Carbonaceous chondrites comprise about 4 percent of all meteorites observed to fall from space. Prior to 1969, the carbonaceous chondrite class was known from a small number of uncommon meteorites such as Orgueil, which fell in France in 1864. Meteorites similar to Allende were known, but many were small and poorly studied.
Allende contains chondrules and CAIs that are estimated to be about 4.567 billion years old, the oldest known matter (other carbonaceous chondrites also contain these). This material is 30 million years older than the earth and 700 million years older than the oldest rock known on Earth, Thus, the Allende meteorite has revealed information about conditions prevailing during the early formation of our solar system. Carbonaceous chondrites, including Allende, are the most primitive meteorites, and contain the most primitive known matter. They have undergone the least mixing and remelting since the early stages of solar system formation. Because of this, their age is frequently taken as the "age of the solar system."
The meteorite was formed from nebular dust and gas during the early formation of the solar system. It is a "stone" meteorite, as opposed to an "iron," or "stony iron," the other two general classes of meteorite. Most Allende stones are covered, in part or in whole, by a black, shiny crust created as the stone descended at great speed through the atmosphere as it was falling towards the earth from space. This causes the exterior of the stone to become very hot, melting it, and forming a glassy "fusion crust."
When an Allende stone is sawed into two pieces and the surface is polished, the structure in the interior can be examined. This reveals a dark matrix embedded throughout with mm-sized, lighter-colored chondrules, tiny stony spherules found only in meteorites and not in earth rock. (Thus it is a chondritic meteorite.) Also seen are white inclusions, up to several cm in size, ranging in shape from spherical to highly irregular or "amoeboidal." These are known as calcium-aluminum-rich inclusions or "CAIs", so named because they are dominantly composed of Ca- and Al-rich silicate and oxide minerals. Like many chondrites, Allende is a breccia, and contains many dark-colored clasts or "dark inclusions" which have a chondritic structure that is distinct from the rest of the meteorite. Unlike many other chondrites, Allende is almost completely lacking in Fe-Ni metal.
The matrix and the chondrules consist of many different minerals, dominantly olivine and pyroxene. Allende is classified as a CV3 carbonaceous chondrite: the chemical composition, which is rich in refractory elements like Ca, Al, and Ti, and poor in relatively volatile elements like Na and K, places it in the CV group, and the lack of secondary heating effects is consistent with petrologic type 3 (see meteorites classification). Like most carbonaceous chondrites and all CV chondrites, Allende is enriched in the isotope O-16 relative to the less abundant oxygen isotopes, O-17 and O-18.
There was found to be a small amount of carbon (including graphite and diamond), and many organic compounds, including amino acids, some not known on Earth. Iron, mostly combined, makes up about 24% of the meteorite.
Close examination of the chondrules in 1971, by a team from Case Western Reserve University, revealed tiny black markings, up to 10 trillion per square centimeter, which were absent from the matrix and interpreted as evidence of radiation damage. Similar structures have turned up in lunar basalts but not in their terrestrial equivalent which would have been screened from cosmic radiation by the Earth's atmosphere and geomagnetic field. Thus it appears that the irradiation of the chondrules happened after they had solidified but before the cold accretion of matter that took place during the early stages of formation of the solar system, when the parent meteorite came together.
The discovery at California Institute of Technology in 1977 of new forms of the elements calcium, barium and neodymium in the meteorite was believed to show that those elements came from some source outside the early clouds of gas and dust that formed the solar system. This supports the theory that shockwaves from a supernova - the explosion of an aging star - may have triggered the formation of, or contributed to the formation of our solar system. As further evidence, the Caltech group said the meteorite contained Aluminum 26, a rare form of aluminum. This acts as a "clock" on the meteorite, dating the explosion of the supernova to within less than 2 million years before the solar system was formed. Subsequent studies have found isotopic ratios of krypton, xenon, nitrogen and other elements that are also unknown in our solar system. The conclusion, from many studies with similar findings, is that there were a lot of substances in the presolar disc that were introduced as fine "dust" from nearby stars, including novas, supernovas, and red giants. These specks persist to this day in meteorites like Allende, and are known as presolar grains.
Disordered biopyriboles, amphibole, and talc in the Allende meteorite: products of nebular or parent body aqueous alteration?
May 16, 1997; Carbonaceous chondrites are among the most primitive of solar system materials and provide important clues into processes such as...
Incorporation of Short-Lived [sup.10]Be in a Calcium-Aluminum-Rich Inclusion from the Allende Meteorite.(Statistical Data Included)
Aug 25, 2000; When the oldest solar system materials, the Ca-Al-rich inclusions (CAIs) of primitive chondrite meteorites (1), first...