All conductors contain charge]]s which will move when an electric potential difference (measured in volts) is applied across separate points on the material. This flow of charge (measured in amperes) is what is meant by electric current. In most materials, the rate of current is proportional to the voltage (Ohm's law,) provided the temperature remains constant and the material remains in the same shape and state. The ratio between the voltage and the current is called the resistance (measured in ohms) of the object between the points where the voltage was applied. The resistance across a standard mass (and shape) of a material at a given temperature is called the resistivity of the material. The inverse of resistance and resistivity is conductance and conductivity. Some good examples of conductors are metal.
Most familiar conductors are metallic. Copper is the most common material for electrical wiring (silver is the best but expensive), and gold for high-quality surface-to-surface contacts. However, there are also many non-metallic conductors, including graphite, solutions of salts, and all plasmas. See electrical conduction for more information on the physical mechanism for charge flow in materials.
Non-conducting materials lack mobile charges, and so resist the flow of electric current, generating heat. In fact, all materials offer some resistance and warm up when a current flows. Thus, proper design of an electrical conductor takes into account the temperature that the conductor needs to be able to endure without damage, as well as the quantity of electrical current. The motion of charges also creates an electromagnetic field around the conductor that exerts a mechanical radial squeezing force on the conductor. A conductor of a given material and volume (length x cross-sectional area) has no real limit to the current it can carry without being destroyed as long as the heat generated by the resistive loss is removed and the conductor can withstand the radial forces. This effect is especially critical in printed circuits, where conductors are relatively small and close together, and inside an enclosure: the heat produced, if not properly removed, can cause fusing (melting) of the tracks.
Since all conductors have some resistance, and all insulators will carry some current, there is no theoretical dividing line between conductors and insulators. However, there is a large gap between the conductance of materials that will carry a useful current at working voltages and those that will carry a negligible current for the purpose in hand, so the categories of insulator and conductor do have practical utility.
Thermal and electrical conductivity often go together (for instance, most metals are both electrical and thermal conductors). However, some materials are practical electrical conductors without being a good thermal conductor.
In many countries, conductors are measured by their cross section in square millimeters.
However, in the United States, conductors are measured by American wire gauge for smaller ones, and circular mils for larger ones. In some poor countries they have overloaded wires going into one circuit.
Of the metals commonly used for conductors, copper, has a high conductivity. Silver is more conductive, but due to cost it is not practical in most cases. However, it is used in specialized equipment, such as satellites, and as a thin plating to mitigate skin effect losses at high frequencies. Because of its ease of connection by soldering or clamping, copper is still the most common choice for most light-gauge wires. Aluminum has been used as a conductor in housing applications for cost reasons. It is actually more conductive than copper when compared by unit weight, but it has technical problems related to heat and compatibility of metals.
The voltage on a conductor is determined by the connected circuitry and has nothing to do with the conductor itself. Conductors are usually surrounded by and/or supported by insulators and the insulation determines the maximum voltage that can be applied to any given conductor.
Voltage of a conductor "V" is given by
The ampacity of a conductor, that is, the amount of current it can carry, is related to its electrical resistance: a lower-resistance conductor can carry more current. The resistance, in turn, is determined by the material the conductor is made from (as described above) and the conductor's size. For a given material, conductors with a larger cross-sectional area have less resistance than conductors with a smaller cross-sectional area.
For bare conductors, the ultimate limit is the point at which power lost to resistance causes the conductor to melt. Aside from fuses, most conductors in the real world are operated far below this limit, however. For example, household wiring is usually insulated with PVC insulation that is only rated to operate to about 60 °C, therefore, the current flowing in such wires must be limited so that it never heats the copper conductor above 60 °C, causing a risk of fire. Other, more expensive insulations such as Teflon or fiberglass may allow operation at much higher temperatures.
The American wire gauge article contains a table showing allowable ampacities for a variety of copper wire sizes.
If an electric field is applied to a material, and the resulting induced electric current is in the same direction, the material is said to be an isotropic electrical conductor. If the resulting electric current is in a different direction from the applied electric field, the material is said to be an anisotropic electrical conductor!.