Copper(II) hydroxide (chemical formula Cu(OH)2) is the hydroxide of the metal copper. Copper hydroxide is a pale blue, gelatinous solid. Some forms of copper(II) hydroxide are sold as "stabilized" copper hydroxide, quite likely a mixture of copper(II) carbonate and hydroxide. These are often greener in color.
Copper(II) hydroxide has been known to man since copper smelting began around 5000 BCE although the alchemists were probably the first to manufacture it. This was easily done by mixing solutions of lye and blue vitriol, both chemicals which were known in antiquity.
"Copper in moist air slowly acquires a dull green coating. The green material is a 1:1 mole mixture of Cu(OH)2 and CuCO3.
2Cu(s) + H2O(g) + CO2(g) + O2(g) ---> Cu(OH)2(s) + CuCO3(s)
Moist samples of copper(II) hydroxide slowly turn black due to the formation of copper(II) oxide. When it is dry, however, copper(II) hydroxide does not decompose unless it is heated to 185°C.
Copper(II) hydroxide reacts with a solution of ammonia to form a deep blue solution consisting of the [Cu(NH3)4]2+ complex ion, but the hydroxide is reformed when the solution is diluted with water. Copper(II) hydroxide in ammonia solution, known as Schweizer's reagent, possesses the interesting ability to dissolve cellulose. This property led to it being used in the production of rayon, a cellulosic fiber.
Copper(II) hydroxide has a rather specialized role in organic synthesis. Often, when it is utilized for this purpose, it is prepared in situ by mixing a soluble copper(II) salt and potassium hydroxide.
It is sometimes used in the synthesis of aryl amines. For example, copper(II) hydroxide catalyzes the reaction of ethylenediamine with 1-bromoanthraquinone or 1-amino-4-bromoanthraquinone to form 1-((2-aminoethyl)amino)anthraquinone or 1-amino-4-((2-aminoethyl)amino)anthraquinone, respectively.
Copper(II) hydroxide also converts acid hydrazides to carboxylic acids at room temperature. This is especially useful in synthesizing carboxylic acids with other fragile functional groups. The published yields are generally excellent as is the case with the production of benzoic acid and octanoic acid.
Copper(II) hydroxide is found in several different copper minerals, most notably azurite, malachite, antlerite, and brochantite. Azurite (2CuCO3 • Cu(OH)2 ) and malachite (CuCO3 • Cu(OH)2) are carbonates while antlerite (CuSO4 • 2Cu(OH)2) and brochantite (CuSO4 • 3Cu(OH)2) are sulfates. Copper(II) hydroxide is rarely found as an uncombined mineral because it slowly reacts with carbon dioxide from the atmosphere to form a basic copper(II) carbonate. The mineral of the formula Cu(OH)2 is called spertiniite.
Copper(II) hydroxide has been used as an alternative to the Bordeaux mixture, a fungicide and nematacide. Nowadays, it is disfavored because of environmental contamination problems. Copper(II) hydroxide is also occasionally used as ceramic colorant.
Copper(II) hydroxide is a skin, eye and respiratory irritant. Always wear safety glasses when handling copper hydroxide. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.