Any of a group of pale yellow to light brown amorphous substances widely distributed in plants and used chiefly in tanning leather, dyeing fabric, and making ink. Their solutions are acid and have an astringent taste. They are isolated from oak bark, sumac, myrobalan (an Asian tree), and galls. Tannins give tea astringency, colour, and some flavour. Tannins are used industrially to clarify wine and beer, reduce viscosity of oil-well drilling mud, and prevent scale in boiler water; they have also had medical uses.
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Tannic acid, a commercial form of tannin, is a polyphenol. Its weak acidity (pKa around 10) is due to these phenol groups in the structure. Tannic acid is a basic ingredient in the chemical staining of wood. The tannic acid or tannin is already present in woods like oak, walnut, and mahogany. Tannic acid can be applied to woods low in tannin so chemical stains that require tannin content will react.
Tannic acid is the most common mordant for cellulose fibers such as cotton. Tannin is often combined with alum and/or iron. The tannin mordant should be done first as metal mordants combine well with the fiber-tannin complex.
The chemical formula for commercial tannic acid is often given as C76H52O46, but in fact it contains a mixture of related compounds. Its structure is based mainly on glucose esters of gallic acid. It is a yellow to light brown amorphous powder which is highly soluble in water; one gram dissolves in 0.35 mL of water.
It is said that soaking feet in tannic acid (or strong tea) can help prevent blisters.
But the use of tea for toughening skin appears to be apocryphal, in as much as tea is said to be incapable of tanning leather.
Tannic acid was once used as a treatment for strychnine poisoning in the late 19th and early 20th centuries.
The Merck Index, 9th edition, Merck & Co., Rahway, New Jersey, 1976.
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