Unlike scientists such as Antoine Lavoisier and Isaac Newton who were more widely recognized, Scheele had a humble position in a small town, and preferred that to the grandeur of an extravagant house, yet he was still able to make significant scientific discoveries. Scheele turned down high-paying offers by prestigious European academies. Frederick II offered him a Berlin position, and the English government offered him a generous salary for his work, but Scheele remained at his pharmacy to serve his faithful customers.
Scheele made many discoveries in chemistry before others who are generally given the credit. One of Scheele's most famous discoveries was oxygen produced as a by-product in a number of experiments in which he heated chemicals during 1771-1772. Scheele, though, did not name or define oxygen; that job would fall to Antoine Lavoisier, the second to quantitatively isolate the gas, (August 1774), who published a paper with the new name in 1775.
Scheele described the discovery of oxygen and nitrogen (1772-1773), in his only book, Chemische Abhandlung von der Luft und dem Feuer (Chemical Treatise on Air and Fire) in 1777, losing some fame to Joseph Priestley, who independently discovered oxygen in 1774. In his book, he also distinguished heat transfer by thermal radiation from that by convection or conduction. Like many other chemists of his time, Scheele often worked under difficult and even dangerous conditions. Also, he had a habit of tasting chemicals that he found. It appears that this was the cause of his premature death at the age of 43; his death symptoms resemble mercury poisoning. (Scheele also discovered an element called Molybdenum (Mo), which is now number 42 on the Periodic Table of the Elements. He discovered it in Köping, Sweden.)
The possibly apocryphal story is told that Scheele was to be ennobled by Gustavus III for his discoveries, but that the honor was mistakenly conferred on an obscure soldier of the same name (Fuller's Thesaurus of Anecdotes, 1116).
By the time he was a teenager, Scheele had learned the dominant theory on gases in the 1770s, the phlogiston theory. Phlogiston, classified as "matter of fire" stated that any material that was able to burn would release phlogiston during combustion, and stops when all the phlogiston had been released. When Scheele discovered oxygen he called it "fire air" because it supported combustion, but he explained oxygen using phlogistical terms because he did not believe that his discovery disproved the phlogiston theory. Before Scheele made his discovery of oxygen, he studied air. Air was thought to be an element that made up the environment in which chemical reactions took place but did not interfere with the reactions. Scheele's investigation of air enabled him to conclude that air was a mixture of "fire air" and "foul air;" in other words, a mixture of two gases. He performed numerous experiments in which he burned substances such as saltpeter (potassium nitrate), manganese dioxide, heavy metal nitrates, silver carbonate and mercuric oxide. In all of these experiments, he isolated gas with the same properties; his "fire air," which he believed combined with phlogiston to be released during heat-releasing reactions. However, his first publication , A Chemical Treatise on Air and Fire, was not released until 1777 at which time both Joseph Priestley and Lavoisier had already published their experimental data and conclusions concerning oxygen and the phlogiston theory.
Scheele's study of the gas not yet named oxygen was sparked by a complaint by Torbern Olof Bergman. Bergman informed Scheele that the saltpeter he purchased from Scheele's employer produced red vapors when it came into contact with acid. Scheele's quick explanation for the vapors led Bergman to suggest that Scheele analyze the properties of manganese dioxide. It was through his studies with manganese dioxide that Scheele developed his concept of "fire air." He ultimately obtained oxygen by heating mercuric oxide, silver carbonate, magnesium nitrate, and saltpeter. Scheele wrote about his findings to Lavoisier who was able to grasp the significance of the results.
Scheele made one other very important scientific discovery in 1774, arguably more revolutionary than his isolation of oxygen. He identified lime, silica, and iron, in a specimen of pyrolusite given to him by his friend, Johann Gottlieb Gahn, but could not identify an additional component. When he treated the pyrolusite with hydrochloric acid over a warm sand bath, a yellow-green gas with a strong odor was produced. He found that the gas sank to the bottom of an open bottle and was denser than ordinary air. He also noted that the gas was not soluble in water. It turned corks a yellow color and removed all color from wet, blue litmus paper and some flowers. He called this gas with bleaching abilities, "dephlogisticated marine acid" (dephlogisticated hydrochloric acid). Eventually, Sir Humphrey Davy named the gas chlorine.
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