spectrum, arrangement or display of light or other form of radiation separated according to wavelength, frequency, energy, or some other property. Beams of charged particles can be separated into a spectrum according to mass in a mass spectrometer (see mass spectrograph). Physicists often find it useful to separate a beam of particles into a spectrum according to their energy.

Continuous and Line Spectra

Dispersion, the separation of visible light into a spectrum, may be accomplished by means of a prism or a diffraction grating. Each different wavelength or frequency of visible light corresponds to a different color, so that the spectrum appears as a band of colors ranging from violet at the short-wavelength (high-frequency) end of the spectrum through indigo, blue, green, yellow, and orange, to red at the long-wavelength (low-frequency) end of the spectrum. In addition to visible light, other types of electromagnetic radiation may be spread into a spectrum according to frequency or wavelength.

The spectrum formed from white light contains all colors, or frequencies, and is known as a continuous spectrum. Continuous spectra are produced by all incandescent solids and liquids and by gases under high pressure. A gas under low pressure does not produce a continuous spectrum but instead produces a line spectrum, i.e., one composed of individual lines at specific frequencies characteristic of the gas, rather than a continuous band of all frequencies. If the gas is made incandescent by heat or an electric discharge, the resulting spectrum is a bright-line, or emission, spectrum, consisting of a series of bright lines against a dark background. A dark-line, or absorption, spectrum is the reverse of a bright-line spectrum; it is produced when white light containing all frequencies passes through a gas not hot enough to be incandescent. It consists of a series of dark lines superimposed on a continuous spectrum, each line corresponding to a frequency where a bright line would appear if the gas were incandescent. The Fraunhofer lines appearing in the spectrum of the sun are an example of a dark-line spectrum; they are caused by the absorption of certain frequencies of light by the cooler, outer layers of the solar atmosphere. Line spectra of either type are useful in chemical analysis, since they reveal the presence of particular elements. The instrument used for studying line spectra is the spectroscope.

The Quantum Explanation of Spectral Lines

The explanation for exact spectral lines for each substance was provided by the quantum theory. In his 1913 model of the hydrogen atom Niels Bohr showed that the observed series of lines could be explained by assuming that electrons are restricted to atomic orbits in which their orbital angular momentum is an integral multiple of the quantity h/2π, where h is Planck's constant. The integer multiple (e.g., 1, 2, 3 …) of h/2π is usually called the quantum number and represented by the symbol n.

When an electron changes from an orbit of higher energy (higher angular momentum) to one of lower energy, a photon of light energy is emitted whose frequency ν is related to the energy difference ΔE by the equation ν=ΔE/h. For hydrogen, the frequencies of the spectral lines are given by ν=cR (1/n_f²-1/n_i²) where c is the speed of light, R is the Rydberg constant, and n_f and n_i are the final and initial quantum numbers of the electron orbits (n_i is always greater than n_f). The series of spectral lines for which n_f=1 is known as the Lyman series; that for n_f=2 is the Balmer series; that for n_f=3 is the Paschen series; that for n_f=4 is the Brackett series; and that for n_f=5 is the Pfund series. The Bohr theory was not as successful in explaining the spectra of other substances, but later developments of the quantum theory showed that all aspects of atomic and molecular spectra can be explained quantitatively in terms of energy transitions between different allowed quantum states.

line spectrum: see spectrum.

flash spectrum: see chromosphere.

emission spectrum: see spectrum.

dark-line spectrum: see spectrum.

bright-line spectrum: see spectrum.

absorption spectrum: see spectrum.

Band of very faint light in the night sky. It is thought to be sunlight reflected from interplanetary dust grains lying mostly in the plane of the zodiac, or ecliptic. Seen in the west after twilight and in the east before dawn, it is most clearly visible in the tropics, where the ecliptic is approximately perpendicular to the horizon. In midnorthern latitudes it is best seen evenings in February and March and mornings in September and October (vice versa in midsouthern latitudes). The light can be followed visually to a point about 90° from the Sun. It continues to the region opposite the Sun, where a slight enhancement, the gegenschein, is visible.

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Distance traveled by light moving in a vacuum in one year, at its accepted speed of 186,282 mi/second (299,792 km/second). It equals about 5.9 trillion mi (9.5 trillion km), 63,240 astronomical units, or 0.307 parsec.

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Semiconductor diode that produces visible or infrared light when subjected to an electric current, as a result of electroluminescence. Visible-light LEDs are used in many electronic devices as indicator lamps (e.g., an on/off indicator) and, when arranged in a matrix, to spell out letters or numbers on alphanumeric displays. Infrared LEDs are used in optoelectronics (e.g., in auto-focus cameras and television remote controls) and as light sources in some long-range fibre-optic communications systems. LEDs are formed by the so-called III-V compound semiconductors related to gallium arsenide. They consume little power and are long-lasting and inexpensive.

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That portion of the electromagnetic spectrum visible to the human eye. It ranges from the red end to the violet end of the spectrum, with wavelengths from 700 to 400 nanometres and frequencies from 4.3 × 10¹⁴ to 7.5 × 10¹⁴ Hz. Like all electromagnetic radiation, it travels through empty space at a speed of about 186,000 mi/sec (300,000 km/sec). In the mid-19th century, light was described by James Clerk Maxwell in terms of electromagnetic waves, but 20th-century physicists showed that it exhibits properties of particles as well; its carrier particle is the photon. Light is the basis for the sense of sight and for the perception of colour. Seealso optics; wave-particle duality.

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Arrangement according to wavelength (or frequency) of electromagnetic radiation. The visible, “rainbow” spectrum is the portion of the electromagnetic spectrum that is visible as light to the human eye. Some sources emit only certain wavelengths and produce an emission spectrum of bright lines with dark spaces between. Such line spectra are characteristic of the elements that emit the radiation. A band spectrum consists of groups of wavelengths so close together that the lines appear to form a continuous band. Atoms and molecules absorb certain wavelengths and so remove them from a complete spectrum; the resulting absorption spectrum contains dark lines or bands at these wavelengths.

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