acid rain or acid deposition, form of precipitation (rain, snow, sleet, or hail) containing high levels of sulfuric or nitric acids (pH below 5.5-5.6). Produced when sulfur dioxide and various nitrogen oxides combine with atmospheric moisture, acid rain can contaminate drinking water, damage vegetation and aquatic life, and erode buildings and monuments. Automobile exhausts and the burning of high-sulfur industrial fuels are thought to be the main causes, but natural sources, such as volcanic gases and forest fires, may also be significant. It has been an increasingly serious problem since the 1950s, particularly in the NE United States, Canada, and W Europe, especially Scandinavia.

Acid rain became a political issue in the 1980s, when Canada claimed that pollutants from the United States were contaminating its forests and waters. Since then regulations have been enacted in North America and Europe to curb sulfur dioxide emissions from power plants; these include the U.S. Clean Air Act (as reauthorized and expanded in 1990) and the Helsinki protocol (1985), in which 21 European nations promised to reduce emissions by specified amounts. To assess the effectiveness of reductions a comprehensive study, comparing data from lakes and rivers across N Europe and North America, was conducted by an international team of scientists in 1999. The results they reported were mixed: while sulfates (the main acidifying water pollutant from acid rain) were lower, only some areas showed a decrease in overall acidity. It remained to be determined whether more time or a greater reduction in sulfur emissions was needed to reduce freshwater acidity in all areas. See air pollution; forest; pollution.

Any precipitation, including snow, that contains a heavy concentration of sulfuric and nitric acids. This form of pollution is a serious environmental problem in the large urban and industrial areas of North America, Europe, and Asia. Automobiles, certain industrial operations, and electric power plants that burn fossil fuels emit the gases sulfur dioxide and nitrogen oxide into the atmosphere, where they combine with water vapour in clouds to form sulfuric and nitric acids. The highly acidic precipitation from these clouds may contaminate lakes and streams, damaging fish and other aquatic species; damage vegetation, including agricultural crops and trees; and corrode the outsides of buildings and other structures (historic monuments are especially vulnerable). Though usually most severe around large urban and industrial areas, acid precipitation may also occur at great distances from the source of the pollutants.

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