Definitions

# petroleum

[puh-troh-lee-uhm]
petroleum, oily, flammable liquid that occurs naturally in deposits, usually beneath the surface of the earth; it is also called crude oil. It consists principally of a mixture of hydrocarbons, with traces of various nitrogenous and sulfurous compounds.

## Origin and Natural Occurrence

During the past 600 million years incompletely decayed plant and animal remains have become buried under thick layers of rock. It is believed that petroleum consists of the remains of these organisms but it is the small microscopic plankton organism remains that are largely responsible for the relatively high organic carbon content of fine-grained sediments like the Chattanooga shale which are the principle source rocks for petroleum. Among the leading producers of petroleum are Saudi Arabia, Russia, the United States (chiefly Texas, California, Louisiana, Alaska, Oklahoma, and Kansas), Iran, China, Norway, Mexico, Venezuela, Iraq, Great Britain, the United Arab Emirates, Nigeria, and Kuwait. The largest known reserves are in the Middle East.

## Exploration and Drilling of Wells

Because of the subterranean origin of petroleum it must be extracted by means of wells. Until an exploratory well, or wildcat, has been dug, there is no sure way of knowing whether or not petroleum lies under a particular site. In order to reduce the number of exploratory wells drilled, scientific methods are used to pick the most promising sites. Sensitive instruments, such as the gravimeter, the magnetometer, and the seismograph, may be used to find subsurface rock formations that can hold crude oil. Drilling is a fairly complex and often risky process. Some wells must be dug several miles deep before petroleum deposits are reached. Many are now drilled offshore from platforms standing in the ocean bed. Usually the petroleum from a new well will come to the surface under its own pressure. Later the crude oil must be pumped out or forced to the surface by injecting water, air, natural gas, steam, carbon dioxide, or another substance into the deposits. Enhanced recovery techniques have increased the percentage of oil that can be extracted from a field.

## Composition and Refining of Petroleum

The physical properties and exact chemical composition of crude oil varies from one locality to another. The different hydrocarbon components of petroleum are dissolved natural gas, gasoline, benzine, naphtha, kerosene, diesel fuel and light heating oils, heavy heating oils, and finally tars of various weights (see tar and pitch). The crude oil is usually sent from a well to a refinery in pipelines (see under pipe) or tanker ships.

The hydrocarbon components are separated from each other by various refining processes. In a process called fractional distillation petroleum is heated and sent into a tower. The vapors of the different components condense on collectors at different heights in the tower. The separated fractions are then drawn from the collectors and further processed into various petroleum products. One of the many products of crude oil is a light substance with little color that is rich in gasoline. Another is a black tarry substance that is rich in asphalt.

As the lighter fractions, especially gasoline, are in the greatest demand, so-called cracking processes have been developed in which heat, pressure, and certain catalysts are used to break up the large molecules of heavy hydrocarbons into small molecules of light hydrocarbons. Some of the heavier fractions find eventual use as lubricating oils, paraffins, and highly refined medicinal substances such as petrolatum.

## History and Development of Petroleum

Petroleum has been known throughout historical time. It was used in mortar, for coating walls and boat hulls, and as a fire weapon in defensive warfare. Native Americans used it in magic and medicine and in making paints. Pioneers bought it from the Native Americans for medicinal use and called it Seneca oil and Genesee oil. In Europe it was scooped from streams or holes in the ground, and in the early 19th cent. small quantities were made from shale. In 1815 several streets in Prague were lighted with petroleum lamps.

The modern petroleum industry began in 1859, when the American oil pioneer E. L. Drake drilled a producing well on Oil Creek in Pennsylvania at a place that later became Titusville. Many wells were drilled in the region. Kerosene was the chief finished product, and kerosene lamps soon replaced whale oil lamps and candles in general use. Little use other than as lamp fuel was made of petroleum until the development of the gasoline engine and its application to automobiles, trucks, tractors, and airplanes. Today the world is heavily dependent on petroleum for motive power, lubrication, fuel, dyes, drugs, and many synthetics. The widespread use of petroleum has created serious environmental problems. The great quantities that are burned as fuels generate most of the air pollution in industrialized countries, and oil spilled from tankers and offshore wells has polluted oceans and coastlines.

## Bibliography

See K. K. Landes, Petroleum Geology of the United States (1970); S. Schackne and N. D. Drake, Oil for the World (2d ed. 1960); L. Mosley, Power Play: Oil in the Middle East (1973).

Subsurface reservoir of petroleum. The oil is always accompanied by water and often by natural gas; all are confined in porous rock. The natural gas, being lightest, occupies the top of the trap and is underlain by the oil and then the water. A layer of impervious rock, called the roof rock, prevents the escape of the petroleum. The part of the trap that is actually occupied by the oil and gas is called the petroleum reservoir.

or crude oil

Complex mixture of hydrocarbons derived from the geologic transformation and decomposition of plants and animals that lived hundreds of millions of years ago. As a technical term, petroleum encompasses the liquid (crude oil), gaseous (natural gas), and viscous or solid (bitumen, asphalt) forms of hydrocarbons that occur in the Earth, but the meaning is often restricted to the liquid oil form. Crude oil and natural gas are the most important primary fossil fuels. Asphalt has been used since ancient times to caulk ships and pave roads. In the mid 1800s petroleum began to replace whale oil in lamps, and the first well specifically to extract it was drilled in 1859. The development of the automobile gave petroleum a new role as the source of gasoline. Petroleum and its products have since been used as fuels for heating, for land, air, and sea transport, and for electric power generation and as petrochemical sources and lubricants. Crude oil and natural gas, produced mostly in Saudi Arabia, the U.S., and Russia, now account for about 60percnt of world energy consumption; the U.S. is by far the largest consumer. At present rates of consumption, the known supply will be exhausted by the mid 21st century. Petroleum is recovered from drilled wells, transported by pipeline or tanker ship to refineries, and there converted to fuels and petrochemicals.

Petroleum (L. petroleum, from Greek πετρέλαιον, lit. "rock oil", first used in the treatise De re metallica published in 1556 by the German mineralogist Georg Bauer, known as Georgius Agricola) or crude oil is a naturally occurring, flammable liquid found in rock formations in the Earth consisting of a complex mixture of hydrocarbons of various molecular weights, plus other organic compounds.

## Composition

The proportion of hydrocarbons in the mixture is highly variable and ranges from as much as 97% by weight in the lighter oils to as little as 50% in the heavier oils and bitumens.

The hydrocarbons in crude oil are mostly alkanes, cycloalkanes and various aromatic hydrocarbons while the other organic compounds contain nitrogen, oxygen and sulfur, and trace amounts of metals such as iron, nickel, copper and vanadium. The exact molecular composition varies widely from formation to formation but the proportion of chemical elements vary over fairly narrow limits as follows:

Composition by weight
Element Percent range
Carbon 83 to 87%
Hydrogen 10 to 14%
Nitrogen 0.1 to 2%
Oxygen 0.1 to 1.5%
Sulfur 0.5 to 6%
Metals less than 1000 ppm

Four different types of hydrocarbon molecules appear in crude oil. The relative percentage of each varies from oil to oil, determining the properties of each oil.

Composition by weight
Hydrocarbon Average Range
Paraffins 30% 15 to 60%
Naphthenes 49% 30 to 60%
Aromatics 15% 3 to 30%
Asphaltics 6% remainder

Crude oil varies greatly in appearance depending on its composition. It is usually black or dark brown (although it may be yellowish or even greenish). In the reservoir it is usually found in association with natural gas, which being lighter forms a gas cap over the petroleum, and saline water which being heavier generally floats underneath it. Crude oil may also be found in semi-solid form mixed with sand as in the Athabasca oil sands in Canada, where is usually referred to as crude bitumen. In Canada, bitumen is considered a sticky, tar-like form of crude oil which is so thick and heavy that it must be heated or diluted before it will flow. Venezuela also has large amounts of oil in the Orinoco oil sands, although the hydrocarbons trapped in them are more fluid than in Canada and are usually called extra heavy oil. These oil sands resources are called non-conventional oil to distinguish them from oil which can be extracted using traditional oil well methods. Between them, Canada and Venezuela contain an estimated of bitumen and extra-heavy oil, about twice the volume of the world's reserves of conventional oil.

Petroleum is used mostly, by volume, for producing fuel oil and gasoline (petrol), both important "primary energy" sources. 84% by volume of the hydrocarbons present in petroleum is converted into energy-rich fuels (petroleum-based fuels), including gasoline, diesel, jet, heating, and other fuel oils, and liquefied petroleum gas. The lighter grades of crude oil produce the best yields of these products, but as the world's reserves of light and medium oil are depleted, oil refineries are increasingly having to process heavy oil and bitumen, and use more complex and expensive methods to produce the products required. Because heavier crude oils have too much carbon and not enough hydrogen, these processes generally involve removing carbon from or adding hydrogen to the molecules, and using fluid catalytic cracking to convert the longer, more complex molecules in the oil to the shorter, simpler ones in the fuels.

Due to its high energy density, easy transportability and relative abundance, oil has become the world's most important source of energy since the mid-1950s. Petroleum is also the raw material for many chemical products, including pharmaceuticals, solvents, fertilizers, pesticides, and plastics; the 16% not used for energy production is converted into these other materials.

Petroleum is found in porous rock formations in the upper strata of some areas of the Earth's crust. There is also petroleum in oil sands (tar sands). Known reserves of petroleum are typically estimated at around 190 km3 (1.2 trillion (short scale) barrels) without oil sands, or 595 km3 (3.74 trillion barrels) with oil sands. Consumption is currently around per day, or 4.9 km3 per year. Because the energy return over energy invested (EROEI) ratio of oil is constantly falling (due to physical phenomena such as residual oil saturation, and the economic factor of rising marginal extraction costs), recoverable oil reserves are significantly less than total oil-in-place. At current consumption levels, and assuming that oil will be consumed only from reservoirs, known recoverable reserves would be gone around 2039, potentially leading to a global energy crisis. However, there are factors which may extend or reduce this estimate, including the rapidly increasing demand for petroleum in China, India, and other developing nations; new discoveries; energy conservation and use of alternative energy sources; and new economically viable exploitation of non-conventional oil sources.

## Chemistry

Petroleum is a mixture of a very large number of different hydrocarbons; the most commonly found molecules are alkanes (linear or branched), cycloalkanes, aromatic hydrocarbons, or more complicated chemicals like asphaltenes. Each petroleum variety has a unique mix of molecules, which define its physical and chemical properties, like color and viscosity.

The alkanes, also known as paraffins, are saturated hydrocarbons with straight or branched chains which contain only carbon and hydrogen and have the general formula CnH2n+2 They generally have from 5 to 40 carbon atoms per molecule, although trace amounts of shorter or longer molecules may be present in the mixture.

The alkanes from pentane (C5H12) to octane (C8H18) are refined into gasoline (petrol), the ones from nonane (C9H20) to hexadecane (C16H34) into diesel fuel and kerosene (primary component of many types of jet fuel), and the ones from hexadecane upwards into fuel oil and lubricating oil. At the heavier end of the range, paraffin wax is an alkane with approximately 25 carbon atoms, while asphalt has 35 and up, although these are usually cracked by modern refineries into more valuable products. Any shorter hydrocarbons are considered natural gas or natural gas liquids.

The cycloalkanes, also known as napthenes, are saturated hydrocarbons which have one or more carbon rings to which hydrogen atoms are attached according to the formula CnH2n. Cycloalkanes have similar properties to alkanes but have higher boiling points.

The aromatic hydrocarbons are unsaturated hydrocarbons which have one or more planar six-carbon rings called benzene rings, to which hydrogen atoms are attached with the formula CnHn. They tend to burn with a sooty flame, and many have a sweet aroma. Some are carcinogenic.

These different molecules are separated by fractional distillation at an oil refinery to produce gasoline, jet fuel, kerosene, and other hydrocarbons. For example 2,2,4-trimethylpentane (isooctane), widely used in gasoline, has a chemical formula of C8H18 and it reacts with oxygen exothermically:

$2mathrm\left\{C\right\}_8 mathrm\left\{H\right\}_\left\{18\left(l\right)\right\} + 25mathrm\left\{O\right\}_\left\{2\left(g\right)\right\} rightarrow ; 16mathrm\left\{CO\right\}_\left\{2\left(g\right)\right\} + 18mathrm\left\{H\right\}_2 mathrm\left\{O\right\}_\left\{\left(l\right)\right\} + 10.86 mathrm\left\{MJ\right\}$

The amount of various molecules in an oil sample can be determined in laboratory. The molecules are typically extracted in a solvent, then separated in a gas chromatograph, and finally determined with a suitable detector, such as a flame ionization detector or a mass spectrometer.

Incomplete combustion of petroleum or gasoline results in production of toxic byproducts. Too little oxygen results in carbon monoxide. Due to the high temperatures and high pressures involved, exhaust gases from gasoline combustion in car engines usually include nitrogen oxides which are responsible for creation of photochemical smog.

## Formation

Geologists view crude oil and natural gas as the product of compression and heating of ancient organic materials (i.e. kerogen) over geological time. Formation of petroleum occurs from hydrocarbon pyrolysis, in a variety of mostly endothermic reactions at high temperature and/or pressure. Today's oil formed from the preserved remains of prehistoric zooplankton and algae, which had settled to a sea or lake bottom in large quantities under anoxic conditions (the remains of prehistoric terrestrial plants, on the other hand, tended to form coal). Over geological time the organic matter mixed with mud, and was buried under heavy layers of sediment resulting in high levels of heat and pressure (known as diagenesis). This caused the organic matter to chemically change, first into a waxy material known as kerogen which is found in various oil shales around the world, and then with more heat into liquid and gaseous hydrocarbons in a process known as catagenesis.

Geologists often refer to the temperature range in which oil forms as an "oil window—below the minimum temperature oil remains trapped in the form of kerogen, and above the maximum temperature the oil is converted to natural gas through the process of thermal cracking. Although this temperature range is found at different depths below the surface throughout the world, a typical depth for the oil window is 4–6 km. Sometimes, oil which is formed at extreme depths may migrate and become trapped at much shallower depths than where it was formed. The Athabasca Oil Sands is one example of this.

### Crude oil reservoirs

Three conditions must be present for oil reservoirs to form: a source rock rich in hydrocarbon material buried deep enough for subterranean heat to cook it into oil; a porous and permeable reservoir rock for it to accumulate in; and a cap rock (seal) or other mechanism that prevents it from escaping to the surface. Within these reservoirs, fluids will typically organize themselves like a three-layer cake with a layer of water below the oil layer and a layer of gas above it, although the different layers vary in size between reservoirs.

Because most hydrocarbons are lighter than rock or water, they often migrate upward through adjacent rock layers until either reaching the surface or becoming trapped within porous rocks (known as reservoirs) by impermeable rocks above. However, the process is influenced by underground water flows, causing oil to migrate hundreds of kilometres horizontally or even short distances downward before becoming trapped in a reservoir. When hydrocarbons are concentrated in a trap, an oil field forms, from which the liquid can be extracted by drilling and pumping.

The reactions that produce oil and natural gas are often modeled as first order breakdown reactions, where hydrocarbons are broken down to oil and natural gas by a set of parallel reactions, and oil eventually breaks down to natural gas by another set of reactions. The latter set is regularly used in petrochemical plants and oil refineries.

### Non-conventional oil reservoirs

Oil-eating bacteria biodegrades oil that has escaped to the surface. Oil sands are reservoirs of partially biodegraded oil still in the process of escaping and being biodegraded, but they contain so much migrating oil that, although most of it has escaped, vast amounts are still present—more than can be found in conventional oil reservoirs. The lighter fractions of the crude oil are destroyed first, resulting in reservoirs containing an extremely heavy form of crude oil, called crude bitumen in Canada, or extra-heavy crude oil in Venezuela. These two countries have the world's largest deposits of oil sands.

On the other hand, oil shales are source rocks that have not been exposed to heat or pressure long enough to convert their trapped hydrocarbons into crude oil. Technically speaking, oil shales are not really shales and do not really contain oil, but are usually relatively hard rocks called marls containing a waxy substance called kerogen. The kerogen trapped in the rock can be converted into crude oil using heat and pressure to simulate natural processes. The method has been known for centuries and was patented in 1694 under British Crown Patent No. 330 covering, "A way to extract and make great quantityes of pitch, tarr, and oyle out of a sort of stone." Although oil shales are found in many countries, the United States has the world's largest deposits.

### Abiogenic origin

A number of geologists in Russia adhere to the abiogenic petroleum origin hypothesis and maintain that hydrocarbons of purely inorganic origin exist within Earth's interior. Astronomer Thomas Gold championed the theory in the Western world by supporting the work done by Nikolai Kudryavtsev in the 1950s. It is currently supported primarily by Kenney and Krayushkin.

The abiogenic origin hypothesis lacks scientific support, and all current oil reserves have biological origin. It also has not been successfully utilized in uncovering oil deposits by geologists.

## Classification

The petroleum industry generally classifies crude oil by the geographic location it is produced in (e.g. West Texas, Brent, or Oman), its API gravity (an oil industry measure of density), and by its sulfur content. Crude oil may be considered light if it has low density or heavy if it has high density; and it may be referred to as sweet if it contains relatively little sulfur or sour if it contains substantial amounts of sulfur.

The geographic location is important because it affects transportation costs to the refinery. Light crude oil is more desirable than heavy oil since it produces a higher yield of gasoline, while sweet oil commands a higher price than sour oil because it has fewer environmental problems and requires less refining to meet sulfur standards imposed on fuels in consuming countries. Each crude oil has unique molecular characteristics which are understood by the use of crude oil assay analysis in petroleum laboratories.

Barrels from an area in which the crude oil's molecular characteristics have been determined and the oil has been classified are used as pricing references throughout the world. Some of the common reference crudes are:

There are declining amounts of these benchmark oils being produced each year, so other oils are more commonly what is actually delivered. While the reference price may be for West Texas Intermediate delivered at Cushing, the actual oil being traded may be a discounted Canadian heavy oil delivered at Hardisty, Alberta, and for a Brent Blend delivered at the Shetlands, it may be a Russian Export Blend delivered at the port of Primorsk.

## Petroleum industry

The petroleum industry is involved in the global processes of exploration, extraction, refining, transporting (often with oil tankers and pipelines), and marketing petroleum products. The largest volume products of the industry are fuel oil and gasoline (petrol). Petroleum is also the raw material for many chemical products, including pharmaceuticals, solvents, fertilizers, pesticides, and plastics. The industry is usually divided into three major components: upstream, midstream and downstream. Midstream operations are usually included in the downstream category.

Petroleum is vital to many industries, and is of importance to the maintenance of industrialized civilization itself, and thus is critical concern to many nations. Oil accounts for a large percentage of the world’s energy consumption, ranging from a low of 32% for Europe and Asia, up to a high of 53% for the Middle East. Other geographic regions’ consumption patterns are as follows: South and Central America (44%), Africa (41%), and North America (40%). The world at large consumes 30 billion barrels (4.8 km³) of oil per year, and the top oil consumers largely consist of developed nations. In fact, 24% of the oil consumed in 2004 went to the United States alone. The production, distribution, refining, and retailing of petroleum taken as a whole represent the single largest industry in terms of dollar value on earth.

## Petroleum exploration

### Extraction

The most common method of obtaining petroleum is extracting it from oil wells found in oil fields. With improved technologies and higher demand for hydrocarbons various methods are applied in petroleum exploration and development to optimize the recovery of oil and gas (Enhanced Oil Recovery, EOR). Primary recovery methods are used to extract oil that is brought to the surface by underground pressure, and can generally recover about 20% of the oil present. The natural pressure can come from several different sources; where it is provided by an underlying water layer it is called a water drive reservoir and where it is from the gas cap above it is called gas drive. After the reservoir pressure has depleted to the point that the oil is no longer brought to the surface, secondary recovery methods draw another 5 to 10% of the oil in the well to the surface. In a water drive oil field, water can be injected into the water layer below the oil, and in a gas drive field it can be injected into the gas cap above to repressurize the reservoir. Finally, when secondary oil recovery methods are no longer viable, tertiary recovery methods reduce the viscosity of the oil in order to bring more to the surface. These may involve the injection of heat, vapor, surfactants, solvents, or miscible gases as in carbon dioxide flooding.

### Alternative methods

During the oil price increases since 2003, alternative methods of producing oil gained importance. The most widely known alternatives involve extracting oil from sources such as oil shale or tar sands. These resources exist in large quantities; however, extracting the oil at low cost without excessively harming the environment remains a challenge.

It is also possible to chemically transform methane or coal into the various hydrocarbons found in oil. The best-known such method is the Fischer-Tropsch process. It was a concept pioneered during the 1920s in Germany to extract oil from coal and became central to Nazi Germany's war efforts when imports of petroleum were restricted due to war. It was known as Ersatz (English:"substitute") oil, and accounted for nearly half the total oil used in WWII by Germany. However, the process was used only as a last resort as naturally occurring oil was much cheaper. As crude oil prices increase, the cost of coal to oil conversion becomes comparatively cheaper. The method involves converting high ash coal into synthetic oil in a multi-stage process.

Currently, two companies have commercialised their Fischer-Tropsch technology. Shell Oil in Bintulu, Malaysia, uses natural gas as a feedstock, and produces primarily low-sulfur diesel fuels. Sasol in South Africa uses coal as a feedstock, and produces a variety of synthetic petroleum products.

The process is today used in South Africa to produce most of the country's diesel fuel from coal by the company Sasol. The process was used in South Africa to meet its energy needs during its isolation under Apartheid. This process produces low sulfur diesel fuel but also produces large amounts of greenhouse gases.

An alternative method of converting coal into petroleum is the Karrick process, which was pioneered in the 1930s in the United States. It uses low temperatures in the absence of ambient air, to distill the short-chain hydrocarbons out of coal instead of petroleum.

Oil shale can also be used to produce oil, either through mining and processing, or in more modern methods, with in-situ thermal conversion.

Conventional crude can be extracted from unconventional reservoirs, such as the Bakken Formation. The formation is about two miles (3 km) underground but only a few meters thick, stretching across hundreds of thousands of square miles. It further has very poor extraction characteristics. Recovery at Elm Coulee has involved extensive use of horizontal drilling, solvents, and proppants.

More recently explored is thermal depolymerization (TDP), a process for the reduction of complex organic materials into light crude oil. Using pressure and heat, long chain polymers of hydrogen, oxygen, and carbon decompose into short-chain hydrocarbons. This mimics the natural geological processes thought to be involved in the production of fossil fuels. In theory, thermal depolymerization can convert any organic waste into petroleum substitutes.

## History

Petroleum, in one form or another, is not a recent discovery. More than four thousand years ago, according to Herodotus and confirmed by Diodorus Siculus, asphalt was employed in the construction of the walls and towers of Babylon; there were oil pits near Ardericca (near Babylon), and a pitch spring on Zacynthus. Great quantities of it were found on the banks of the river Issus, one of the tributaries of the Euphrates. Ancient Persian tablets indicate the medicinal and lighting uses of petroleum in the upper levels of their society.

Oil was exploited in the Roman province of Dacia, now in Romania, where it was called picula.

The earliest known oil wells were drilled in China in 347 CE or earlier. They had depths of up to about and were drilled using bits attached to bamboo poles. The oil was burned to evaporate brine and produce salt. By the 10th century, extensive bamboo pipelines connected oil wells with salt springs. The ancient records of China and Japan are said to contain many allusions to the use of natural gas for lighting and heating. Petroleum was known as burning water in Japan in the 7th century. In his book Dream Pool Essays written in 1088, the polymathic scientist and statesman Shen Kuo of the Song Dynasty coined the word 石油 (Shíyóu, literally "rock oil") for petroleum, which remains the term used in contemporary Chinese.

The first streets of Baghdad were paved with tar, derived from petroleum that became accessible from natural fields in the region. In the 9th century, oil fields were exploited in the area around modern Baku, Azerbaijan, to produce naphtha. These fields were described by the Arab geographer Abu al-Hasan 'Alī al-Mas'ūdī in the 10th century, and by Marco Polo in the 13th century, who described the output of those wells as hundreds of shiploads. Petroleum was distilled by the Persian alchemist Muhammad ibn Zakarīya Rāzi (Rhazes) in the 9th century, producing chemicals such as kerosene in the alembic (al-ambiq), and which was mainly used for kerosene lamps. Arab and Persian chemists also distilled crude oil in order to produce flammable products for military purposes. Through Islamic Spain, distillation became available in Western Europe by the 12th century. It has also been present in Romania since the 13th century, being recorded as păcură.

The earliest mention of petroleum in the Americas occurs in Sir Walter Raleigh's account of the Trinidad Pitch Lake in 1595; whilst thirty-seven years later, the account of a visit of a Franciscan, Joseph de la Roche d'Allion, to the oil springs of New York was published in Sagard's Histoire du Canada. A Russian traveller, Peter Kalm, in his work on America published in 1748 showed on a map the oil springs of Pennsylvania.

In 1710 or 1711 (sources vary) the Russian-born Swiss physician and Greek teacher Eyrini d’Eyrinis (also spelled as Eirini d'Eirinis) discovered asphaltum at Val-de-Travers, (Neuchâtel). He established a bitumen mine de la Presta there in 1719 that operated until 1986.

Oil sands were mined from 1745 in Merkwiller-Pechelbronn, Alsace under the direction of Louis Pierre Ancillon de la Sablonnière, by special appointment of Louis XV. The Pechelbronn oil field was active until 1970, and was the birth place of companies like Antar and Schlumberger. The first modern refinery was built there in 1857.

The modern history of petroleum began in 1846 with the discovery of the process of refining kerosene from coal by Nova Scotian Abraham Pineo Gesner. Ignacy Łukasiewicz improved Gesner's method to develop a means of refining kerosene from the more readily available "rock oil" ("petr-oleum") seeps in 1852 and the first rock oil mine was built in Bóbrka, near Krosno in Galicia in the following year. In 1854, Benjamin Silliman, a science professor at Yale University in New Haven, was the first to fractionate petroleum by distillation. These discoveries rapidly spread around the world, and Meerzoeff built the first Russian refinery in the mature oil fields at Baku in 1861. At that time Baku produced about 90% of the world's oil.

The first commercial oil well in Romania was drilled in 1857 at Bend, North of Bucharest. The first oil well in North America was in Oil Springs, Ontario, Canada in 1858, dug by James Miller Williams. The US petroleum industry began with Edwin Drake's drilling of a oil well in 1859, on Oil Creek near Titusville, Pennsylvania, for the Seneca Oil Company (originally yielding , by the end of the year output was at the rate of ). The industry grew through the 1800s, driven by the demand for kerosene and oil lamps. It became a major national concern in the early part of the 20th century; the introduction of the internal combustion engine provided a demand that has largely sustained the industry to this day. Early "local" finds like those in Pennsylvania and Ontario were quickly outpaced by demand, leading to "oil booms" in Texas, Oklahoma, and California.

Early production of crude petroleum in the United States:

• 1859:
• 1869:
• 1879:
• 1889:
• 1899:
• 1906:

By 1910, significant oil fields had been discovered in Canada (specifically, in the province of Ontario), the Dutch East Indies (1885, in Sumatra), Iran (1908, in Masjed Soleiman), Peru, Venezuela, and Mexico, and were being developed at an industrial level.

Even until the mid-1950s, coal was still the world's foremost fuel, but oil quickly took over. Following the 1973 energy crisis and the 1979 energy crisis, there was significant media coverage of oil supply levels. This brought to light the concern that oil is a limited resource that will eventually run out, at least as an economically viable energy source. At the time, the most common and popular predictions were quite dire. However, a period of increased production and reduced demand caused an oil glut in the 1980s.

Today, about 90% of vehicular fuel needs are met by oil. Petroleum also makes up 40% of total energy consumption in the United States, but is responsible for only 2% of electricity generation. Petroleum's worth as a portable, dense energy source powering the vast majority of vehicles and as the base of many industrial chemicals makes it one of the world's most important commodities. Access to it was a major factor in several military conflicts of the late twentieth and early twenty-first centuries, including World War II and the Persian Gulf Wars (Iran–Iraq War, Operation Desert Storm, and the Iraq War). The top three oil producing countries are Saudi Arabia, Russia, and the United States. About 80% of the world's readily accessible reserves are located in the Middle East, with 62.5% coming from the Arab 5: Saudi Arabia (12.5%), UAE, Iraq, Qatar and Kuwait. However, with today's oil prices, Venezuela has larger reserves than Saudi Arabia due to crude reserves derived from bitumen.

## Uses

The chemical structure of petroleum is composed of hydrocarbon chains of different lengths. Because of this, petroleum may be taken to oil refineries and the hydrocarbon chemicals separated by distillation and treated by other chemical processes, to be used for a variety of purposes. See Petroleum products.

### Fuels

The most common distillations of petroleum are fuels.

Fuels include:

### Other derivatives

Certain types of resultant hydrocarbons may be mixed with other non-hydrocarbons, to create other end products:

## Environmental effects

The presence of oil has significant social and environmental impacts, from accidents and routine activities such as seismic exploration, drilling, and generation of polluting wastes not produced by other alternative energies.

### Extraction

Oil extraction is costly and sometimes environmentally damaging, although Dr. John Hunt of the Woods Hole Oceanographic Institution pointed out in a 1981 paper that over 70% of the reserves in the world are associated with visible macroseepages, and many oil fields are found due to natural seeps. Offshore exploration and extraction of oil disturbs the surrounding marine environment. Extraction may involve dredging, which stirs up the seabed, killing the sea plants that marine creatures need to survive. But at the same time, offshore oil platforms also form micro-habitats for marine creatures.

### Oil spills

Crude oil and refined fuel spills from tanker ship accidents have damaged natural ecosystems in Alaska, the Galapagos Islands, France and many other places.

The quantity of oil spilled during accidents has ranged from a few hundred tons to several hundred thousand tons (Atlantic Empress, Amoco Cadiz...). Smaller spills have already proven to have a great impact on ecosystems, such as the Exxon Valdez oil spill

Oil spills at sea are generally much more damaging than those on land, since they can spread for hundreds of nautical miles in a thin oil slick which can cover beaches with a thin coating of oil. This can kill sea birds, mammals, shellfish and other organisms it coats. Oil spills on land are more readily containable if a makeshift earth dam can be rapidly bulldozed around the spill site before most of the oil escapes, and land animals can avoid the oil more easily.

Control of oil spills is difficult, requires ad hoc methods, and often a large amount of manpower (picture). The dropping of bombs and incendiary devices from aircraft on the Torrey Canyon wreck produced poor results; modern techniques would include pumping the oil from the wreck, like in the Prestige oil spill or the Erika oil spill.

### Global warming

Burning oil releases carbon dioxide (CO2) into the atmosphere, which is generally acknowledged as contributing to global warming. Per joule, oil produces 15% less CO2 than coal, but 30% more than natural gas. However, the unique role of oil as the main source of transportation fuel makes reducing its CO2 emissions a difficult problem. While large power plants can, in theory, eliminate their CO2 emissions by techniques such as carbon sequestering or even use them to increase oil production through enhanced oil recovery techniques, these amelioration strategies do not generally work for individual vehicles.

### Whales

It has been argued that the advent of petroleum-refined kerosene saved the great cetaceans from extinction by providing a cheap substitute for whale oil, thus eliminating the economic imperative for whaling.

## Alternatives to petroleum

In the United States in 2007 about 70% of petroleum was used for transportation (e.g. gasoline, diesel, jet fuel), 24% by industry (e.g. production of plastics), 5% for residential and commercial uses, and 2% for electricity production. Outside of the US, a higher proportion of petroleum tends to be used for electricity.

### Alternatives to petroleum-based vehicle fuels

Alternative propulsion refers to both:

Currently, cars can be classified into the following groups:

### Alternatives to using oil in industry

Biological feedstocks do exist for industrial uses such as plastic production. If the price of petroleum remains high, biological alternatives are likely to be developed for industrial uses.

### Alternatives to burning petroleum for electricity

In oil producing countries with little refinery capacity, oil is sometimes burned to produce electricity. Renewable energy technologies such as solar power, wind power, hydroelectricity, micro hydro, biomass and biofuels could be used to replace these generators.

## Future of petroleum production

The future of petroleum as a fuel remains somewhat controversial. USA Today news reported in 2004 that there were 40 years of petroleum left in the ground. Some argue that because the total amount of petroleum is finite, the dire predictions of the 1970s have merely been postponed. Others claim that technology will continue to allow for the production of cheap hydrocarbons and that the earth has vast sources of unconventional petroleum reserves in the form of tar sands, bitumen fields and oil shale that will allow for petroleum use to continue in the future, with both the Canadian tar sands and United States shale oil deposits representing potential reserves matching existing liquid petroleum deposits worldwide.

### Hubbert peak theory

The Hubbert peak theory (also known as peak oil) posits that future petroleum production (whether for individual oil wells, entire oil fields, whole countries, or worldwide production) will eventually peak and then decline at a similar rate to the rate of increase before the peak as these reserves are exhausted. It also suggests a method to calculate the timing of this peak, based on past production rates, the observed peak of past discovery rates, and proven oil reserves. The peak of oil discoveries was in 1965, and oil production per year has surpassed oil discoveries every year since 1980.

In 1956, M. King Hubbert correctly predicted US oil production would peak around 1971. When this occurred and the US began losing its excess production capacity, OPEC gained the ability to manipulate oil prices, leading to the 1973 and 1979 oil crises. Since then, most other countries have also peaked. China has confirmed that two of its largest producing regions are in decline, and Mexico's national oil company, Pemex, has announced that Cantarell Field, one of the world's largest offshore fields, was expected to peak in 2006, and then decline 14% per annum.

Controversy surrounds predictions of the timing of the global peak, as these predictions are dependent on the past production and discovery data used in the calculation as well as how unconventional reserves are considered. Supergiant fields have been discovered in the past decade, such as Azadegan, Carioca/Sugar Loaf, Tupi, Jupiter, Ferdows/Mounds/Zagheh, Tahe, Jidong Nanpu/Bohai Bay, West Kamchatka, and Kashagan, as well as tremendous reservoir growth from places like the Bakken and massive syncrude operations in Venezuela and Canada. However, while past understanding of total oil reserves changed with newer scientific understanding of petroleum geology, current estimates of total oil reserves have been in general agreement since the 1960s. Further, predictions regarding the timing of the peak are highly dependent on the past production and discovery data used in the calculation.

It is difficult to predict the oil peak in any given region, due to the lack of transparency in accounting of global oil reserves. Based on available production data, proponents have previously predicted the peak for the world to be in years 1989, 1995, or 1995-2000. Some of these predictions date from before the recession of the early 1980s, and the consequent reduction in global consumption, the effect of which was to delay the date of any peak by several years. Just as the 1971 U.S. peak in oil production was only clearly recognized after the fact, a peak in world production will be difficult to discern until production clearly drops off.

## Petroleum by country

### Consumption

There are two main ways to measure the oil consumption rates of countries: by population or by gross domestic product (GDP). This metric is important in the global debate over oil consumption/energy consumption/climate change because it takes social and economic considerations into account when scoring countries on their oil consumption/energy consumption/climate change goals. Nations such as China and India with large populations tend to promote the use of population based metrics, while nations with large economies such as the United States would tend to promote the GDP based metric.

Selected Nations GDP-to-consumption ratio
(US\$1000/(barrel/year))
Switzerland 3.75
United Kingdom 3.34
Norway 3.31
Austria 2.96
France 2.65
Germany 2.89
Sweden 2.71
Italy 2.57
European Union 2.52
DRC 2.4
Japan 2.34
Australia 2.21
Spain 1.96
Poland 1.87
United States 1.65
Belgium 1.59
World 1.47
Turkey 1.39
Mexico 1.07
Ethiopia 1.04
South Korea 1.00
Philippines 1.00
Brazil 0.99
Republic of China (Taiwan) 0.98
China 0.94
Nigeria 0.94
Pakistan 0.93
Myanmar 0.89
India 0.86
Russia 0.84
Indonesia 0.71
Vietnam 0.61
Thailand 0.53
Saudi Arabia 0.46
Egypt 0.41
Singapore 0.40
Iran 0.35

Selected Nations Per capita energy consumption, oil equivalent
(barrel/person/year)
DRC 0.13
Ethiopia 0.37
Myanmar 0.73
Pakistan 1.95
Nigeria 2.17
India 2.18
Vietnam 2.70
Philippines 3.77
Indonesia 4.63
China 4.96
Egypt 7.48
Turkey 9.85
Brazil 11.67
Poland 11.67
World 12.55
Thailand 13.86
Russia 17.66
Mexico 18.07
Iran 21.56
European Union 29.70
United Kingdom 30.18
Germany 32.31
France 32.43
Italy 32.43
Austria 34.01
Spain 35.18
Switzerland 34.64
Sweden 34.68
Republic of China (Taiwan) 41.68
Japan 42.01
Australia 42.22
South Korea 43.84
Norway 52.06
Belgium 61.52
United States 68.81
Saudi Arabia 75.08
Singapore 178.45

(Note: The figure for Singapore is skewed because of its small
population compared with its large oil refining capacity.
Most of this oil is sent to other countries.)

### Production

In petroleum industry parlance, production refers to the quantity of crude extracted from reserves, not the literal creation of the product.

# Producing Nation 103bbl/d (2006) 103bbl/d (2007)
1

Saudi Arabia (OPEC) 10,665 10,234
2

Russia 1 9,677 9,876
3

United States 1 8,331 8,481
4

Iran (OPEC) 4,148 4,043
5

China 3,845 3,901
6

Mexico 1 3,707 3,501
7

8

United Arab Emirates (OPEC) 2,945 2,948
9

Venezuela (OPEC) 1 2,803 2,667
10

Kuwait (OPEC) 2,675 2,613
11

Norway 1 2,786 2,565
12

Nigeria (OPEC) 2,443 2,352
13

Brazil 2,166 2,279
14

Algeria (OPEC) 2,122 2,173
15

Iraq (OPEC) 3 2,008 2,094
16

Libya (OPEC) 1,809 1,845
17

Angola (OPEC) 1,435 1,769
18

United Kingdom 1,689 1,690
19

Kazakhstan 1,388 1,445
20

Qatar (OPEC) 1,141 1,136
21

Indonesia 1,102 1,044
22

India 854 881
23

Azerbaijan 648 850
24

Argentina 802 791
25

Oman 743 714
26

Malaysia 729 703
27

Egypt 667 664
28

Australia 552 595
29

Colombia 544 543
30

31

Sudan 380 466
32

Syria 449 446
33

Equatorial Guinea 386 400
34

Yemen 377 361
35

Vietnam 362 352
36

Thailand 334 349
37

Denmark 344 314
38

Congo 247 250
39

Gabon 237 244
40

South Africa 204 199

1 Peak production of conventional oil already passed in this state

2 Although Canadian conventional oil production is declining, total oil production is increasing as oil sands production grows. If oil sands are included, it has the world's second largest oil reserves after Saudi Arabia.

3 Though still a member, Iraq has not been included in production figures since 1998

### Export

In order of net exports in 2006 in thousand bbl/d and thousand /d:

# Exporting Nation (2006) (103bbl/d) (103m3/d)
1

Saudi Arabia (OPEC) 8,651 1,376
2

Russia 1 6,565 1,044
3

Norway 1 2,542 404
4

Iran (OPEC) 2,519 401
5

United Arab Emirates (OPEC) 2,515 400
6

Venezuela (OPEC) 1 2,203 350
7

Kuwait (OPEC) 2,150 342
8

Nigeria (OPEC) 2,146 341
9

Algeria (OPEC) 1 1,847 297
10

Mexico 1 1,676 266
11

Libya (OPEC) 1 1,525 242
12

Iraq (OPEC) 1,438 229
13

Angola (OPEC) 1,363 217
14

Kazakhstan 1,114 177
15

1 peak production already passed in this state

2 Canadian statistics are complicated by the fact it is both an importer and exporter of crude oil, and refines large amounts of oil for the U.S. market. It is the leading source of U.S. imports of oil and products, averaging 2.5 MMbbl/d in August 2007.

Total world production/consumption (as of 2005) is approximately .

### Consumption

In order of amount consumed in 2006 in thousand bbl/d and thousand /d:

# Consuming Nation 2006 (103bbl/day) (103m3/day)
1

United States 1 20,588 3,273
2

China 7,274 1,157
3

Japan 2 5,222 830
4

Russia 1 3,103 493
5

Germany 2 2,630 418
6

India 2 2,534 403
7

8

Brazil 2,183 347
9

South Korea 2 2,157 343
10

Saudi Arabia (OPEC) 2,068 329
11

Mexico 1 2,030 323
12

France 2 1,972 314
13

United Kingdom 1 1,816 289
14

Italy 2 1,709 272
15

Iran (OPEC) 1,627 259

1 peak production of oil already passed in this state

2 This country is not a major oil producer

### Import

In order of net imports in 2006 in thousand bbl/d and thousand /d:

# Importing Nation (2006) (103bbl/day) (103m3/day)
1

United States 1 12,220 1,943
2

Japan 5,097 810
3

China 2 3,438 547
4

Germany 2,483 395
5

South Korea 2,150 342
6

France 1,893 301
7

India 1,687 268
8

Italy 1,558 248
9

Spain 1,555 247
10

Republic of China (Taiwan) 942 150
11

Netherlands 936 149
12

Singapore 787 125
13

Thailand 606 96
14

Turkey 576 92
15

Belgium 546 87

1 peak production of oil already passed in this state

2 Major oil producer whose production is still increasing

### Non-producing consumers

Countries whose oil production is 10% or less of their consumption.

# Consuming Nation (bbl/day) (m³/day)
1

Japan 5,578,000 886,831
2

Germany 2,677,000 425,609
3

South Korea 2,061,000 327,673
4

France 2,060,000 327,514
5

Italy 1,874,000 297,942
6

Spain 1,537,000 244,363
7

Netherlands 946,700 150,513
Source : CIA World Factbook