zinc oxide, chemical compound, ZnO, that is nearly insoluble in water but soluble in acids or alkalies. It occurs as white hexagonal crystals or a white powder commonly known as zinc white. Zinc white is used as a pigment in paints; less opaque than lithopone, it remains white when exposed to hydrogen sulfide or ultraviolet light. It is also used as a filler for rubber goods and in coatings for paper. Chinese white is a special grade of zinc white used in artists' pigments. Because it absorbs ultraviolet light, zinc oxide can be used in ointments, creams, and lotions to protect against sunburn. Crystalline zinc oxide exhibits the piezoelectric effect, is luminescent, and is light sensitive. Zinc oxide occurs in nature as the mineral zincite. Zinc peroxide, ZnO₂·1/2H₂O, is a white to yellow powder used in antiseptic ointments.

oxide, chemical compound containing oxygen and one other chemical element. Oxides are widely and abundantly distributed in nature. Water is the oxide of hydrogen. Silicon dioxide is the major component of sand and quartz. Carbon dioxide is given off during respiration by animals and plants. Carbon monoxide, sulfur dioxide, and oxides of nitrogen are among the waste gases of gasoline-burning internal-combustion engines. Nitrous oxide is an oxide of nitrogen often called laughing gas. Many of the metals form oxides. Some metal oxides, e.g., those of iron, aluminum, tin, and zinc, are important as ores. Litharge and red lead are lead oxides used as pigments in paint. A number of elements, e.g., arsenic, carbon, manganese, nitrogen, phosphorous, and sulfur, combine with oxygen to form more than one oxide. The inert gases do not form oxides. The halogens and inactive metals do not combine directly with oxygen, but their oxides can be formed by indirect methods. Oxides are usually named according to the number of oxygen atoms present in a molecule, e.g., monoxide (or simply oxide), dioxide, trioxide. In a molecule of carbon monoxide, CO, for example, there is one oxygen atom; in carbon dioxide, CO₂, there are two; and in phosphorus pentoxide, P₂O₅, there are five. Oxides are commonly classified as acidic or basic oxides or anhydrides. Sulfur trioxide is an acid anhydride; it reacts with water to form sulfuric acid. Phosphorus pentoxide reacts vigorously with water to form phosphoric acid. Many metal oxides react with water to form alkaline hydroxides, e.g., calcium oxide (lime) reacts with water to form calcium hydroxide (slaked lime). Some metal oxides do not react with water but are basic in that they react with an acid to form a salt and water. Others exhibit amphoterism; i.e., they react with both acids and bases. Still others are neutral and nonreactive.

nitrous oxide or nitrogen (I) oxide, chemical compound, N₂O, a colorless gas with a sweetish taste and odor. Its density is 1.977 grams per liter at STP. It is soluble in water, alcohol, ether, and other solvents. Although it does not burn, it supports combustion since it decomposes into oxygen and nitrogen when heated. The gas is prepared commercially by the thermal decomposition of ammonium nitrate, NH₄NO₃, at about 240°C; to produce nitrous oxide and water; the reaction must be carefully controlled to prevent explosive decomposition of the nitrous oxide. The gas is purified, liquified by compressing and cooling it, and stored in metal cylinders. A major use of nitrous oxide is in anesthesia, e.g., in dentistry. It is commonly called laughing gas since it produces euphoria and mirth when inhaled in small amounts. It is also used in making certain canned pressurized foods, e.g., instant whipped cream. Nitrous oxide was discovered (1772) by Joseph Priestley, who called it "diminished nitrous air"; he prepared it from "nitrous air" (nitric oxide, NO) by treatment with iron powder or a mixture of iron and sulfur powders. Its properties were further studied (1799) by Sir Humphry Davy.

nitric oxide or nitrogen monoxide, a colorless gas formed by the combustion of nitrogen and oxygen as given by the reaction: energy + N₂ + O₂ → 2NO; m.p. -163.6°C;; b.p. -151.8°C;. Nitric oxide readily combines with oxygen or air to form nitrogen dioxide (NO₂), which can again be separated by ultraviolet light to produce nitric oxide and highly reactive oxygen atoms. These oxygen atoms combine with hydrocarbons producing noxious compounds that irritate the membranes of living organisms and destroy vegetation. Large amounts of nitric oxide are created by internal-combustion engines and manufacturing processes. Its quantity is greatly reduced by passing the oxide gas through a catalyst, thereby converting it back to its constituent nitrogen and oxygen gases.

In the environment, nitric oxide is a precursor of smog and acid rain. Nitric oxide in minute amounts serves as a source of energy in certain bacteria. In the body, it serves as a chemical messenger with a wide range of functions. It acts as a neurotransmitter and is necessary for penile erection. It affects blood pressure and is produced by macrophages in the immune system to help defend against infection and cancer. Despite its usefulness, nitric oxide can have a toxic effect on body cells and has been implicated in Huntington's disease and Alzheimer's disease.

magnesium oxide: see magnesia.

calcium oxide, chemical compound, CaO, a colorless, cubic crystalline or white amorphous substance. It is also called lime, quicklime, or caustic lime, but commercial lime often contains impurities, e.g., silica, iron, alumina, and magnesia. It is prepared by heating calcium carbonate (e.g., limestone) in a special lime kiln to about 500°C; to 600°C;, decomposing it into the oxide and carbon dioxide. Calcium oxide is widely used in industry, e.g., in making porcelain and glass; in purifying sugar; in preparing bleaching powder, calcium carbide, and calcium cyanamide; in water softeners; and in mortars and cements. In agriculture it is used for treating acidic soils (liming). It is incandescent when heated to high temperatures; the Drummond light, or limelight, provides a brilliant white light by heating a cylinder of lime with the flame of an oxyhydrogen torch. Calcium oxide is a basic anhydride, reacting with water to form calcium hydroxide; during the reaction (slaking) much heat is given off and the solid nearly doubles its volume.

aluminum oxide: see alumina.

Any naturally occurring inorganic compound with a structure based on close-packed oxygen atoms in which smaller, positively charged metal or other ions occur. Oxide minerals are common in all rock types, whether igneous, sedimentary, or metamorphic.

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Any of a large and important class of chemical compounds in which oxygen is combined with another element. Metal oxides contain a metal cation and the oxide anion (O₂⁻); they typically react with water to form bases or with acids to form salts. Oxides of nonmetallic elements are volatile compounds in which a covalent bond joins the oxygen and the nonmetal; they react with water to form acids or with bases to form salts. A few substances (e.g., aluminum, zinc) form amphoteric oxides, which form salts with both acids and bases. Certain organic compounds form oxides in which the oxygen is covalently bonded to an atom of nitrogen (amine oxides), phosphorus (phosphine oxides), or sulfur (sulfoxides) in the organic molecule.

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or laughing gas

Inorganic compound, one of the oxides of nitrogen. A colourless gas with a pleasantly sweetish odour and taste, it has an analgesic effect when inhaled; it is used as an anesthetic (often called just “gas”) in dentistry and surgery. This effect is preceded by mild hysteria, sometimes with laughter, hence the name laughing gas. It is also used as a propellant in food aerosols and as a leak detector.

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Colourless, toxic gas (NO), formed from nitrogen and oxygen by the action of electric sparks or high temperatures or, more conveniently, by the action of dilute nitric acid on copper or mercury. First prepared circa 1620 by Jan B. Helmont, it was first studied in 1772 by Joseph Priestley, who called it “nitrous air.” An industrial procedure for the manufacture of hydroxylamine is based on the reaction of nitric oxide with hydrogen in the presence of a catalyst. The formation of nitric oxide from nitric acid and mercury is applied in a volumetric method of analysis for nitric acid or its salts. The gas is synthesized via enzyme-catalyzed reactions in humans and other animals, where it serves as a signaling molecule. Among its numerous biological roles, it causes dilation of blood vessels and as such is an important regulator of blood pressure. Nitric oxide is one of the components of air pollution generated by internal-combustion engines.

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or deuterium oxide

Water composed of two atoms of deuterium (D; a heavy isotope of hydrogen) and one atom of oxygen (O), chemical formula D₂O. Water from most natural sources contains about 0.015percnt deuterium oxide; this can be enriched or purified by distillation, electrolysis, or chemical processing. Heavy water is used as a moderator in nuclear power plants, slowing down the fast neutrons so that they can react with the fuel in the reactor. Heavy water is also used in research as an isotopic tracer for chemical reactions and biochemical pathways. Water with tritium (T₂O) rather than deuterium may also be called heavy water.

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