of the steel during heating is judged by its color, caused by an oxide film. A desired hardness can be achieved by plunging the steel into a bath when it has cooled to the right shade of yellow or brown or blue. To secure a bath of the right temperature, various liquids are used, e.g., pure water, saltwater, oil, and molten metal. The process of softening steel that is harder than desired is called annealing. In modern mass production the processes of tempering are guided by scientific tests in place of the artisan's skill. Comparable to tempering is the process of hastening the cooling of a surface of a casting to increase the hardness of the part so "chilled."

Tempering is a heat treatment technique for metals and alloys. In steels, tempering is done to "toughen" the metal by transforming brittle martensite into bainite or a combination of ferrite and cementite. Precipitation hardening alloys, like many grades of aluminum and superalloys, are tempered to precipitate intermetallic particles which strengthen the metal.

The brittle martensite becomes strong and ductile after it is tempered. Carbon atoms were trapped in the austenite when it was rapidly cooled, typically by oil or water quenching, forming the martensite. The martensite becomes strong after being tempered because when reheated, the microstructure can rearrange and the carbon atoms can diffuse out of the distorted BCT structure. After the carbon diffuses, the result is nearly pure ferrite.

In metallurgy, there is always a tradeoff between ductility and brittleness. This delicate balance highlights many of the subtleties inherent to the tempering process. Precise control of time and temperature during the tempering process are critical to achieve a metal with well balanced mechanical properties.

Tempering in steel

Typically steel is heat treated in a multi-step process. First it is heated to create a solid solution of iron and carbon in a process called austenizing. Austenizing is followed by quenching to produce a martensitic microstructure. The steel is then tempered by heating between the ranges of 150°C-260°C (300°F-500°F) and 370°C-650°C (700°F-1200°F). Tempering in the range of 260°C-370°C (500°F-700°F) is sometimes avoided to reduce temper brittling. The steel is held at that temperature until the carbon trapped in the martensite diffuses to produce a chemical composition with the potential to create either bainite or pearlite (a crystal structure formed from a mixture of ferrite and cementite). It should be noted that when producing a truly bainitic or pearlitic steel the steel must be once again taken up to the austenite region (austenizing) and cooled slowly to a controlled temperature before being fully quenched to a low temperature. In bainitic steels, upper bainite or lower bainite may form depending on the length and temperature of the tempering process. It is thermodynamically impossible that the martensite will be totally converted during tempering, so a mixture of martensite, bainite, ferrite and cementite is often formed.

Tempering in precipitation hardened alloys

Before a precipitation hardened alloy can be tempered, it must be "solutionized". During solutionizing, the alloy is heated to dissolve and uniformly distribute alloying elements. The alloy is then quenched at a rate of cooling high enough to prevent the alloying elements from falling out of solution. The alloy is then tempered, by heating at temperatures lower than the solutionizing temperature.

During tempering, the alloying elements will diffuse through the alloy and react to form intermetallic compounds. The intermetallic compounds are not soluble in the alloy, and will precipitate, forming small particles. These particles strengthen the metal by impeding the movement of dislocations through the crystal structure of the alloy. Careful manipulation of tempering time and temperature allows the size and amount of precipitates to be controlled, thus tailoring the mechanical properties of the alloy.

Tempering in aluminium is also referred to as "aging". Artificially aged alloys are tempered at elevated temperature, while naturally aging alloys may be tempered at room temperature.

Alloy systems with a large number of alloying elements, like some superalloys may be subjected to several tempering operations. During each operation a different precipitate is formed, resulting in a large number of different precipitates that are difficult to drive back into solution. This phenomenon contributes to the high temperature strength of precipitation hardened superalloys.

Tempering in blacksmithing

The temperatures used in tempering are often too low to be gauged by the color of the workpiece. In this case, the blacksmith will heat the work piece for a known amount of time. Doing this ensures a certain degree of consistency in the tempering process from work piece to work piece. The cumulative effects of time and temperature can also be gauged by monitoring the color of the oxide film formed while tempering a well-polished blade.

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