fusel oil

fusel oil, oily, colorless liquid with a disagreeable odor and taste. It is a mixture of alcohols (largely amyl alcohols) and fatty acids, formed during the alcoholic fermentation of organic materials. After imperfect distillation of these fermentation products it becomes an impurity in the distilled liquor. Fusel oil is used as a solvent in the manufacture of certain lacquers and enamels (it dissolves nitrocellulose). It has a detrimental effect on the human system.

Fusel alcohols, also sometimes called fusel oils, or potato oil in Europe, are higher order (more than two carbons) alcohols formed by fermentation and present in cider, mead, beer, wine, and spirits to varying degrees. The term fusel is German for “bad liquor.”

Composition and taste

The compounds involved are chiefly:

• 1-propanol
• 2-propanol
• butanol (various isomers)
• amyl alcohol
• furfural

Excessive concentrations of these fractions may cause off flavours, sometimes described as "spicy," "hot," or "solvent-like." Some beverages, such as whiskey, Siwucha and traditional ales and ciders, are expected to have relatively high concentrations of fusel alcohols as part of the flavour profile. In other beverages, such as vodka and lagers, the presence of fusel alcohols is considered a fault. Very high concentrations — usually caused by incompetent distillation — can cause acute illness, including headaches, nausea, vomiting, clinical depression, or coma. Such a liquor may be referred to as rotgut.

Formation and removal

Fusel alcohols are formed when fermentation occurs:

• at higher temperatures,
• at lower pH,
• when yeast activity is limited by low nitrogen content.

During distillation, fusel alcohols are concentrated in the "tails" at the end of the distillation run. They have an oily consistency, which is noticeable to the distiller, hence the other name fusel oil. If desired, these heavier alcohols can be almost completely separated in a reflux still. Freeze distillation, on the other hand, does not remove fusel alcohols.