Slavo-Serbia was directly governed by Russia's Governing Senate. The settlers eventually formed the Bakhmut hussar regiment in 1764. Also in 1764, Slavo-Serbia was transformed into the Donets uyezd of Yekaterinoslav Governorate (now in Dnipropetrovs'ka oblast', Ukraine).
The province had ethnically diverse population that included Serbs, Vlachs, Hungarians, Macedonians, and others. In 1755, the population of Slavo-Serbia numbered 1,513 inhabitants (of both genders), while in 1763, the population numbered 3,992 male inhabitants, of whom only 378 were Serbs.
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