Elastomers are usually thermosets (requiring vulcanization) but may also be thermoplastic (see thermoplastic elastomer). The long polymer chains cross-link during curing. The molecular structure of elastomers can be imagined as a 'spaghetti and meatball' structure, with the meatballs signifying cross-links. The elasticity is derived from the ability of the long chains to reconfigure themselves to distribute an applied stress. The covalent cross-linkages ensure that the elastomer will return to its original configuration when the stress is removed. As a result of this extreme flexibility, elastomers can reversibly extend from 5-700%, depending on the specific material. Without the cross-linkages or with short, uneasily reconfigured chains, the applied stress would result in a permanent deformation.
Temperature effects are also present in the demonstrated elasticity of a polymer. Elastomers that have cooled to a glassy or crystalline phase will have less mobile chains, and consequentially less elasticity, than those manipulated at temperatures higher than the glass transition temperature of the polymer.
It is also possible for a polymer to exhibit elasticity that is not due to covalent cross-links, but instead for thermodynamic reasons.
Using the laws of thermodynamics, stress definitions and polymer characteristics (complete derivation in , pages103-105), we find ideal stress behavior:
where is the number of chain segments per unit volume, is Boltzmann's Constant, is temperature, and is distortion in the 1 direction.
These findings are accurate for values of up to approximately 400% strain. At this point, alignment between stretched chains begins to result in crystallization from noncovalent bonding.
While Young's Modulus does not exist for elastomers due to the nonlinear nature of the stress-strain relationship, a "secant modulus" can be found at a particular strain.
Unsaturated rubbers that can be cured by sulfur vulcanization:
(Note that unsaturated rubbers can also be cured by non-sulfur vulcanization if desired).
Saturated Rubbers that cannot be cured by sulfur vulcanization:
Various other types of elastomers:
Elastomers stretch modeling abilities: three straightforward strategies can dramatically improve the accuracy of thermoplastic elastomer simulations.(ENGINEERING PLASTICS)
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