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Irving Langmuir

Irving Langmuir

[lang-myoor]
Langmuir, Irving, 1881-1957, American chemist, b. Brooklyn, N.Y. Associated (1909-50) with the research laboratory of the General Electric Company, he introduced atomic-hydrogen welding, invented a gas-filled tungsten lamp, and by his work on the high vacuum contributed greatly to the development of the radio vacuum tube. He extended the work of Gilbert Lewis on electron bonding, evolving the Lewis-Langmuir theory of atomic structure. In his research on surface tension and surface chemistry he developed a new technique (employing monolayers, i.e., layers of molecules one molecule thick) for the study of molecules, which has applications in research on microorganisms and toxins and in other studies contributing to advances in immunology. For his contributions in surface chemistry he received the 1932 Nobel Prize in Chemistry. It was Langmuir who discovered that the introduction of particles of dry ice and iodide into a cloud of low temperature containing sufficient moisture in tiny droplets triggered a chain reaction producing rain or snow, depending on the condition of the weather.

See his works, ed. by C. G. Suits and H. E. Way (12 vol., 1960-62); study by A. Rosenfeld (1966).

(born Jan. 31, 1881, Brooklyn, N.Y., N.Y., U.S.—died Aug. 16, 1957, Falmouth, Mass.) U.S. physical chemist. He received a Ph.D. from the University of Göttingen, Ger. As a researcher for General Electric (1909–50), he investigated electrical discharges in gases, electron emission, and the high-temperature surface chemistry of tungsten, making possible a great extension in the life of tungsten-filament lightbulbs. He developed a vacuum pump and the high-vacuum tubes used in radio broadcasting. He formulated theories of atomic structure and chemical bond formation, introducing the term covalence. He received a Nobel Prize in 1932.

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Irving Langmuir (January 31, 1881 in Brooklyn, New YorkAugust 16, 1957 in Woods Hole, Massachusetts) was an American chemist and physicist. His most noted publication was the famous 1919 article "The Arrangement of Electrons in Atoms and Molecules" in which, building on Gilbert N. Lewis's cubical atom theory and Walther Kossel's chemical bonding theory, he outlined his "concentric theory of atomic structure". Langmuir became embroiled in a priority dispute with Lewis over this work; Langmuir's presentation skills were largely responsible for the popularization of the theory, although the credit for the theory itself belongs mostly to Lewis. While at G.E., from 1909-1950, Langmuir advanced several basic fields of physics and chemistry, invented the gas-filled incandescent lamp, the hydrogen welding technique, and was awarded the 1932 Nobel Prize for Chemistry for his work in surface chemistry. He was the first industrial chemist to become a Nobel laureate. The Langmuir Laboratory for Atmospheric Research near Socorro, New Mexico was named in his honor as was the American Chemical Society journal for Surface Science, called Langmuir.

Biography

Early life

Irving Langmuir was born in Brooklyn, New York on January 31, 1881. He was the third child of four of Charles Langmuir and Sadie, née Comings. During his childhood, Langmuir's parents encouraged him to carefully observe nature and to keep a detailed record of his various observations. When Irving was eleven, it was discovered that he had poor eyesight. When this problem was corrected, details that had previously eluded him were revealed. Because of this, his interest in nature and the various complications of nature was heightened.

During his childhood, Langmuir was greatly influenced by his older brother, Arthur Langmuir. Arthur was a research chemist who encouraged Irving to be curious about nature and how things work. Arthur helped Irving set up his first chemistry lab in the corner of his bedroom, and he was content to answer the myriad of questions that Irving would pose. Langmuir's hobbies included mountaineering, skiing, piloting his own plane, and classical music. In addition to his professional interest in the politics of atomic energy, he was deeply concerned about wilderness conservation.

Education

Langmuir attended his early education at various schools and institutes in America and Paris (1892-1895). He graduated with a Bachelor of Science degree. in metallurgical engineering from the Columbia University School of Mines (the first mining and metallurgy school in the U.S., established,1864 and presently known as Fu Foundation School of Engineering and Applied Science) in 1903. He earned his Ph.D. degree in 1906 under Nobel laureate Walther Nernst in Göttingen, for research done using the "Nernst glower", an electric lamp invented by Nernst. His doctoral thesis was entitled “On the Partial Recombination of Dissolved Gases During Cooling.” He later did postgraduate work in chemistry. Langmuir then taught at Stevens Institute of Technology in Hoboken, New Jersey, until 1909, when he began working at the General Electric research laboratory (Schenectady, New York). In 1912, he married Marion Mersereau.

Research

His initial contributions to science came from his study of light bulbs (a continuation of his Ph.D. work). His first major development was the improvement of the diffusion pump, which ultimately led to the invention of the high-vacuum tube. A year later, he and colleague Lewi Tonks discovered that the lifetime of a tungsten filament was greatly lengthened by filling the bulb with an inert gas, such as argon. He also discovered that twisting the filament into a tight coil improved its efficiency. These were important developments in the history of the incandescent light bulb. His work in surface chemistry began at this point, when he discovered that molecular hydrogen introduced into a tungsten-filament bulb dissociated into atomic hydrogen and formed a layer one atom thick on the surface of the bulb.

His assistant in vacuum tube research was his cousin William Comings White.

In 1917, he published a paper on the chemistry of oil films that later became the basis for the award of the 1932 Nobel Prize in chemistry. Langmuir theorized that oils consisting of an aliphatic chain with a hydropilic end group (perhpas an alchohol or acid) were oriented as a film one molecule thick upon the surface of water, with the hydrophilic group down in the water and the hydrophilic chains clumped together on the surface. The thickness of the film could be easily determined from the known volume and area of the oil, which allowed investigation of the molecular configuration before spectroscopic techniques were available.

As he continued to study filaments in vacuum and different gas environments, he began to study the emission of charged particles from hot filaments (thermionic emission). He was one of the first scientists to work with plasmas and was the first to call these ionized gases by that name, because they reminded him of blood plasma.

He introduced the concept of electron temperature and in 1924 invented the diagnostic method for measuring both temperature and density with an electrostatic probe, now called a Langmuir probe and commonly used in plasma physics. The current of a biased probe tip is measured as a function of bias voltage to determine the local plasma temperature and density. He also discovered atomic hydrogen, which he put to use by inventing the atomic hydrogen welding process; the first plasma weld ever made. Plasma welding has since been developed into gas tungsten arc welding.

Later years

Following World War I Langmuir contributed to atomic theory and the understanding of atomic structure by defining the modern concept of valence shells and isotopes.

He joined Katharine B. Blodgett to study thin films and surface absorption. They introduced the concept of a monolayer (a layer of material one molecule thick) and the two-dimensional physics which describe such a surface. In 1932 he received the Nobel Prize for Chemistry "for his discoveries and investigations in surface chemistry." In 1938, Langmuir's scientific interests began to turn to atmospheric science and meteorology. One of his first ventures, although tangentially related, was a refutation of the claim of entomologist Charles H. T. Townsend that the deer botfly flew at speeds in excess of 800 miles per hour. Langmuir estimated the fly's true speed at 25 miles per hour.

After observing windrows of drifting seaweed in the Sargasso Sea he discovered a wind-driven surface circulation in the sea. It is now called the Langmuir circulation.

During World War II, Langmuir worked on improving naval sonar for submarine detection, and later to develop protective smoke screens and methods for deicing aircraft wings. This research led him to theorize that the introduction of dry ice and iodide into a sufficiently moist cloud of low temperature could induce precipitation (cloud seeding); though in frequent practice, particularly in Australia and the People's Republic of China, the efficiency of this technique remains controversial today.

In 1953 Langmuir coined the term "pathological science", describing research conducted with accordance to the scientific method, but tainted by unconscious bias or subjective effects. This is in contrast to pseudoscience, which has no pretense of following the scientific method. In his original speech, he presented ESP and flying saucers as examples of pathological science; since then, the label has been applied to polywater and cold fusion.

After a short illness, he died of a heart attack in 1957. His obituary ran on the front page of the New York Times.

His house in Schenectady, was designated a National Historic Landmark in 1976.

Patents

  • Langmuir, , "Incandescent Electric Lamp"
  • Langmuir, , "Electron-discharge apparatus and method of operating the same"
  • Langmuir, , "Method of and apparatus for controlling x-ray tubes"

See also

Langmuir isotherm

References

Further reading

  • Patrick Coffey, Cathedrals of Science: The Personalities and Rivalries That Made Modern Chemistry, Oxford University Press, 2008. ISBN 978-0-19-532134-0

External links


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