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Walther Hermann Nernst

Walther Hermann Nernst

Nernst, Walther Hermann, 1864-1941, German physicist and chemist, a founder of modern physical chemistry. After doing outstanding research on osmotic pressure and electrochemistry, he turned to thermodynamics, establishing in 1906 a new tenet (often called the third law of thermodynamics) that dealt with the behavior of matter at temperatures approaching absolute zero. For his work in thermodynamics he won the 1920 Nobel Prize in Chemistry. He later specialized in electroacoustics and astrophysics. Nernst invented (1898) an electric metallic-filament lamp, a link between the carbon lamp and the incandescent lamp. His works include Theoretical Chemistry from the Standpoint of Avogadro's Rule and Thermodynamics (1893, 5th Eng. ed. 1923) and The New Heat Theorem (1918, tr. 1926).

See biography by K. A. G. Mendelssohn (1973).

(born June 25, 1864, Briesen, Prussia—died Nov. 18, 1941, Muskau, Ger.) German scientist, one of the founders of modern physical chemistry. He taught at the Universities of Göttingen and Berlin until forced to retire in 1933 by the Nazi regime. Nernst's researches on the theory of electric cells (see battery), the thermodynamics of chemical equilibrium, the properties of vapours at high temperatures and of solids at low temperatures, and the mechanism of photochemistry have had important applications. His formulation of the third law of thermodynamics gained him a 1920 Nobel Prize. He also invented an improved electric light and an electronically amplified piano.

Learn more about Nernst, Walther Hermann with a free trial on Britannica.com.

Walther Hermann Nernst (June 25, 1864November 18, 1941) was a German physicist who is known for his theories behind the calculation of chemical affinity as embodied in the third law of thermodynamics, for which he won the 1920 Nobel Prize in chemistry. Nernst helped establish the modern field of physical chemistry and contributed to electrochemistry, thermodynamics, solid state chemistry and photochemistry. He is also known for developing the Nernst equation.

Biography

Nernst was born in Briesen in West Prussia (now Wąbrzeźno in Poland). He studied physics and mathematics at the universities of Zürich, Berlin and Graz. After some work at Leipzig, he founded the Institute of Physical Chemistry and Electrochemistry at Göttingen. Nernst invented, in 1897, the Nernst lamp, an electric lamp using an incandescent ceramic rod (the successor to the carbon lamp and the precursor to the incandescent lamp). Nernst researched osmotic pressure and electrochemistry. In 1905, he established what he referred to as his "New Heat Theorem", later known as the Third law of thermodynamics (which describes the behavior of matter as temperatures approach absolute zero). This is the work for which he is best remembered, as it provided a means of determining free energies (and therefore equilibrium points) of chemical reactions from heat measurements. Theodore Richards claimed Nernst had stolen the idea from him, but Nernst is almost universally credited with the discovery.

In 1920, he received the Nobel Prize in chemistry in recognition of his work in thermochemistry. In 1924, he became director of the Institute of Physical Chemistry at Berlin, a position from which he retired in 1933. Nernst went on to work in electroacoustics and astrophysics.

Nernst developed an electric piano, the "Neo-Bechstein-Flügel" in 1930 in association with the Bechstein and Siemens companies, replacing the sounding board with radio amplifiers. The piano used electromagnetic pickups to produce electronically modified and amplified sound in the same way as an electric guitar.

His Nernst glower, important in the field of infra-red spectroscopy, is a solid-body radiator with a filament of rare-earth oxides. Continuous ohmic heating of the filament results in conduction. The glower operates best in wavelengths from 2 to 14 micrometers.

Nernst was a vocal critic of Adolf Hitler and Nazism, and he had two daughters who married Jews. In 1933, the rise of Nazism led to the end of Nernst's career as a scientist. Nernst died in 1941 and is buried near Max Planck in Göttingen, Germany.

Publications

  • Walther Nernst, "Reasoning of theoretical chemistry: Nine papers (1889-1921)" (Ger., Begründung der Theoretischen Chemie : Neun Abhandlungen, 1889-1921). Frankfurt am Main : Verlag Harri Deutsch, c. 2003. ISBN 3-8171-3290-5
  • Walther Nernst, "The theoretical and experimental bases of the New Heat Theorem" (Ger., Die theoretischen und experimentellen Grundlagen des neuen Wärmesatzes). Halle [Ger.] W. Knapp, 1918 [tr. 1926]. [ed., this is a list of thermodynamical papers from the physico-chemical institute of the University of Berlin (1906-1916); Translation available by Guy Barr (LCCN 27002575)])
  • Walther Nernst, "Theoretical chemistry from the standpoint of Avogadro's rule and thermodynamics" (Ger., Theoretische Chemie vom Standpunkte der Avogadroschen Regel und der Thermodynamik). Stuttgart, F. Enke, 1893 [5th edition, 1923]. LCCN po 28000417

References

Further reading

  • Mendelssohn, Kurt A. G., "The world of Walther Nernst. The rise and fall of German science.". Macmillan, 1973 (biography).
  • Barkan, Diana Kormos, "Walther Nernst and the Transition to Modern Physical Science". Cambridge University Press, 1998.
  • Bartel, Hans-Georg and Huebener, Rudolf P. "Walther Nernst. Pioneer of Physics and of Chemistry". World Scientific, 2007.
  • Patrick Coffey, Cathedrals of Science: The Personalities and Rivalries That Made Modern Chemistry, Oxford University Press, 2008. ISBN 978-0-19-532134-0

External links

  • "Hermann Walther Nernst, Nobel Prize in Chemistry 1920 : Prize Presentation". Presentation Speech by Professor Gerard de Geer, President of the Royal Swedish Academy of Sciences.
  • Schmitt, Ulrich, " Walther Nernst". Physicochemical institute, Göttingen

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