Many unpaired words are the result of one of the words disappearing from popular usage, though others were never part of a pairing and just begin with the same letters as used in common prefixes.
| Word | Paired word(s) | Notes |
|---|---|---|
| Disambiguate | *Ambiguate | Not a word; derived from dis- + ambigu(ous) + -ate in the mid-20th century |
| Disconsolate | Consolate | Derived from the Latin consolatus; rarely used |
| Disheveled, Dishevelled | *Sheveled, *Shevelled | Not a word; from the Old French deschevelé |
| Indomitable | Domitable | Rarely used antonym |
| Ineffable | Effable | Rarely used antonym |
| Innocent | Nocent | Not an exact antonym; rarely used |
| Innocuous | Nocuous | Rarely used antonym |
| Uncouth | Couth | Derived from Old English word cunnan meaning "well-known" or "familiar"; rarely used |
| Ungainly | Gainly | Rarely used antonym |
| Unkempt | Kempt | Rarely used antonym |
| Unruly | Ruly | Rarely used antonym |
| Unstinting | Stinting | Rarely used antonym |
| Untoward | Toward | Not an antonym |
| Unwieldy | Wieldy | Rarely used antonym |
amongst others. Congress is from the Middle English congresse meaning a body of attendants, (Latin congressus, meaning a meeting), and progress is from Middle English progresse (Latin prōgressus) meaning to advance. Here, pro and con are in fact not opposite, with con meaning "together" and pro meaning "supporting" or "in place of" (while in other contexts con, or contr- can mean "against").