Aggregate is the component of a composite material used to resist compressive stress. For efficient filling, aggregate should be much smaller than the finished item, but have a wide variety of sizes. For example, the particles of stone used to make concrete typically include both sand and gravel.
Not all composite materials include aggregate in their design. This is because aggregate particles tend to have about the same dimensions in every direction (that is, an aspect ratio of about one), so that aggregate composites do not display the level of synergy that fiber composites often do. A strong aggregate held together by a weak matrix will be weak in tension, whereas fibers can be less sensitive to matrix properties, especially if they are properly oriented and run the entire length of the part (i.e., a continuous filament).
Most composites are filled with particles whose aspect ratio lies somewhere between oriented filaments and spherical aggregates. A good compromise is chopped fiber, where the performance of filament or cloth is traded off in favor of more aggregate-like processing techniques. Ellipsoid and plate-shaped aggregates are also used.
The upper limit to particle size depends on the amount of flow required before the composite sets (the gravel in paving concrete can be fairly coarse, but fine sand must be used for tile mortar), whereas the lower limit is due to the thickness of matrix material at which its properties change (clay is not included in concrete because it would "absorb" the matrix, preventing a strong bond to other aggregate particles). Particle size distribution is also the subject of much study in the fields of ceramics and powder metallurgy.
Some exceptions to this rule include:
Unless some practical method is implemented to orient the particles in micro- or nano-composites, their small size and (usually) high strength relative to the particle-matrix bond allows any macroscopic object made from them to be treated as an aggregate composite in many respects.
While bulk synthesis of such nanoparticles as carbon nanotubes is currently too expensive for widespread use, some less extreme nanostructured materials can be synthesized by traditional methods, including electrospinning and spray pyrolysis. One important aggregate made by spray pyrolysis is glass microspheres. Often called microballoons, they consist of a hollow shell several tens of nanometers thick and approximately one micrometer in diameter. Casting them in a polymer matrix yields syntactic foam, with extremely high compressive strength for its low density.
Many traditional nanocomposites escape the problem of aggregate synthesis in one of two ways:
Natural aggregates: By far the most widely-used aggregates for nano-composites are naturally occurring. Usually these are ceramic materials whose crystalline structure is extremely directional, allowing it to be easily separated into flakes or fibers. The nanotechnology touted by General Motors for automotive use is in the former category: a fine-grained clay with a laminar structure suspended in a thermoplastic olefin (a class which includes many common plastics like polyethylene and polypropylene). The latter category includes fibrous asbestos composites (popular in the mid-20th century), often with matrix materials such as linoleum and Portland cement.
In-situ aggregate formation: Many micro-composites form their aggregate particles by a process of self-assembly. For example, in high impact polystyrene, two immiscible phases of polymer (including brittle polystyrene and rubbery polybutadiene) are mixed together. Special molecules (graft copolymers) include separate portions which are soluble in each phase, and so are only stable at the interface between them, in the manner of a detergent. Since the number of this type of molecule determines the interfacial area, and since spheres naturally form to minimize surface tension, synthetic chemists can control the size of polybutediene droplets in the molten mix, which harden to form rubbery aggregates in a hard matrix. Dispersion strengthening is a similar example from the field of metallurgy. In glass-ceramics, the aggregate is often chosen to have a negative coefficient of thermal expansion, and the proportion of aggregate to matrix adjusted so that the overall expansion is very near zero. Aggregate size can be reduced so that the material is transparent to infrared light.
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