In the video Twain is riding around on her horse through rows of Yucca wearing red dress, and walking around within the hotel wearing white dress with the corset. Near the end of the video a tear running down Shania's face can be seen.
Released to adult contemporary radio on March 28 2005, "Don't!" debuted at number 29, the highest debut of the week, on April 16 2005. The single spent 16 weeks on the chart and climbed to a peak position of number 18 on May 14 2005, where it remained for four non-consecutive weeks. "Don't!" became Twain's tenth consecutive top twenty single, making all of Twain's singles released to AC hit the top twenty so far.
In the UK, "Don't!" appeared at its peak position of number 30 on March 12 2005. This became, and remains her lowest peaking single in that country, and only remained on the chart for two weeks. It fell to number 57 in its second week, then fell off the chart completely. The low peak can be attributed to no promotion by Twain or the label, and was basically released for fans.
| Chart | Peak position |
|---|---|
| Canadian Singles Chart | 24* |
| Canadian BDS Airplay Chart | 10 |
| Eurochart Hot 100 | 58 |
| German Singles Chart | 58 |
| Irish Singles Chart | 48 |
| Romanian Singles Chart | 77 |
| UK Singles Chart | 30 |
| U.S. Billboard Hot Country Singles & Tracks | 24 |
| U.S. Billboard Adult Contemporary | 18 |
| U.S. Billboard Bubbling Under Hot 100 Singles | 22** |