No. 5 is the last studio album to feature Kei Yasuda and Natsumi Abe as full members of the group. Yasuda graduated later in 2003, and Abe graduated in early 2004. It is also the first Morning Musume studio album to feature a former member as a returning guest artist, as Maki Goto guests on "Yes! Pocky Girls" and "Sotsugyou Rouko" (as well as appears on "Do it! Now", her last single as a member of the band).
Two of the songs, "Megami ~Mousse na Yasashisa~" and "Yes! Pocky Girls", are credited to two one-time Morning Musume spinoff groups, "Venus Mousse" and "Pocky Girls", respectively. The songs originated as promotional songs for Pocky biscuit snacks and appeared in versions that are least one minute shorter on the Petit Best 3 compilation album in December 2002.