prism, in optics, a piece of translucent glass or crystal used to form a spectrum of light separated according to colors. Its cross section is usually triangular. The light becomes separated because different wavelengths or frequencies are refracted (bent) by different amounts as they enter the prism obliquely and again as they leave it (see refraction). The shorter wavelengths, toward the blue or violet end of the spectrum, are refracted by the greatest amount; the longer wavelengths, toward the red end, are refracted the least. The Nicol prism is a special type of prism made of calcite; it is used for polarization of light.

Nicol prism, optical device invented (1828) by William Nicol of Edinburgh. It consists essentially of a crystal of calcite, or Iceland spar, that is cut at an angle into two equal pieces and joined together again with Canada balsam. An ordinary beam of light entering the crystal undergoes double refraction, i.e., is split into two parts, each of which is affected in a different way. One of these parts, the so-called ordinary ray, undergoes total reflection at the Canada-balsam joint and is turned off from its course to pass out at one side of the crystal. The other ray, the extraordinary ray, passes on through the crystal. By means of this device a beam of light can be polarized (see polarization of light) or a beam of polarized light can be subjected to analysis. The principle involved has been applied to the microscope in the illumination of the field.

Piece of glass or other transparent material cut with precise angles and plane faces. Prisms are useful for analyzing and refracting light (see refraction). A triangular prism can separate white light into its constituent colours by refracting each different wavelength of light by a different amount. The longer wavelengths (those at the red end of the spectrum) are bent the least, the shorter ones (those at the violet end) the most. The result is the spectrum of visible light, or the rainbow. Prisms are used in certain kinds of spectroscopy and in various optical systems.

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