In the former case, one may regard the Gelfand representation as a far-reaching generalization of the Fourier transform of an integrable function. In the latter case, the Gelfand-Naimark representation theorem is one avenue in the development of spectral theory for normal operators, and generalizes the notion of diagonalizing a normal matrix.
For any locally compact Hausdorff topological space X, the space C0(X) of continuous complex-valued functions on X which vanish at infinity is in a natural way a commutative C*-algebra:
Note that A is unital if and only if X is compact, in which case C0(X) is equal to C(X), the algebra of all continuous complex-valued functions on X.
It can be shown that every character on A is automatically continuous, and hence is a subset of the space of continuous linear functionals on A; moreover, when equipped with the relative weak-* topology, turns out to be locally compact and Hausdorff. (This follows from the Banach-Alaoglu theorem.) The space is compact (in the topology just defined) if and only if the algebra A has an identity element.
Given , one defines the function by . The definition of and the topology on it ensure that is continuous and vanishes at infinity, and that the map defines a norm-decreasing, unit-preserving algebra homomorphism from A to . This homomorphism is the Gelfand representation of A, and is the Gelfand transform of the element . In general the representation is neither injective nor surjective.
In the case where A has an identity element, there is a bijection between and the set of maximal proper ideals in A (this relies on the Gelfand-Mazur theorem). As a consequence, the kernel of the Gelfand representation may be identified with the Jacobson radical of A. Thus the Gelfand representation is injective if and only if A is semisimple.
In the case where , the L1-convolution algebra of the real half-line, then is homeomorphic to , and the Gelfand transform of an element is the Laplace transform .
The spectrum or Gelfand space of a commutative C*-algebra A, denoted Â, consists of the set of non-zero *-homomorphisms from A to the complex numbers. Elements of the spectrum are called characters on A. (It can be shown that every algebra homomorphism from A to the complex numbers is automatically a *-homomorphism, so that this definition of the term 'character' agrees with the one above.)
In particular, the spectrum of a commutative C*-algebra is a locally compact Hausdorff space: In the unital case, i.e. where the C*-algebra has a multiplicative unit element 1, all characters f must be unital, i.e. f(1) is the complex number one. This excludes the zero homomorphism. So  is closed under weak-* convergence and the spectrum is actually compact. In the non-unital case, the weak-* closure of  is  ∪ {0}, where 0 is the zero homomorphism, and the removal of a single point from a compact Hausdorff space yields a locally compact Hausdorff space.
Note that spectrum is an overloaded word. It also refers to the spectrum σ(x) of an element x of an algebra with unit 1, that is the set of complex numbers r for which x - r 1 is not invertible in A. For unital C*-algebras, the two notions are connected in the following way: σ(x) is the set of complex numbers f(x) where f ranges over Gelfand space of A. Together with the spectral radius formula, this shows that  is a subset of the unit ball of A* and as such can be given the relative weak-* topology. This is the topology of pointwise convergence. A nets {fk}k of elements of the spectrum of A converges to f if and only if for each x in A, the net of complex numbers {fk(x)}k converges to f(x).
If A is a separable C*-algebra, the weak-* topology is metrizable on bounded subsets. Thus the spectrum of a separable commutative C*-algebra A can be regarded as a metric space. So the topology can be characterized via convergence of sequences.
Equivalently, σ(x) is the range of γ(x), where γ is the Gelfand representation.
Let A be a commutative C*-algebra and let X be the spectrum of A. Let be the Gelfand representation defined above.
Theorem. The Gelfand map γ is an isometric *-isomorphism from A onto C0(X).
See the Arveson reference below.
The spectrum of a commutative C*-algebra can also be viewed as the set of all maximal ideals m of A, with the hull-kernel topology (see the earlier remarks for the general, commutative Banach algebra case). For any such m the quotient algebra A/m is one-dimensional (by the Gelfand-Mazur theorem), and therefore any a in A gives rise to a complex-valued function on Y.
In the case of C*-algebras with unit, the spectrum map gives rise to a contravariant functor from the category of C*-algebras with unit and unit-preserving continuous *-homomorphisms, to the category of compact Hausdorff spaces and continuous maps. This functor is one half of a contravariant equivalence between these two categories (its adjoint being the functor that assigns to each compact Hausdorff space X the C*-algebra ). In particular, given compact Hausdorff spaces X and Y, then C(X) is isomorphic to C(Y) (as a C*-algebra) if and only if X is homeomorphic to Y.
The 'full' Gelfand–Naimark theorem is a result for arbitrary (abstract) noncommutative C*-algebras A, which though not quite analogous to the Gelfand representation, does provide a concrete representation of A as an algebra of operators.
One of the most significant applications is the existence of a continuous functional calculus for normal elements in C*-algebra A: An element x is normal if and only if x commutes with its adjoint x*, or equivalently if and only if it generates a commutative C*-algebra C*(x). By the Gelfand isomorphism applied to C*(x) this is *-isomorphic to an algebra of continuous functions on a locally compact space. This observation leads almost immediately to:
Theorem. Let A be a C*-algebra with identity and x an element of A. Then there is a *-morphism f → f(x) from the algebra of continuous functions on the spectrum σ(x) into A such that
This allows us to apply continuous functions to bounded normal operators on Hilbert space.