An acetal is a molecule with two single bonded oxygens attached to the same carbon atom.
Traditional usages distinguish ketal from acetals; where the acetal has one R group as H-. Current accepted terminology classifies ketals as a subset of acetals.
The plastic known as acetal is a polyacetal.
Formation of an acetal occurs when the hydroxyl group of a hemiacetal becomes protonated and is lost as water. The carbocation ion that is produced is then rapidly attacked by a molecule of alcohol. Loss of the proton from the attached alcohol gives the acetal. Acetals are stable compared to hemiacetals but their formation is reversible as with esters. As a reaction to create an acetal proceeds, water must be removed from the reaction mixture or it will hydrolyse the product. The formation of acetals reduces the total number of molecules present and therefore is not favourable with regards to entropy. A way to improve this is to use an orthoester as a source of alcohol. Aldehydes and ketones undergo a process called acetal exchange with orthoesters to give acetals. Water produced along with the acetal product is used up in hydrolysing the orthoester and producing more alcohol to be used in the reaction.
Acetals are important in nature, for example in solution the most stable form of glucose is its cyclic hemiacetal and maltose is an acetal made from two glucose units. Acetaldehyde diethyl acetal is an important flavouring compound in distilled beverages.
Advantages of acetal based plastics:
Disadvantages of acetal based plastics:
Happy Birthday, Delrin.(Delrin 327 UV acetal addresses automotive interior requirements.)(New lubricated Delrin acetal grades, 100 TL and 500 MP.)(DuPont has introduced low-emission Delrin acetal grades.)
Oct 09, 2006; By Design News Staff Now 50 years old, DuPont's acetal polymer has gotten a makeover Delrin acetal turns 50 this...