• Charmian (servant to Cleopatra), servant and advisor to the historical Cleopatra VII of Egypt
• Charmian Carr, an actress is best known for her role as Liesl in The Sound of Music
• Charmian Clift, an Australian writer and essayist during the mid-20th Century
• Charmian Faulkner, a missing/murdered Australian toddler
• Charmian Faulkner, a murdered English woman
• Charmian Gradwell, a British actress
• Charmian Kittredge, the second wife of American author Jack London
• Charmian May, a British actress

You may also be looking for:

• Charmion, an American vaudeville trapeze artist and strongwoman
• Charmion King, a Canadian actress
• Charmion Von Wiegand, an American journalist
• The Conversation of Eiros and Charmion, a science fiction short story by Edgar Allan Poe
• Charmion (skipper), a genus of Hesperiidae (skippers); see List of hesperiid genera:C
• Charmin, a brand-name of toilet paper owned by Procter & Gamble