Enstatite is the magnesium endmember of the pyroxene silicate mineral series enstatite (MgSiO3) - ferrosilite (FeSiO3). The magnesium rich members of the solid solution series are common rock-forming minerals found in igneous and metamorphic rocks. The intermediate composition, (Mg,Fe)SiO3, has historically been known as hypersthene, although this name has been formally abandoned and replaced by orthopyroxene. When determined petrographically or chemicaly the composition is given as relative proportions of enstatite (En) and ferrosilite (Fs) (e.g., En80Fs20).
Most natural crystals are orthorhombic (space group Pbca) although three polymorphs are known. The high temperature, low pressure polymorphs are protoenstatite and protoferrosilite (also orthorhombic, space group Pbcn) while the low temperature forms, clinoenstatite and clinoferrosilite, are monoclinic (space group P21/c).
Bronzite and hypersthene were known long before enstatite, which was first described by G. A. Kenngott in 1855.
An emerald-green variety of enstatite is called chrome-enstatite and is cut as a gemstone. The green color is caused by traces of chromium, hence the varietal name. In addition, bronzite is also sometimes used as a gemstone.
Enstatite, close to En90Fs10 in composition, is an essential mineral in typical peridotite and pyroxenite of the Earth's mantle. Xenoliths of peridotite are common in kimberlite and in some basalt. Measurements of the calcium, aluminum, and chromium contents of enstatite in these xenoliths have been crucial in reconstructing the depths from which the xenoliths were plucked by the ascending magmas.
Orthopyroxene is an important constituent of some metamorphic rocks such as granulite. Orthopyroxene near pure enstatite in composition occurs in some metamorphosed serpentines. Large crystals, a foot in length and mostly altered to steatite, were found in 1874 in the apatite veins traversing mica-schist and hornblende-schist at the apatite mine of Kjorrestad, near Brevig in southern Norway.
Enstatite is a common mineral in meteorites. Crystals have been found in stony and iron meteorites, including one that fell at Breitenhach in the Erzgebirge, Bohemia. In some meteorites, together with olivine it forms the bulk of the material; it can occur in small spherical masses, or chondrules, with an internal radiated structure.