dipole

dipole

[dahy-pohl]
dipole: see pole, in electricity and magnetism.

Tiny magnet with subatomic dimensions, equivalent to the flow of electric charge around a loop. Examples include electrons circulating around atomic nuclei, rotating atomic nuclei, and single subatomic particles with spin. On a large scale, these effects may add together, as in iron atoms, to make magnetic compass needles and bar magnets, which are macroscopic magnetic dipoles. The strength of a magnetic dipole, its magnetic moment, is a measure of its ability to turn itself into alignment with a given external magnetic field. When free to rotate, dipoles align themselves so that their moments point predominantly in the direction of the magnetic field. The SI unit for dipole moment is the ampere-square metre.

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Pair of equal and opposite electric charges, the centres of which do not coincide. An atom in which the centre of the negative cloud of electrons has been shifted slightly away from the nucleus by an external electric field is an induced electric dipole. When the external field is removed, the atom loses its dipolarity. A water molecule, in which two hydrogen atoms are situated to one side of an oxygen atom, is a permanent electric dipole. The oxygen side is always slightly negative, the hydrogen side slightly positive.

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In physics, there are two kinds of dipoles (Hellènic: di(s)- = two- and pòla = pivot, hinge):

  • An electric dipole is a separation of positive and negative charge. The simplest example of this is a pair of electric charges of equal magnitude but opposite sign, separated by some, usually small, distance. A permanent electric dipole is called an electret.
  • A magnetic dipole is a closed circulation of electric current. A simple example of this is a single loop of wire with some constant current flowing through it.

Dipoles can be characterized by their dipole moment, a vector quantity. For the simple electric dipole given above, the electric dipole moment would point from the negative charge towards the positive charge, and have a magnitude equal to the strength of each charge times the separation between the charges. For the current loop, the magnetic dipole moment would point through the loop (according to the right hand grip rule), with a magnitude equal to the current in the loop times the area of the loop.

In addition to current loops, the electron, among other fundamental particles, is said to have a magnetic dipole moment. This is because it generates a magnetic field which is identical to that generated by a very small current loop. However, to the best of our knowledge, the electron's magnetic moment is not due to a current loop, but is instead an intrinsic property of the electron. It is also possible that the electron has an electric dipole moment, although this has not yet been observed (see electron electric dipole moment for more information).

A permanent magnet, such as a bar magnet, owes its magnetism to the intrinsic magnetic dipole moment of the electron. The two ends of a bar magnet are referred to as poles (not to be confused with monopoles), and are labeled "north" and "south." The dipole moment of the bar magnet points from its magnetic south to its magnetic north pole—confusingly, the "north" and "south" convention for magnetic dipoles is the opposite of that used to describe the Earth's geographic and magnetic poles, so that the Earth's geomagnetic north pole is the south pole of its dipole moment. (This should not be difficult to remember; it simply means that the north pole of a bar magnet is the one which points north if used as a compass.)

The only known mechanisms for the creation of magnetic dipoles are by current loops or quantum-mechanical spin since the existence of magnetic monopoles has never been experimentally demonstrated.

Physical dipoles, point dipoles, and approximate dipoles

A physical dipole consists of two equal and opposite point charges: literally, two poles. Its field at large distances (i.e., distances large in comparison to the separation of the poles) depends almost entirely on the dipole moment as defined above. A point (electric) dipole is the limit obtained by letting the separation tend to 0 while keeping the dipole moment fixed. The field of a point dipole has a particularly simple form, and the order-1 term in the multipole expansion is precisely the point dipole field.

Although there are no known magnetic monopoles in nature, there are magnetic dipoles in the form of the quantum-mechanical spin associated with particles such as electrons (although the accurate description of such effects falls outside of classical electromagnetism). A theoretical magnetic point dipole has a magnetic field of the exact same form as the electric field of an electric point dipole. A very small current-carrying loop is approximately a magnetic point dipole; the magnetic dipole moment of such a loop is the product of the current flowing in the loop and the (vector) area of the loop.

Any configuration of charges or currents has a 'dipole moment', which describes the dipole whose field is the best approximation, at large distances, to that of the given configuration. This is simply one term in the multipole expansion; when the charge ("monopole moment") is 0 — as it always is for the magnetic case, since there are no magnetic monopoles — the dipole term is the dominant one at large distances: its field falls off in proportion to 1/r^3, as compared to 1/r^4 for the next (quadrupole) term and higher powers of 1/r for higher terms, or 1/r^2 for the monopole term.

Molecular dipoles

Many molecules have such dipole moments due to non-uniform distributions of positive and negative charges on the various atoms. For example:

(positive) H-Cl (negative)

A molecule with a permanent dipole moment is called a polar molecule. A molecule is polarized when it carries an induced dipole. The physical chemist Peter J. W. Debye was the first scientist to study molecular dipoles extensively, and dipole moments are consequently measured in units named debye in his honor.

With respect to molecules there are three types of dipoles:

  • Permanent dipoles: These occur when two atoms in a molecule have substantially different electronegativity—one atom attracts electrons more than another becoming more negative, while the other atom becomes more positive. See dipole-dipole attractions.
  • Instantaneous dipoles: These occur due to chance when electrons happen to be more concentrated in one place than another in a molecule, creating a temporary dipole. See instantaneous dipole.
  • Induced dipoles These occur when one molecule with a permanent dipole repels another molecule's electrons, "inducing" a dipole moment in that molecule. See induced-dipole attraction.

The definition of an induced dipole given in the previous sentence is too restrictive and misleading. An induced dipole of any polarizable charge distribution rho (remember that a molecule has a charge distribution) is caused by an electric field external to rho. This field may, for instance, originate from an ion or polar molecule in the vicinity of rho or may be macroscopic (e.g., a molecule between the plates of a charged capacitor). The size of the induced dipole is equal to the product of the strength of the external field and the dipole polarizability of rho.

Typical gas phase values of some chemical compounds in debye units:

These values can be obtained from measurement of the dielectric constant. When the symmetry of a molecule cancels out a net dipole moment, the value is set at 0. The highest dipole moments are in the range of 10 to 11. From the dipole moment information can be deduced about the molecular geometry of the molecule. For example the data illustrate that carbon dioxide is a linear molecule but ozone is not.

Quantum mechanical dipole operator

Consider a collection of N particles with charges q_i and position vectors mathbf{r}_i. For instance, this collection may be a molecule consisting of electrons, all with charge -e, and nuclei with charge e Z_i , where Z_i is the atomic number of the i th nucleus. The physical quantity (observable) dipole has the quantum mechanical operator:
mathfrak{p} = sum_{i=1}^N , q_i , mathbf{r}_i .

Atomic dipoles

A non-degenerate (S-state) atom can have only a zero permanent dipole. This fact follows quantum mechanically from the inversion symmetry of atoms. All 3 components of the dipole operator are antisymmetric under inversion with respect to the nucleus,
mathfrak{I} ;mathfrak{p}; mathfrak{I}^{-1} = - mathfrak{p},
where stackrel{mathfrak{p}}{} is the dipole operator and stackrel{mathfrak{I}}{}, is the inversion operator. The permanent dipole moment of an atom in a non-degenerate state (see degenerate energy level) is given as the expectation (average) value of the dipole operator,
langle mathfrak{p} rangle = langle, S, | mathfrak{p} |, S ,rangle, where |, S, rangle is an S-state, non-degenerate, wavefunction, which is symmetric or antisymmetric under inversion: mathfrak{I},|, S, rangle= pm |, S, rangle. Since the product of the wavefunction (in the ket) and its complex conjugate (in the bra) is always symmetric under inversion and its inverse,
langle mathfrak{p} rangle = langle, mathfrak{I}^{-1}, S, | mathfrak{p} |, mathfrak{I}^{-1}, S ,rangle = langle, S, | mathfrak{I}, mathfrak{p} , mathfrak{I}^{-1}| , S ,rangle = -langle mathfrak{p} rangle it follows that the expectation value changes sign under inversion. We used here the fact that mathfrak{I},, being a symmetry operator, is unitary: mathfrak{I}^{-1} = mathfrak{I}^{*}, and by definition the Hermitian adjoint mathfrak{I}^*, may be moved from bra to ket and then becomes mathfrak{I}^{**} = mathfrak{I},. Since the only quantity that is equal to minus itself is the zero, the expectation value vanishes,
langle mathfrak{p}rangle = 0. In the case of open-shell atoms with degenerate energy levels, one could define a dipole moment by the aid of the first-order Stark effect. This only gives a non-vanishing dipole (by definition proportional to a non-vanishing first-order Stark shift) if some of the wavefunctions belonging to the degenerate energies have opposite parity; i.e., have different behavior under inversion. This is a rare occurrence, but happens for the excited H-atom, where 2s and 2p states are "accidentally" degenerate (see this article for the origin of this degeneracy) and have opposite parity (2s is even and 2p is odd).

Field from a magnetic dipole

Magnitude

The far-field strength, B, of a dipole magnetic field is given by

B(m, r, lambda) = frac {mu_0} {4pi} frac {m} {r^3} sqrt {1+3sin^2lambda}

where

B is the strength of the field, measured in teslas;
r is the distance from the center, measured in metres;
λ is the magnetic latitude (90°-θ) where θ = magnetic colatitude, measured in radians or degrees from the dipole axis (Magnetic colatitude is 0 along the dipole's axis and 90° in the plane perpendicular to its axis.);
m is the dipole moment (VADM=virtual axial dipole moment), measured in ampere square-metres (A•m2), which equals joules per tesla;
μ0 is the permeability of free space, measured in henrys per metre.

Conversion to cylindrical coordinates is achieved using

r^2 = z^2 + rho^2
and
lambda = arcsinleft(frac{z}{sqrt{z^2+rho^2}}right)

where ρ is the perpendicular distance from the z-axis. Then,

B(rho,z) = frac{mu_0 m}{4 pi (z^2+rho^2)^{3/2}} sqrt{1+frac{3 z^2}{z^2 + rho^2}}

Vector form

The field itself is a vector quantity:

mathbf{B}(mathbf{m}, mathbf{r}) = frac {mu_0} {4pi r^3} left(3(mathbf{m}cdothat{mathbf{r}})hat{mathbf{r}}-mathbf{m}right) + frac{2mu_0}{3}mathbf{m}delta^3(mathbf{r})

where

B is the field;
r is the vector from the position of the dipole to the position where the field is being measured;
r is the absolute value of r: the distance from the dipole;
hat{mathbf{r}} = mathbf{r}/r is the unit vector parallel to r;
m is the (vector) dipole moment;
μ0 is the permeability of free space;
delta^3 is the three-dimensional delta function. (delta^3(mathbf{r}) = 0 except at r = (0,0,0), so this term is ignored in multipole expansion.)
This is exactly the field of a point dipole, exactly the dipole term in the multipole expansion of an arbitrary field, and approximately the field of any dipole-like configuration at large distances.

Magnetic vector potential

The vector potential A of a magnetic dipole is

mathbf{A}(mathbf{r}) = frac {mu_0} {4pi r^2} (mathbf{m}timeshat{mathbf{r}})

with the same definitions as above.

Field from an electric dipole

The electrostatic potential at position mathbf{r} due to an electric dipole at the origin is given by:

Phi(mathbf{r}) = frac{1}{4piepsilon_0},frac{mathbf{p}cdothat{mathbf{r}}}{r^2}

where

hat{mathbf{r}} is a unit vector in the direction of mathbf{r};
p is the (vector) dipole moment;
ε0 is the permittivity of free space.

This term appears as the second term in the multipole expansion of an arbitrary electrostatic potential Φ(r). If the source of Φ(r) is a dipole, as it is assumed here, this term is the only non-vanishing term in the multipole expansion of Φ(r). The electric field from a dipole can be found from the gradient of this potential:

mathbf{E} = - nabla Phi =frac {1} {4piepsilon_0} left(frac{3(mathbf{p}cdothat{mathbf{r}})hat{mathbf{r}}-mathbf{p}}{r^3}right) - frac{1}{3epsilon_0}mathbf{p}delta^3(mathbf{r})

where E is the electric field and delta^3 is the 3-dimensional delta function. (delta^3(mathbf{r}) = 0 except at r = (0,0,0), so this term is ignored in multipole expansion.) Notice that this is formally identical to the magnetic field of a point magnetic dipole; only a few names have changed.

Torque on a dipole

Since the direction of an electric field is defined as the direction of the force on a positive charge, electric field lines point away from a positive charge and toward a negative charge.

When placed in an electric or magnetic field, equal but opposite forces arise on each side of the dipole creating a torque τ:

boldsymbol{tau} = mathbf{p} times mathbf{E}
for an electric dipole moment p (in coulomb-meters), or

boldsymbol{tau} = mathbf{m} times mathbf{B}
for a magnetic dipole moment m (in ampere-square meters).

The resulting torque will tend to align the dipole with the applied field, which in the case of an electric dipole, yields a potential energy of

U = -mathbf{p} cdot mathbf{E}.

The energy of a magnetic dipole is similarly

U = -mathbf{m} cdot mathbf{B}.

Dipole radiation

In addition to dipoles in electrostatics, it is also common to consider an electric or magnetic dipole that is oscillating in time.

In particular, a harmonically oscillating electric dipole is described by a dipole moment of the form mathbf{p}=mathbf{p'(mathbf r)}e^{-iomega t} where ω is the angular frequency. In vacuum, this produces fields:

mathbf{E} = frac{1}{4pivarepsilon_0} left{ frac{omega^2}{c^2 r} hat{mathbf{r}} times mathbf{p} times hat{mathbf{r}}
+ left(frac{1}{r^3} - frac{iomega}{cr^2} right) left[3 hat{mathbf{r}} (hat{mathbf{r}} cdot mathbf{p}) - mathbf{p} right] right} e^{iomega r/c}
mathbf{B} = frac{omega^2}{4pivarepsilon_0 c^3} hat{mathbf{r}} times mathbf{p} left(1 - frac{c}{iomega r} right) frac{e^{iomega r/c}}{r}.

Far away (for romega/c gg 1), the fields approach the limiting form of a radiating spherical wave:

mathbf{B} = frac{omega^2}{4pivarepsilon_0 c^3} (hat{mathbf{r}} times mathbf{p}) frac{e^{iomega r/c}}{r}
mathbf{E} = c mathbf{B} times hat{mathbf{r}}

which produces a total time-average radiated power P given by

P = frac{omega^4}{12pivarepsilon_0 c^3} |mathbf{p}|^2.

This power is not distributed isotropically, but is rather concentrated around the directions lying perpendicular to the dipole moment. Usually such equations are described by spherical harmonics, but they look very different. A circular polarized dipole is described as a superposition of two linear dipoles.

See also

References

External links

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