wall-attachment effect: see Coanda effect.

piezoelectric effect, voltage produced between surfaces of a solid dielectric (nonconducting substance) when a mechanical stress is applied to it. A small current may be produced as well. The effect, discovered by Pierre Curie in 1883, is exhibited by certain crystals, e.g., quartz and Rochelle salt, and ceramic materials. When a voltage is applied across certain surfaces of a solid that exhibits the piezoelectric effect, the solid undergoes a mechanical distortion. Piezoelectric materials are used in transducers, e.g., phonograph cartridges, microphones, and strain gauges, which produce an electrical output from a mechanical input, and in earphones and ultrasonic radiators, which produce a mechanical output from an electrical input. Piezoelectric solids typically resonate within narrowly defined frequency ranges; when suitably mounted they can be used in electric circuits as components of highly selective filters or as frequency-control devices for very stable oscillators.

photoelectric effect, emission of electrons by substances, especially metals, when light falls on their surfaces. The effect was discovered by H. R. Hertz in 1887. The failure of the classical theory of electromagnetic radiation to explain it helped lead to the development of the quantum theory. According to classical theory, when light, thought to be composed of waves, strikes substances, the energy of the liberated electrons ought to be proportional to the intensity of light. Experiments showed that, although the electron current produced depends upon the intensity of the light, the maximum energy of the electrons was not dependent on the intensity. Moreover, classical theory predicted that the photoelectric current should not depend on the frequency of the light and that there should be a time lag between the reception of light on the surface and the emission of the electrons. Neither of these predictions was borne out by experiment. In 1905, Albert Einstein published a theory that successfully explained the photoelectric effect. It was closely related to Planck's theory of black body radiation announced in 1900. According to Einstein's theory, the incident light is composed of discrete particles of energy, or quanta, called photons, the energy of each photon being proportional to its frequency according to the equation E=hυ, where E is the energy, υ is the frequency, and h is Planck's constant. Each photoelectron ejected is the result of the absorption of one photon. The maximum kinetic energy, KE, that any photoelectron can possess is given by KE = hυ-W, where W is the work function, i.e., the energy required to free an electron from the material, varying with the particular material. The effect has a number of practical applications, most based on the photoelectric cell.

ground-effect machine: see air-cushion vehicle.

greenhouse effect: see global warming.

field-effect transistor: see transistor.

common-ion effect, decrease in solubility of an ionic salt, i.e., one that dissociates in solution into its ions, caused by the presence in solution of another solute that contains one of the same ions as the salt. The common-ion effect is an example of chemical equilibrium. For example, silver chloride, AgCl, is a slightly soluble salt that in solution dissociates into the ions Ag⁺ and Cl^-, the equilibrium state being represented by the equation AgCl_solid ⇌Ag⁺+Cl^-. According to Le Châtelier's principle, when a stress is placed on a system in equilibrium, the system responds by tending to reduce that stress. In the system taken as an example, if another solute containing one of those ions is added, e.g., sodium chloride, NaCl, which supplies Cl^- ions, the solubility equilibrium of the solution will be shifted to remove more Cl^- from the solution, so that at the new equilibrium point there will be fewer Ag⁺ ions in solution and more AgCl precipitated out as a solid.

Zeeman effect, splitting of a single spectral line (see spectrum) into a group of closely spaced lines when the substance producing the single line is subjected to a uniform magnetic field. The effect was discovered in 1896 by the Dutch physicist Pieter Zeeman. In the so-called normal Zeeman effect, the spectral line corresponding to the original frequency of the light (in the absence of the magnetic field) appears with two other lines arranged symmetrically on either side of the original line. In the anomalous Zeeman effect (which is actually more common than the normal effect), several lines appear, forming a complex pattern. The normal Zeeman effect was successfully explained by H. A. Lorentz using the laws of classical physics (Zeeman and Lorentz shared the 1902 Nobel Prize in Physics). The anomalous Zeeman effect could not be explained using classical physics; the development of the quantum theory and the discovery of the electron's intrinsic spin led to a satisfactory explanation. According to the quantum theory all spectral lines arise from transitions of electrons between different allowed energy levels within the atom, the frequency of the spectral line being proportional to the energy difference between the initial and final levels. Because of its intrinsic spin, the electron has a magnetic field associated with it. When an external magnetic field is applied, the electron's magnetic field may assume only certain alignments. Slight differences in energy are associated with these different orientations, so that what was once a single energy level becomes three or more. Practical applications based on the Zeeman effect include spectral analysis and measurement of magnetic field strength. Since the separation of the components of the spectral line is proportional to the field strength, the Zeeman effect is particularly useful where the magnetic field cannot be measured by more direct methods.

Tyndall effect: see colloid.

Thomson effect: see thermoelectricity.

Seebeck effect: see thermoelectricity.

Raman effect, appearance of additional lines in the spectrum of monochromatic light that has been scattered by a transparent material medium. The effect was discovered by C. V. Raman in 1928. The energy and thus the frequency and wavelength of the scattered light is changed as the light either imparts rotational or vibrational energy to the scattering molecules or takes energy away. The line spectrum of the scattered light will have one prominent line corresponding to the original wavelength of the incident radiation, plus additional lines to each side of it corresponding to the shorter or longer wavelengths of the altered portion of the light. This Raman spectrum is characteristic of the transmitting substance. Raman spectrometry is a useful technique in physical and chemical research, particularly for the characterization of materials.

Peltier effect: see thermoelectricity.

Hall effect, experiment that shows the sign of the charge carriers in a conductor. In 1879 E. H. Hall discovered that when he placed a metal strip carrying a current in a magnetic field, a voltage difference was produced across the strip. The side of the strip that is at the higher voltage depends on the sign of the charge carrier; Hall's work demonstrated that in metals the charge carriers are negative. Today it is known that this negative charge carrier is the electron. The Hall effect has again become an active area of research with the discovery of the quantized Hall effect, for which Klaus von Klitzing was awarded the 1985 Nobel Prize in physics. Before von Klitzing's work it was thought that the amount of voltage difference across the strip varied in direct proportion to the strength of the magnetic field—the greater the magnetic field, the greater the voltage difference. Von Klitzing showed that under the special conditions of low temperature, high magnetic field, and two-dimensional electronic systems (in which the electrons are confined to move in planes), the voltage difference increases as a series of steps with increasing magnetic field.

Doppler effect, change in the wavelength (or frequency) of energy in the form of waves, e.g., sound or light, as a result of motion of either the source or the receiver of the waves; the effect is named for the Austrian scientist Christian Doppler, who demonstrated the effect for sound. If the source of the waves and the receiver are approaching each other (because of the motion of either or both), the frequency of the waves will increase and the wavelength will be shortened—sounds will become higher pitched and light will appear bluer. If the sender and receiver are moving apart, sounds will become lower pitched and light will appear redder. A common example is the sudden drop in the pitch of a train whistle as the train passes a stationary listener. The Doppler effect in reflected radio waves is employed in radar to sense the velocity of the object under surveillance. In astronomy, the Doppler effect for light is used to measure the velocity (and indirectly distance) and rotation of stars and galaxies along the direction of sight. In the spectrum of nearly every star there are wavelengths, characteristic of atoms, that lie near but not quite coincident to the same wavelengths as measured in the laboratory. The small deviations or shifts are generally due to the relative motion of the celestial object and the earth. Both blue shifts and red shifts are observed for various objects, indicating relative motion both toward and away from the earth. Such shifts have been used to measure the orbital velocity of the earth, to detect binary stars and variable stars, and to detect rotation of other galaxies. The Doppler effect is responsible for the red shifts of distant galaxies, and also of quasars, and thus provides the best evidence for the expansion of the universe, as described by Hubble's law. In addition to observations of visible light, the Doppler effect for radio waves is utilized by astronomers to determine the velocities of dust clouds in the spiral arms of the Milky Way galaxy. These observations provided the first direct proof that our own galaxy is rotating. The Doppler shift in radar pulses reflected from the surfaces of Venus and Mercury have been analyzed to obtain new values for their periods of rotation about their axes.

Coriolis effect [for G.-G. de Coriolis, a French mathematician], tendency for any moving body on or above the earth's surface, e.g., an ocean current or an artillery round, to drift sideways from its course because of the earth's rotation. In the Northern Hemisphere the deflection is to the right of the motion; in the Southern Hemisphere it is to the left. The Coriolis deflection of a body moving toward the north or south results from the fact that the earth's surface is rotating eastward at greater speed near the equator than near the poles, since a point on the equator traces out a larger circle per day than a point on another latitude nearer either pole. A body traveling toward the equator with the slower rotational speed of higher latitudes tends to fall behind or veer to the west relative to the more rapidly rotating earth below it at lower latitudes. Similarly, a body traveling toward either pole veers eastward because it retains the greater eastward rotational speed of the lower latitudes as it passes over the more slowly rotating earth closer to the pole. It is extremely important to account for the Coriolis effect when considering projectile trajectories, terrestrial wind systems, and ocean currents.

Compton effect [for A. H. Compton], increase in the wavelengths of X rays and gamma rays when they collide with and are scattered from loosely bound electrons in matter. This effect provides strong verification of the quantum theory since the theoretical explanation of the effect requires that one treat the X rays and gamma rays as particles or photons (quanta of energy) rather than as waves. The classical treatment of these rays as waves would predict no such effect. According to the quantum theory a photon can transfer part of its energy and linear momentum to a loosely bound electron in a collision. Since the energy and magnitude of linear momentum of a photon are proportional to its frequency, after the collision the photon has a lower frequency and thus a longer wavelength. The increase in the wavelength does not depend upon the wavelength of the incident rays or upon the target material. It depends only upon the angle that is formed between the incident and scattered rays. A larger scattering angle will yield a larger increase in wavelength. The effect was discovered in 1923. It is used in the study of electrons in matter and in the production of variable energy gamma-ray beams.

Coanda effect or wall-attachment effect, the tendency of a moving fluid, either liquid or gas, to attach itself to a surface and flow along it. As a fluid moves across a surface a certain amount of friction (called "skin friction") occurs between the fluid and the surface, which tends to slow the moving fluid. This resistance to the flow of the fluid pulls the fluid towards the surface, causing it stick to the surface. Thus, a fluid emerging from a nozzle tends to follow a nearby curved surface—even to the point of bending around corners—if the curvature of the surface or the angle the surface makes with the stream is not too sharp. Discovered in 1930 by Henri Coanda, a Romanian aircraft engineer, the phenomenon has many practical applications in fluidics and aerodynamics.

or barrier penetration

In physics, the passage of a particle through a seemingly impassable energy barrier. Though a particle's energy may be too low to surmount a barrier in classical physics, the particle may still cross the barrier as a consequence of its quantum-mechanical wave properties. An important application of this phenomenon is in the operation of the scanning tunneling microscope.

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Artificial imitation of sound to accompany action and supply realism in a dramatic production. Sound effects were first used in the theatre, where they can represent a range of action too vast or difficult to present onstage, from battles and gunshots to trotting horses and rainstorms. Various methods were devised by backstage technicians to reproduce sounds (e.g., rattling sheet metal to create thunder); today most sound effects are reproduced by recordings. An important part of old-fashioned radio dramas, sound effects are still painstakingly added to television and movie soundtracks.

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Process in which two dissimilar materials in close contact act as an electric cell when struck by light or other radiant energy. In crystals of certain elements, such as silicon and germanium, the electrons are usually not free to move from atom to atom. Light striking the crystal provides the energy needed to free electrons from their bound condition. These electrons can cross the junction between two dissimilar crystals more easily in one direction than another, so one side of the junction acquires a negative voltage with respect to the other. As long as light falls on the two materials, the photovoltaic battery can continue to provide voltage and current. The current can be used to measure the brightness of the light or as a source of power, as in a solar cell.

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Phenomenon in which charged particles are released from a material when it absorbs radiant energy (see radiation). It is often thought of as the ejection of electrons from the surface of a metal plate when visible light falls on it. It can also occur if the radiation is in the wavelength range of ultraviolet radiation, X rays, or gamma rays. The emitting surface may be a solid, liquid, or gas, and the emitted particles may be electrons or ions. The effect was discovered in 1887 by Heinrich Hertz and explained by Albert Einstein in work for which he received the Nobel Prize.

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or hovercraft

Vehicle supported above the surface of land or water by an air cushion, produced by downwardly directed fans, enclosed within a flexible skirt beneath the hull. The concept was first proposed by John Thornycroft in the 1870s, but a working model was not produced until 1955, when Christopher Cockerell solved the problem of keeping the air cushion from escaping from under the vehicle, and formed Hovercraft Ltd. to manufacture prototypes. Problems with skirt design and engine maintenance have restricted the vehicle's commercial application; today hovercraft are used mainly as ferries.

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Warming of the Earth's surface and lower atmosphere caused by water vapour, carbon dioxide, and other trace gases in the atmosphere. Visible light from the Sun heats the Earth's surface. Part of this energy is radiated back into the atmosphere in the form of infrared radiation, much of which is absorbed by molecules of carbon dioxide and water vapour in the atmosphere and reradiated toward the surface as more heat. (Despite the name, the greenhouse effect is different from the warming in a greenhouse, where panes of glass allow the passage of visible light but hold heat inside the building by trapping warmed air.) The absorption of infrared radiation causes the Earth's surface and lower atmosphere to warm more than they otherwise would, making the Earth's surface habitable. An increase in atmospheric carbon dioxide caused by widespread combustion of fossil fuels may intensify the greenhouse effect and cause long-term climatic changes. Likewise, an increase in atmospheric concentrations of other trace greenhouse gases such as chlorofluorocarbons, nitrous oxide, and methane resulting from human activities may also intensify the greenhouse effect. From the beginning of the Industrial Revolution through the end of the 20th century, the amount of carbon dioxide in the atmosphere increased 30percnt and the amount of methane more than doubled. It is also estimated that the U.S. is responsible for about one-fifth of all human-produced greenhouse-gas emissions. Seealso global warming.

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or domino effect

Doctrine of U.S. foreign policy during the Cold War, according to which the fall of a noncommunist state to communism would precipitate the fall of other neighbouring noncommunist states. The theory was first enunciated by Pres. Harry Truman, who used it to justify sending U.S. military aid to Greece and Turkey in the late 1940s. Dwight D. Eisenhower, John F. Kennedy, and Lyndon B. Johnson invoked it to justify U.S. military involvement in Southeast Asia, especially the prosecution of the Vietnam War.

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Splitting of a spectral line (see spectrum) into two or more lines of different frequencies. The effect occurs when the light source is placed in a magnetic field. It has helped identify the energy levels in atoms; it also provides a means of studying atomic nuclei and electron paramagnetic resonance (see magnetic resonance) and is used in measuring the magnetic field of the Sun and other stars. It was discovered in 1896 by Pieter Zeeman (1865–1943); he shared the second Nobel Prize for Physics (1902) with Hendrik Antoon Lorentz, who had hypothesized that a magnetic field would affect the frequency of the light emitted.

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Development of a transverse electric field in a solid material carrying an electric current and placed in a magnetic field perpendicular to the current. Discovered in 1879 by Edwin H. Hall (1855–1938), the Hall field results from the force exerted by the magnetic field on the moving particles of the current. The Hall effect can be used to measure certain properties of current carriers as well as to detect the presence of a current on a magnetic field.

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Apparent difference between the frequency at which waves—including light, sound, and radio waves—leave a source and that at which they reach an observer. The effect, first described by the Austrian physicist Christian Doppler (1803–1853), is caused by the relative motion of the observer and the wave source. It can be observed by listening to the blowing horn or siren of an approaching vehicle, whose pitch rises as the vehicle approaches the observer and falls as it recedes. It is used in radar and to calculate the speed of stars by observing the change in frequency of their light.

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Change in wavelength of X rays and other energetic forms of electromagnetic radiation when they collide with electrons. It is a principal way in which radiant energy is absorbed by matter, and is caused by the transfer of energy from photons to electrons. When photons collide with electrons that are free or loosely bound in atoms, they transfer some of their energy and momentum to the electrons, which then recoil. New photons of less energy and momentum, and hence longer wavelength, are produced; these scatter at various angles, depending on the amount of energy lost to the recoiling electrons. The effect demonstrates the nature of the photon as a true particle with both energy and momentum. Its discovery in 1922 by Arthur Compton was essential to establishing the wave-particle duality of electromagnetic radiation.

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