There are three naturally occurring isotopes of carbon on Earth: 99% of the carbon is carbon-12, 1% is carbon-13, and carbon-14 occurs in trace amounts, e.g. making up as much as 1 part per trillion (0.0000000001%) of the carbon in the atmosphere. The half-life of carbon-14 is 5,730±40 years. It decays into nitrogen-14 through beta-decay. The activity of the modern radiocarbon standardis about 14 disintegrations per minute (dpm) per gram carbon .
The atomic mass of carbon-14 is about 14.003241 amu. The different isotopes of carbon do not differ appreciably in their chemical properties. This is used in chemical research in a technique called carbon labeling: some carbon-12 atoms of a given compound are replaced with carbon-14 atoms (or some carbon-13 atoms) in order to trace them along chemical reactions involving the given compound.
The highest rate of carbon-14 production takes place at altitudes of 9 to 15 km (30.000 to 50,000 ft) and at high geomagnetic latitudes, but the carbon-14 readily mixes and becomes evenly distributed throughout the atmosphere and reacts with oxygen to form radioactive carbon dioxide. Carbon dioxide also dissolves in water and thus permeates the oceans. Carbon-14 can also be produced in ice by fast neutrons causing spallation reactions in oxygen.
Carbon-14 then goes through radioactive beta decay.
The inventory of carbon-14 in Earth's biosphere is about 300 million Curies, of which most is in the oceans.
Radiocarbon dating is a radiometric dating method that uses (14C) to determine the age of carbonaceous materials up to about 60,000 years old. The technique was developed by Willard Libby and his colleagues in 1949 during his tenure as a professor at the University of Chicago. Libby estimated that the radioactivity of exchangeable carbon-14 would be about 14 disintegrations per minute (dpm) per gram. In 1960, he was awarded the Nobel Prize in chemistry for this work. One of the frequent uses of the technique is to date organic remains from archaeological sites. Plants fix atmospheric carbon during photosynthesis, so the level of 14C in plants and animals when they die approximately equals the level of 14C in the atmosphere at that time. However, it decreases thereafter from radioactive decay, allowing the date of death or fixation to be estimated. The initial 14C level for the calculation can either be estimated, or else directly compared with known year-by-year data from tree-ring data (dendrochronology) to 10,000 years ago, or from cave deposits (speleothems), to about 45,000 years of age. A calculation or (more accurately) a direct comparison with tree ring or cave-deposit carbon-14 levels, gives the wood or animal sample age-from-formation. The technique has limitations within the modern industrial era, due to fossil fuel carbon (which has little carbon-14) being released into the atmosphere in large quantities, in the past few centuries.
The above-ground nuclear tests that occurred in several countries between 1955 and 1963 dramatically increased the amount of carbon-14 in the atmosphere and subsequently in the biosphere; after the tests ended the atmospheric concentration of the isotope began to decrease.
One side effect of the change in atmospheric carbon-14 is that this enables the determination of the birth year of an individual: the amount of carbon-14 in tooth enamel is measured with accelerator mass spectrometry and compared to records of past atmospheric carbon-14 concentrations. Since teeth are formed at a specific age and do not exchange carbon thereafter, this method allows age to be determined to within 1.6 years. This method only works for individuals born after 1943, and it must be known whether the individual was born in the Northern or the Southern Hemisphere.
An alternative dating method relies on the lens of the eye; transparent proteins called "lens crystallines" produced during the first year of life are unchanged afterward, so measuring carbon-14 concentrations there can provide a record of the time of birth. The primary restrictions on the technology are that the person has to have been born after 1950, the lens must be removed while the subject is alive or within three days after death before it decays too much, and the individual cannot have subsisted primarily on seafood.
Carbon-14 can be used as a radioactive tracer in medicine. In the urea breath test, a diagnostic test for Helicobacter pylori, urea labeled with approximately carbon-14 is fed to a patient. In the event of a H. pylori infection, the bacterial urease enzyme breaks down the urea into ammonia and radioactively-labeled carbon dioxide, which can be detected by low-level counting of the patient's breath.
Original carbon-14 dating limit re-set to 50,000 years.(News From The Lab)(research from scientists at Woods Hole Oceanographic Institution)(Brief Article)
Feb 02, 2004; Radiocarbon dating is currently accurate to about 26,000 years before the present. Marine scientists at Woods Hole Oceanographic...